吹扫-捕集气相色谱法测定海水中挥发性卤代烃

挥发性卤代烃(VHC)是大气中的痕量气体,对臭氧层损耗和温室效应有重要作用。海洋是大气中VHC的主要自然排放源,开展海洋VHC的研究有助于了解海洋对大气VHC和全球变暖的贡献。本文建立了吹扫-捕集与气相色谱-微池电子捕获检测器联用技术(P-T-GC-(ECD)分析海水中6种VHC的方法,确定了吹扫-捕集条件和气相色谱分离条件。该方法的检测限在0.003~0.369 ng.L-1之间;相对标准偏差是1.83~3.97;加标回收率为98.1%~110.2%;相关系数在0.997 3~0.999 8之间。可准确地测定海水中6种VHC。     

A Moored Underwater Energy Conservation System for Profiling Measurement

There is a need to obtain the hydrologic data including ocean current,wave,temperature and so on in the South China Sea.A new profiling instrument which does not suffer from the damage due to nature forces or incidents caused by passing ships,is under development to acquire data from this area.This device is based on a taut single point mid-water mooring system.It incorporates a small,instrumented vertically profiling float attached via an electromechanical cable to a winch integral with the main subsurface flotation.On a pre-set schedule,the instrument float with sensors is winched up to the surface if there is no ship passing by,which is defined by an on-board miniature sonar.And it can be immediately winched down to a certain depth if the sonar sensor finds something is coming.Since,because of logistics,the area can only be visited once for a long time and a minimum of 10 times per day profiles are desired,energy demands are severe.To respond to these concerns,the system has been designed to conserve a substantial portion of the potential energy lost during the ascent phase of each profile and subsequently use this energy to pull the instrument down.Compared with the previous single-point layered measuring mode,it is advanced and economica1.At last the paper introduces the test in the South China Sea.     

Forecasting ocean wave energy: The ECMWF wave model and time series methods

Recently, the technology has been developed to make wave farms commercially viable. Since electricity is perishable, utilities will be interested in forecasting ocean wave energy. The horizons involved in short-term management of power grids range from as little as a few hours to as long as several days. In selecting a method, the forecaster has a choice between physics-based models and statistical techniques. A further idea is to combine both types of models. This paper analyzes the forecasting properties of a well-known physics-based model, the European Center for Medium-Range Weather Forecasts (ECMWF) Wave Model, and two statistical techniques, time-varying parameter regressions and neural networks. Thirteen data sets at locations in the Atlantic and Pacific Oceans and the Gulf of Mexico are tested. The quantities to be predicted are the significant wave height, the wave period, and the wave energy flux. In the initial tests, the ECMWF model and the statistical models are compared directly. The statistical models do better at short horizons, producing more accurate forecasts in the 1-5 h range. The ECMWF model is superior at longer horizons. The convergence point, at which the two methods achieve comparable degrees of accuracy, is in the area of 6 h. By implication, the physics-based model captures the underlying signals at lower frequencies, while the statistical models capture relationships over shorter intervals. Further tests are run in which the forecasts from the ECMWF model are used as inputs in regressions and neural networks. The combined models yield more accurate forecasts than either one individually.     

黄条鰤贮藏挥发性化合物的研究

用气相色谱仪和气—质联机等方法对黄条鱼师的腐败挥发性化合物进行了定性和定量分析。这将有利于对黄条做一步的生化性质分析和制定其鲜品的国家标准。样品在２５℃贮藏５ｄ期间，测定了某些化学指标。结果表明在贮藏１ｄ后，鱼肉变腐臭，挥发性碱基化合物三甲胺和二甲基在贮藏中增加。在５ｄ的贮藏期间发现的挥发性有机酸包括乙酸、丙酸、丁酸、异丁酸、戊酸、异成酸，并且它们的含量不断增加，检测出脂肪氧化产物和含硫化合物，正己醛、３—辛酮、３，５—丰二烯—２—酮，２—壬酮辛烯—３—醇，二甲基三硫化物、１Ｈ—吲哚等都是黄条腐败时产生的重要挥发性化合物。应指出的是，２—甲基丁醇、庚醇、苯酚、辛烯—３—醇己醛是黄条中所特有的化合物，其余化合物与其它鱼类的挥发性化合物几乎相近。     

