BDS网络RTK参考站三频整周模糊度解算方法

北斗卫星导航系统是目前唯一一个全星座提供三频观测数据的卫星导航定位系统,三频观测值有助于载波相位整周模糊度的快速、准确固定。本文提出了一种BDS网络RTK参考站三频整周模糊度解算方法。首先利用B2、B3频率的观测值及严格的模糊度固定标准确定超宽巷整周模糊度,将固定的超宽巷整周模糊度与其他宽巷整周模糊度的线性关系作为约束条件,然后估计宽巷整周模糊度、相对天顶对流层延迟误差和电离层延迟误差,并搜索确定宽巷整周模糊度。利用固定的宽巷整周模糊度与三频载波相位整周模糊度的整数线性关系,将线性关系加入载波相位整周模糊度参数估计观测模型中,然后确定载波相位整周模糊度。使用实测的CORS网BDS三频观测数据进行算法验证,结果表明,该方法可正确有效地实现参考站间三频载波相位整周模糊度的快速解算。     

不同因素下的ZTD端部效应影响分析

任何平滑拟合方法对实际资料处理时均会产生端部效应,即处理结果在资料(弧)段的两端精度较差,端部效应问题,已成为区域GPS气象网准实时PWV(可降水量)解算的重要问题之一。Bernese数据处理软件在解算对流层天顶延迟方面独树一帜,以中国境内和其周边共5个IGS站2012年某天的数据为解算实例,在简要介绍Bernese解算对流层产品的基础上,采用单一变量的原则,研究分析不同截止高度角和时间分辨率对数据处理结果的端部效应影响和误差量级,并给出参考性建议。     

顾及大气延迟误差的中长基线RTK算法

针对常规RTK作业距离一般不超过15km的问题,提出了一种顾及大气延迟误差的中长基线RTK的算法,突破了常规RTK作业距离。在中长基线情况下,与大气延迟有关的误差如电离层延迟误差、对流层延迟误差等,随着基线长度的增加,空间相关性大大降低,进而影响整周模糊度的快速解算。基于卡尔曼滤波算法,采用非组合差分定位模型,对于电离层延迟误差采用了电离层加权模型进行估计,对于对流层延迟分别采用了相对对流层延迟参数估计和绝对天顶对流层参数估计。最终通过实测数据对该算法进行了算法验证和结果分析。试验结果表明:该算法可以实现中长基线RTK的快速解算,并且在估计相对对流层延迟时,绝对天顶对流层参数估计不利于基准站和流动站的对流层延迟分离,一般采用估计流动站上的相对对流层延迟。     

Formulation and Evaluation of IMS, an Interactive Three-Dimensional Tropospheric Chemical Transport Model 3. Comparison of Modelled C2–C5 Hydrocarbons with Surface Measurements

In part 3 of this series of papers on a new 3-D global troposphericchemical transport model, using an Integrated Modelling System (IMS), anevaluation of the model performance in simulating global distributions andseasonal variations for volatile organic compounds (VOCs) in the atmosphere,is presented. Comparisons of model OH concentrations with previous modelstudies show consistent modelled OH levels from the subtropics tomidlatitudes, while more discrepancies occur over the tropical lowlatitudes, with IMS predicting the highest levels of OH. The close agreementbetween modelled OH concentrations over midlatitudes, where high surfaceNO_xand VOC concentrations are also found, is indicative of the strongphotochemical coupling between NO_x, VOCs and O₃ overthese latitudes. IMSOH concentrations in the Northern Hemisphere (NH) midlatitudes during summerare generally lower than available measurements, implying that models ingeneral are underestimating OH levels at this location and time of year.Substantial differences between model OH concentrations over low latitudesclearly highlight areas of uncertainty between models. IMS OH concentrationsare the highest in general of the models compared, one possible reason isthat biogenic emissions of species such as isoprene and monoterpenes arehighest in IMS, leading to higher O₃ levels and hence higher OH.Generally, the IMS VOC concentrations show a similar seasonality to themeasurements at most locations. In general though, IMS tends to underestimatethe NH wintertime VOC maximum and overestimate the NH summertime VOCminimum. Such an overestimate in summer could be due to IMSunderestimating OH levels, or an overestimation of VOC emissions or possiblya problem with model transport, all of these possibilities are explored.Except for n-pentane, the model underprediction of a VOC maximum during theNH winter month strongly suggests a missing emission mechanism in the modelor an underestimate of an existing one. It is very likely that there is alack of time varying emission sources in the model to account for theseasonal change in emission behaviour such as increasing energy usage (e.g.,electricity and gas), road transportation, engine performance, and otheranthropogenic factors which show strong seasonal characteristics. Theanomalous overprediction of wintertime n-pentane compared with its closesummertime prediction with the measurements suggest that emissions in thiscase may be too high.     

