未定名矿物(Bi38CrO60)的矿物学研究

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.     

Environmental Properties of Minerals and Contaminants Purified by the Mineralogical Method

The investigation of the environmental properties of minerals, i.e., environmental mineralogy, is a branch of science dealing with interactions between natural minerals and spheres of the Earth surface as well as a reflection of global change, prevention of ecological destruction, participation in biomineralogy, and remediation of environmental pollution. Pollutant treatment by natural minerals is based on the natural law and reflects natural self-purification functions in the inorganic world, similar to that of the organic world - a biological treatment. A series of case studies related to natural self-purification, which were mostly completed by our group, are discussed in this paper. In natural cryptomelane there is a larger pseudotetragonal tunnel than that formed by [MnO6] octahedral double chains, with an aperture of 0.462-0.466 nm2, filled with K cations. Cryptomelane might be a real naturally-occurring mineral of the active octahedral molecular sieve (OMS-2). CrⅥ-bearing wastewater can be treate     

SMBR中污染物处理效率随污泥浓度变化的数学模型

以一体式膜生物反应器(SMBR)对生活污水进行处理,研究不同水力停留时间(HRT)条件下污泥浓度对有机物去除率的影响,并对所得试验数据进行曲线拟合,建立有机物去除率与污泥浓度的数学模型。试验结果表明:在溶解氧(DO)浓度为2.0～3.0mg/L的条件下,HRT为3h、2h和1h时,有机物去除率(η)随着污泥浓度的增大而增大,但当污泥浓度增大到6000mg/L时,η增大趋势逐渐减小,并趋于稳定。有机物去除率与污泥浓度的数学模型表明:有机物去除率(η)与水力停留时间(τ)、进水COD浓度(S_o)和污泥负荷率(N_s)等主要运行参数有关,并可以通过调节运行参数τ、S_o和N_s来达到所需要的COD去除率。     

红层软岩隧洞围岩变形破坏机制研究

红层软岩的物质组成、化学成分、物理力学性质等方面在国内外已有较系统的研究,但对软岩隧道围岩的变形破坏机理及其治理一直是工程技术人员关心问题。通过对回龙宫隧洞的地质环境分析及有限元数值计算,阐明了红层隧洞围岩的膨胀变形破坏机理,最后提出了在此类围岩中修建水工隧洞的过程中,防止围岩变形破坏的建议。     

川藏公路二郎山隧道和平沟泥石流特征研究与治理设计

泥石流作为地质环境较差的山区的主要自然灾害之一,对于泥石流的研究思路的进一步发展和完善,在很大程度上将对山区的工程建设有很重要的指导意义。从工程地质研究思路的角度出发,对位于川藏公路二郎山隧道西口和平沟泥石流进行了研究。采用工程地质分析的方法对和平沟泥石流的形成环境(地层岩性条件、构造条件、地貌条件、气象条件、植被发育及人类活动)、基本特征(泥石流沟的基本特征、泥石流的堆积特征)进行了系统的研究,并在此基础上对泥石流沟沿岸的岸坡稳定性(可能泥石流的物源)等进行了评价分析。对泥石流的活动趋势以及可能泥石流的方量做出了较为科学的评价预测。经过这样的系统分析对工程建设中的泥石流防治提出了治理设计方案。     

The Bulong Gold Deposit-a Quartz-Barite Vein Type Gold Deposit in Xinjiang:Geological Characteristics and S, He and Ar Isotopic Compositions

The Bulong gold deposit, located in the southwest Tianshan in China, occurs in the Upper Devonian finegrained clastic rocks. The gold orebodies are controlled by an gently inclined interlayer fractured zone. They are hosted only in quartz-barite veins though there are barite veins and quartz veins in the ore district. The δ34S values of pyrite in the ores range from 14.6‰ to 19.2‰ and those of barite from 35.0‰ to 39.6‰, indicating that the sulfur was derived from the strata. 3He/4He ratios of fluid inclusions in pyrite are 0.24-0.82 R/Ra, approximating to that of the crust. The 40Ar/39Ar ratios range from 338 to 471, slightly higher than that of the atmosphere. 40Ar /4He ratios of ore fluids range from 0.015 to 0.412 with a mean of 0.153. Helium and argon isotope compositions of fluid inclusions show that the ore fluids of the Bulong gold deposit were mainly derived from the crust.     

塔中地区油气运聚特征

塔中地区主要受塔中Ⅰ号、Ⅱ号及Ⅲ号三条大断层控制 ,形成巨型复式背斜 ,隆起高部位地层遭受了强烈的风化剥蚀。背斜之上 ,断裂和局部构造发育。可划分出两个主要成藏期 :第Ⅰ成藏期为寒武系—下奥陶统烃源岩成熟生烃运移期 ,生排烃高峰为志留纪 ;第Ⅱ成藏期为中—上奥陶统烃源岩在燕山期—喜马拉雅期成熟生烃运聚。第Ⅰ成藏期形成的油藏有两个特征 :在塔中Ⅰ号断裂带、北部斜坡带油气注入奥陶系及志留系圈闭中 ,形成原生油气藏 ;构造高部位 (如中央断垒带 )的油气藏在后期构造运动中遭受破坏。第Ⅱ成藏期形成的油藏可分为两类 :对早期油藏的再次充注 ;聚集形成新油藏。塔中地区的油气运移通道主要有断裂和不整合面 ,油气的分布也主要受断裂和不整合面所控制。塔中Ⅰ号构造带和北部斜坡带是较为有利的勘探区带     

岩层离距图法研究沉积岩断裂发育史——以松辽盆地敖古拉断裂为例

利用断裂活动过程中留下的各种地质标记研究断裂发育史是比较困难的 ,已有的研究方法主要可归纳出七种 ,都存在局限性。岩层离距图法是以地震剖面为基础 ,将穿过断裂的各剖面上的标志层投影到沿断裂走向的铅垂面上 ,得到多组标志层的垂向断距数据 ,然后用下部各标志层的断距减去最上部标志层的断距 ,并作多轮次计算 ,直到最后的断距差近似为零或仅剩一个非零标志层。每一轮次计算代表一个活动期次 ,如果出现负值 ,则表示有构造反转。对松辽盆地敖古拉断裂作了实例计算 ,结果为该断裂发育经历了三个正断活动期和一个逆断活动期 ,与盆地区域性活动有些差别。岩层离距图法比起其他已有方法 ,可靠程度大大提高     

Organic Petrological Studies on Immature Source Rocks

Organic petrology is a marginal science that is quite practicable. At present, it has developed into a routine research tool that is widely applied in petroleum exploration and assessment. Based on several years‘ research of the authors, this paper presents the advances in organic petrological studies on immature source rocks, including the classification and characteristics of macerals, the composition of macerals and types of organic matter, the abundance and evolution of organic matter, oil-prone macerals, hydrocarbon generation and expulsion. All these results show that organic petrology is of considerable value pertaining to its application in the assessment of immature oil and gas. The immature source rocks consist of various macerals with obvious heterogeneity, contain different hydrocarbon-generating macerals with different oil thresholds and oil peaks, and show a two-staged evolutionary pattern of organic matter.     

MAPGIS在矿产预测中的应用及其效果——以江西省东北部“金三角”区为例

运用GIS系统对江西省东北部“金三角”区进行资源潜力预测，共圈定Ⅰ级区7个、Ⅱ级区9个。优选其中2个区进行预查及工程验证，预测效果良好。