变性绕极深层水入侵时南极普里兹湾湍流混合特征研究

基于中国第28、29和31次南极科学考察中的CTD数据,利用Thorpe尺度方法计算了普里兹湾及其附近海域湍动能耗散率,分析了其分布特征,并对当地的水团结构进行研究.结果表明,普里兹湾及其附近海域中,前两个航次观测中次表层湍动能耗散率强度在陆架坡折区域达到最大.在水团分布方面,在第28和29航次中均观测到了变性绕极深层...     

绿色海堤的沉积地貌与生态系统动力学原理: 研究综述*

绿色海堤是传统结构工程与海岸生态系统共同组合而成的新型海堤, 用以应对未来海面上升、风暴加剧给低地海岸防护带来的挑战。需解决的问题主要有海岸生态系统消浪过程及生态系统在海堤体系中的配置方式。理论分析、现场观测、物模数模所获结果表明, 海岸生态系统确有显著的消浪功能: 1) 陆架泥区消浪, 其机制以再悬浮和浮泥运动为主, 底部摩擦为次; 2) 潮滩下部的粉砂细砂滩底部摩擦和推移质运动共同造成波能耗散, 而上部的泥滩则以再悬浮和悬沙输运为主; 3) 在盐沼、红树林、海草床等由植被构成的生态系统, 植物通过形态阻力、茎秆运动来阻滞水流、耗散波能, 其效能高于沉积物床面对波能的耗散; 4) 生物礁主要有珊瑚礁和牡蛎礁, 其消能作用主要通过床面摩擦和波浪破碎, 效能较高, 尤其是在风暴期间。生态系统如何成为海堤的有机组成部分, 尤其是侵蚀型海岸的生态位修复和绿色海堤整体设计, 还需进一步研究相关的科学问题: 与硬质工程结合的盐沼-牡蛎礁的适应性生物学; 未来环境变化条件下生态系统的稳定性; 绿色海堤生态系统空间配置及其与风暴事件的时间尺度匹配; 基于均衡剖面理论的海堤形态优化。     

换道概率对交通系统动能的影响

基于跟车模型的特点,提出了跟车模型的动能变化公式,利用该公式研究换道概率对各车辆动能的影响.数值实验结果表明,换道概率和相对速度对各车辆动能产生较大影响,但换道概率和相对速度会分别降低其动能变化频率和幅度.此外,系统增加的平均动能会随着系统最大换道概率的增加而降低.     

Analytical method of radiation by a wave energy device with dual rectangular floating bodies

The system with one floating rectangular body on the free surface and one submerged rectangular body has been applied to a wave energy conversion device in water of finite depth. The radiation problem by this device on a plane incident wave is solved by the use of an eigenfunction expansion method, and a new analytical expression for the radiation velocity potential is obtained. The wave excitation force is calculated via the known incident wave potential and the radiation potential with a theorem of Haskind employed. To verify the correctness of this method, an example is computed respectively through the bound element method and analytical method. Results show that two numerical methods. are in good agreement, which shows that the present method is applicable. In addition, the trends of hydrodynamic coefficients and wave force are analyzed under different conditions by use of the present analytical method.     

先锋孤立子生成的理论平均波阻(Ⅰ).理论

根据作者导得的AfKdV方程，理论上确定了先锋孤立子生成问题的理论平均波阻，能量劈分及能量劈分比。本文的能量劈分是确定先锋孤立子生成参数的理论基础。同时，本理论确定了现有理论中的自由未知参数问题，从而使先锋孤立子生成参数得到理论预报。