对流层传播延迟改正

介绍了流层大气折射对GPS信息的影响及修正方法，着重讨论了各种天顶延迟计算方法和投影函数模型；通过试算，并分析比较这些模型的差异，得出了一些有益的结果。     

Extrinsic and intrinsic mode of hydrogen occurrence in natural olivines: FTIR and TEM investigation

Olivine crystals from two mantle nodules in kimberlites (pipe Udachnaya and pipe Obnazennaya, Yakutiya, Siberia) were investigated using EMP, TEM, AEM and FTIR techniques to determine the mode of hydrogen occurrence in olivine. Olivine contains three types of nanometer-sized inclusions: “large” inclusions of hexagonal-like shape up to several hundred nm in size (1), lamellar defects (2) and small inclusions of hexagon-like shape up to several 10?nm in size (3). Lamellar defects and small inclusions are considered to be a “hydrous” olivine. All three types of inclusions contain OH^? or water, but they are different with respect to their phase composition. In “large” inclusions (1) hydrous magnesium silicates, such as serpentine?+?talc (“kerolite”?) and 10-Å phase?+?talc were identified. Lamellar defects (2) and small inclusions (3) are depleted in Mg and Fe compared to the olivine matrix, while the silica content is the same as that of olivine. Modulations in the periodicity of the olivine structure are observed in SAED patterns and HREM images of (2) and (3). The superperiodicity can be referred to OH^?-bearing point defect ordering in the olivine structure. If this is the case, the material of both lamellar defects and small inclusions can be assumed to be a “hydrous olivine” Mg_{2– x} v _x SiO₄H_{2 x} with a cation-deficient olivine crystal structure. Thus, both an extrinsic mode of hydrogen occurrence in olivine, such as nanometer-sized inclusions of OH^?-bearing magnesium silicates, and an intrinsic mode of hydrogen incorporation into the olivine structure, such as “hydrous olivine” in itself, were found. The data obtained here show that the OH absorption bands observed in olivine spectra at 3704(3717) and 3683(3688) cm^?1 can be unambiguously identified with serpentine; the band at 3677(3676) cm^?1 can be associated with talc. The absorption bands observed at 3591 and 3660?cm^?1 in olivine match those of the 10-Å phase at 3594, 3662 and 3666?cm^?1.     

Chemical reactions and transport of alkanes and their products in the troposphere

The product distributions have been calculated for more abundant alkanes contributing most of the carbon atoms in the alkane fraction of an ambient air hydrocarbon mixture reasonably representative of U.S. emissions. The effects of ambient temperatures on product yields has been calculated for a range of temperatures from 250 to 330 K. The sensitivity of product yields to uncertainties in alkoxy radical process rate constants has been examined with emphasis on uncertainties in decomposition reactions. Chemical lifetimes are estimated at 300 K under summertime conditions for hydrocarbons and for products of alkane photooxidation in the atmosphere. The atmospheric distribution of alkanes and products is evaluated in terms of the extent to which reaction processes are likely to occur in the planetary boundary layer compared to the free troposphere.The calculations predict a substantial effect of temperature on product yields. A large decrease in alkyl nitrate yields and a smaller decrease in ketone yields occur with increasing temperature. The yields of the short-lived, more reactive aldehydes undergo substantial increases with increasing temperature. Lower yields of ketones and higher yields of aldehydes are associated with the use of higher compared to lower decomposition process rate constants. For the type of U.S. hydrocarbon mixture available from measurements, 16 oxygenated products account for more than 60% of the total alkane carbon atoms converted to products, with most of these carbon atoms accounted for by four products. The effects of increased temperature on product reactivity and radical production may also influence O₃ production.     

边界层微型火箭气象探空系统研制与应用

首次介绍了国内自主研制的边界层微型火箭气象探空系统,系统包括火箭发射装置、探空仪、降落伞、地基接收设备和数据接收处理软件,其温度、湿度和气压测量采用数字式传感器,风速和风向由北斗/GPS全球定位信息获得。火箭升空至顶点后,将探空仪和降落伞从仪器舱弹出,在下降过程中测量大气的温度、湿度、气压和风速、风向等参数,通过无线发射机传送至地面接收机,由处理软件实现数据存储和参数分析。不同地区、不同气象条件下多次外场比较试验和实际应用结果表明,该系统性能稳定,探测技术指标和功能满足使用单位的设备研制要求,可应用于气象保障、大气探测、环境监测及海洋气象要素廓线的观测。     

Estimating product yields of carbon-containing products from the atmospheric photooxidation of ambient air alkenes

The yields of products have been calculated for the reactions of hydroxyl radicals and ozone with 19 of the two-through-six carbon anthropogenic alkenes. Based on their rate of reaction, mechanisms of reactions and the ambient air distribution for these alkenes their seasonal ambient air yields have been estimated.Aldehydes predominate as products irrespective of season, with smaller yields of several ketones. Other minor products include carboxylic acids, carbon monoxide, carbon dioxide, and alkenes. About a two-fold increase is estimated in the yields of hot biradicals and their products from summer to winter.One sensitivity analysis was made by recomputing yields at a different OH radical to O₃ concentration than assumed most likely in the calculations discussed above. In addition, the sensitivity of product yields to an estimated range of seasonally averaged sunset-to-sunrise NO₃ radical concentrations was calculated. The effects of free radical reactions are discussed, but these are believed to make a relatively minor contribution within the NO _x -rich atmospheres that contain anthropogenic alkenes.The uncertainties in product yields associated with the range of NO₃ radical concentrations assumed present is relatively small for aldehydes, as is the decrease in yield of the one carbon hot biradical. Larger uncertainties occur for ketones. Significant decreases in yields occur for larger hot biradicals, especially the branched-chain hot radicals in the presence of NO₃ radicals.     

The OH Maser Line Receiving System for the Urumqi 25m Radio Telescope

A maser spectral line system is newly implemented on the Urumqi 25m Radio Telescope. The system consists mainly of a cooling receiver and a 4096 channels digital correlation spectrometer. The frequency resolution of the spectrometer at the maximum signal bandwidth of 80MHz is 19.5kHz. After careful calibrations observation at the 1665 MHz OH maser emission was made towards a number of sources, including W49N and W75N. The observed results demonstrate that the digital correlation spectrometer is suitable for astronomical spectral line observations.