Researches on the Internal Molecular Weight Uniformity of Chitosan Biomaterials

Uniform molecular weight(Mw)chitosan(CS)is highly demanded in medical biomaterial industry.This present article described heterogeneous degradation of CS in aqueous HCl/ethanol solution,in which progress uniform Mw CS was successfully prepared.The Mw distribution of CS was measured by gel permeation chromatography(GPC)analysis.Moreover,the structure and properties of degraded CS were characterized by Fourier transform infrared spectroscopy(FT-IR),nuclear magnetic resonance spectroscopy(^1H NMR),X-ray diffraction(XRD)and thermogravimetric(TG)analysis.In addition,the biocompatibility of degraded CS was also assessed by hemolysis rate(HR)measurement.The Mw of CS dramatically decreased from 246 KDa to 76 k Da at the initial 30 min,and stabilized at 18 kDa after 24 h.GPC analysis results showed that the degraded CS molecular become homogenization.FT-IR and 1 H NMR analysis confirmed the basic structure of CS molecular backbone was not destroyed during this progress.Besides,the water solubility of CS was not significantly influenced by this reaction.Moreover,the XRD analysis revealed that crystallinity of degraded CS increased from 70.32% to 99.25%with time.The TG analysis showed improved thermal stability of degraded CS.HR measurement demonstrated the degraded CS possessed excellent biocompatibility.This simple and efficient heterogeneous degradation would open up a new route to produce uniform Mw CS.     

定常风场和吞吐流对乌梁素海流场的影响

风场和吞吐流是浅水湖泊运动的主要驱动力,影响着湖区污染物的迁移转化。基于二维非结构网格,构建了乌梁素海水动力模型。通过对比定常风作用下湖流的方向、环流的分布及形式与无风条件下的区别,模拟不同算例吞吐流作用下湖区流速及环流结构的差异,探究了定常风和吞吐流对乌梁素海流场的影响。结果表明:乌梁素海在无风条件下出现大面积的滞流区;风场会增加湖流的流速,影响区域主要在西大滩区、东大滩区及湖区南部明水区,产生明显环流,风场是乌梁素海主要的驱动力; SSW与ENE向风场作用下,典型区域产生的环流位置、形态结构相近,方向相反;吞吐流量的增加会增大湖区整体流速,对湖区流场形态、结构影响较小;定常风条件下,吞吐流量的增加(一定范围)会导致环流强度减弱。研究结果为乌梁素海营养盐、污染物质输移规律研究奠定基础。     

胶东玲珑矿田石英脉型金矿床中流体包裹体特征研究

玲珑矿田含有两种类型金矿床,一是蚀变岩型金矿床,二是石英脉型金矿床。该文重点研究玲珑金矿田西山矿区石英脉型金矿床中流体包裹体的特征。石英脉型金矿床分布在玲珑帚状构造之中,含金石英脉受"帚状构造"的断裂和节理控制,有300余条。流体包裹体显微观察研究表明,玲珑石英脉型金矿新鲜花岗岩和钾化花岗岩主要含有H2O包裹体,其次有少量H2O-CO2包裹体;(黄铁)绢英岩通常含较粗粒石英集合体,石英中有丰富的H2O,特别是H2O-CO2包裹体;金矿体(含金石英脉)含有明显数量的H2O-CO2包裹体;特别是存在较大的三相H2O-CO2包裹体。不同期次(世代)石英中H2O和H2O-CO2包裹体的大小、形态、相对含量和丰度变化较大。     

S－闭空间上的函数

研究了当Ｘ为Ｓ－闭空间时，Ｃ（Ｘ）的子集Ｆ为紧的充要条件，从而扩充了著名的Ａｓｃｏｌｉ定理。     

基于人工地震波作用下大跨度悬索桥多点激励地震响应分析

为研究大跨度悬索桥在多点激励作用下的地震响应规律,在已有的功率谱模型基础上提出了改进的功率谱模型,并将其应用到人工地震波合成过程中。以某水库上主跨720 m双塔单跨悬索桥为研究对象,用Midas civil建立全桥有限元模型,采用大质量法进行不同波速多点激励地震响应分析。结果表明:大跨度悬索桥在多点激励作用下的主塔内力响应、主塔位移响应及主梁位移响应均受行波效应、衰减效应、不相干效应及衰减后地震波叠加效应影响,且最终的响应值由衰减后地震波的叠加效应与衰减效应的共同作用决定;500 m/s多点激励下衰减后的地震波叠加加强效应与衰减效应共同作用后,对主塔轴力响应、主塔塔底顺桥向剪力响应、左塔上横梁处剪力和弯矩响应的加强效果最大;各波速多点激励下,主塔顶顺桥向位移响应相对变化率均大于零且几乎保持不变,主梁两端顺桥向位移响应相对变化率在1 000 m/s波速取得最大值,主梁竖向位移响应在500 m/s取得最大值并随波速的增加逐渐接近一致激励情况。     

