金矿样品的几种溶样方法

通过王水、封闭和烧杯敞口及聚乙烯溶样瓶封闭溶样等方法，对含Au矿样的试样分解、溶样体系及各种溶样方法的对比表明，利用聚乙烯溶样瓶，采用HNO3 NaCl KMnO4 NH4HF2溶样体系，在水浴锅中封闭溶样40min，矿样中的Au即可完全分解。经国家标准物质分析验证，结果与标准值相符。封闭溶样可以避免样品外溢、进溅，使分析结果更准确可靠，降低成本，减少环境污染，适用于大批量样品分析。     

贵州百花湖分层晚期有机质降解过程与溶解N2O循环

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。     

地球化学场精细结构解析方案与应用

为满足勘查地球化学对化探数据处理越来越精细的要求，把人工神经网络和统计分析结合起来形成地球化学场精细结构解析方案。该方案包括对地球化学样品的分类和对各类样品性质的详细研究，目的在于提供便捷的数学和计算机软件工具，以提取化探数据中的深层信息。可以用于：①研究各组样品中元素含量水平和组合特征以解释可能的矿种；②研究元素组合特征与指示元素的关联和区别以揭示可能的成矿作用过程；③研究异常样品的空间组合属性以揭示地球化学场的精细结构；④研究异常样品之间的差异性以缩小找矿靶区；⑤综合分析以确定剥蚀深度和找矿前景。该方案也适用于环境地球化学及矿产资源预测研究。     

Approximate modal decomposition of inelastic dynamic responses of wall buildings

Two approximate methods for decomposing complicated inelastic dynamic responses of wall buildings into simple modal responses are presented. Both methods are based on the equivalent linear concept, where a non‐linear structure is represented by a set of equivalent linear models. One linear model is used for representing only one vibration mode of the non‐linear structure, and its equivalent linear parameters are identified from the inelastic response time histories by using a numerical optimizer. Several theoretical relations essential for the modal decomposition are derived under the framework of complex modal analysis. Various numerical examinations have been carried out to check the validity of the proposed modal decomposition methods, and the results are quite satisfactory in all cases. Fluctuating bending moment and shear at any location along the wall height contributed by each individual vibration mode can be obtained. Modal contributions to shear and flexural strength demands, as well as the corresponding modal properties, under various seismic loading conditions can also be identified and examined in detail. Furthermore, the effects of higher vibration modes on seismic demands of wall buildings are investigated by using the modal decomposition methods. Several new insights into the complicated inelastic dynamics of multi‐story wall buildings are presented. Copyright © 2004 John Wiley & Sons, Ltd.     

基于小波分解的西太平洋副热带高压模糊推理预测

基于NCEP/NCAR再分析资料,讨论了西太平洋副高脊线与其前期位置的相互关系,并在此基础上用小波分解和自适应模糊推理方法,对副高脊线进行集成建模和预测.基于小波分解重构的副高脊线短期活动集成预测结果表明,该方法可有效降低预报难度,明显改进和提高了副高脊线短期活动的预报准确率.     

化学腐蚀下砂岩三轴细观损伤机理及损伤变量分析

利用CT识别技术对化学腐蚀下的砂岩进行了三轴加载全过程的即时扫描试验，得到了在不同级荷载作用下砂岩的压密、微裂纹萌生、扩展和破裂的CT图像和CT数，分析了砂岩损伤演化的细观机理。同时，建立了一个基于化学腐蚀影响和CT数的损伤变量模型。     

On Some Simplifications of Cokriging Neighborhood

Choosing the cokriging neighborhood is often difficult. A poor choice, ignoring influent data, can result in a loss of information as well as in artifacts in simulations based on cokriging. Then it is convenient to use if possible, or to refer to models that lead to simplified cokriging neighborhood. We essentially consider the case of two stationary variables, a target variable and an auxiliary one. By examining possible simplifications, we set up a list of models (essentially models with residuals) that, in general or under specific configurations, lead to simplifications of cokriging neighborhood. Collocated, dislocated, and other types of neighborhood are identified, that are optimal in some models and configurations. Possible extensions to cokriging with unknown means, and to more variables, are included.     

A Finite Volume Scheme for the Transport of Radionucleides in Porous Media

The COUPLEX1 Test case (Bourgeat et al., 2003) is devoted to the comparison of numerical schemes on a convection–diffusion–reaction problem. We first show that the results of the simulation can be mainly predicted by a simple analysis of the data. A finite volume scheme, with three different treatments of the convective term, is then shown to deliver accurate and stable results under a low computational cost.     

Asymptotic Analysis and Layer Decomposition for the Couplex Exercise

This document explores the possibilities of multiscale expansions and domain decomposition to solve part of the Couplex 1 exercise. We concentrate on the hydrostatic pressure and show that the slenderness of the domain and the large variations of the Darcy constants allows an analytical approximation which our test reveals to be true to relative errors smaller than 10^–3. The numerical tests are done in 2D with freefem+ and in 3D with freefem3D. Some considerations are also given for Iodine transport.     

川西亚高山三个森林群落的湿林冠蒸发速率

于3个假说和林冠上方2m处的气象变量，采用Penman-Monteith组合模型估算了一个生长季节内川西亚高山林区分别以云杉(SF)、冷杉(FF)和白桦(BF)为优势树种的3个林分的湿林冠蒸发速率(Er)。研究结果表明，SF、FF和BF的湿林冠蒸发量(E)分别为44．51mm、88．51mm和57．8mm，分别占总降雨量的9．2％、16．6％和10．2％。与SF和BF相比，FF具有最高的月平均Er和蒸发比例。SF、FF和BF的平均Er分别为0．097mm／h(变化范围：0．028-0．487mm／h)、0．242mm／h(变化范围：0．068～0．711mm／h)和0．149mm／h(0．060～0．576mm／h)。最高和最低的月平均Er分别在6月(SF、FF和BF分别为0．120mm／h、0．317mm／h和0．169mm／h)和10月(SF、FF和BF分别为0．083mm／h、0．187mm／h和0．101mm／h)。8：00至16：00期间的平均点Er显著高于0：00至8：00以及16：00至0：00期间的平均Er。Er显著的日变化和月变化主要归因于林冠上方的太阳辐射、空气温度和相对湿度的变化。