场地地震反应分析中侧向人工边界距离选取及影响因素分析

结合均匀场地模型和分层均匀场地模型,采用数值试验的方法研究了场地地震反应分析中侧向人工边界距离的选取问题。分析了各主要因素对人工边界距离选取的影响,得到了如下结论:单侧人工边界距离与土层深度之比L/h是影响人工边界距离选取的主要参数;随着侧向人工边界距离的增加,有限元模型的计算误差并不一直减小,在局部范围内,会出现计算误差随着边界距离的增加而增大的现象;场地硬度、阻尼比和激振频率等因素不会影响计算误差随边界距离的变化规律,但采用自由场边界时受输入地震动频谱特性的影响较为明显;对水平激振下的一维场地模型来说,采用结合自由度边界时所需边界距离最短,自由场边界次之,采用粘性边界达到收敛时所需边界距离最长;无论哪种边界条件,当边界距离大于某一范围后,都能得到稳定的计算结果;相对于均质场地模型来说,实际的分层均匀场地建模时可适当减小侧向人工边界距离。     

Dynamic interaction of bridge–train system under non‐uniform seismic ground motion

The probability that an earthquake occurs when a train is running over a bridge in earthquake‐prone regions is much higher than before, for high‐speed railway lines are rapidly developed to connect major cities worldwide. This paper presents a finite element method‐based framework for dynamic analysis of coupled bridge–train systems under non‐uniform seismic ground motion, in which rail–wheel interactions and possible separations between wheels and rails are taken into consideration. The governing equations of motion of the coupled bridge–train system are established in an absolute coordinate system. Without considering the decomposition of seismic responses into pseudo‐static and inertia‐dynamic components, the equations of motion of the coupled system are formed in terms of displacement seismic ground motions. The mode superposition method is applied to the bridge structure to make the problem manageable while the Newmark‐β method with an iterative computation scheme is used to find the best solution for the problem concerned. Eight high‐speed trains running over a multi‐span steel truss‐arch bridge subject to earthquakes are taken as a case study. The results from the case study demonstrate that the spatial variation of seismic ground motion affects dynamic responses of the bridge–train system. The ignorance of pseudo‐static component when using acceleration seismic ground motions as input may underestimate seismic responses of the bridge–train system. The probability of separation between wheels and rails becomes higher with increasing train speed. Copyright © 2011 John Wiley & Sons, Ltd.     

Probability field for the post-processing of stochastic simulations

A combination of factorial kriging and probability field simulation is proposed to correct realizations resulting from any simulation algorithm for either too high nugget effect (noise) or poor histogram reproduction. First, a factorial kriging is done to filter out the noise from the noisy realization. Second, the uniform scores of the filtered realization are used as probability field to sample the local probability distributions conditional to the same dataset used to generate the original realization. This second step allows to restore the data variance. The result is a corrected realization which reproduces better target variogram and histogram models, yet honoring the conditioning data.     

GNSS控制网坐标移动转换的三次曲面拟合法

针对2000国家大地坐标到海南独立坐标系需要保密参数的局限性,该文利用三次曲面拟合坐标移动转换法进行2000国家大地坐标系到海南独立坐标转换,解决了在没有海南独立坐标系参数的情况下无法进行坐标转换的困扰,确保参数保密性。测试比较结果表明,三次曲面拟合法移动坐标转换法能够提高坐标转换精度。     

分层均匀介质折射率廓线的重建

依据电磁逆散射理论，由频域的反射系数或时域的反射脉冲重建分层均匀介质折射率廓线。采用非线性重整化技术对利卡提方程进行化简，并由此导出反射脉冲与折射率廓线分布函数之间的关系。数值模拟结果表明，用非线性重整化技术重建折射率廓线具有物理图象清晰、精度高、抗噪声干扰及简便快捷的优点。