Seasonal and interannual variations of upper tropospheric water vapor band brightness temperature over the global monsoon regions

The upper-troposphere water vapor (UTWV) band brightness temperature (BT) dataset derived from the High-resolution Infrared Radiation Sounder (HIRS) channel 12 of the National Oceanic and Atmospheric Admini-stration (NOAA) polar satellites from 1979 to 1995 is used to analyze the seasonal and interannual variations for the global monsoon regions. Results show that (i) there are three major regions where the UTWV band BT varies significantly with season, i.e., South Asia, the western coastal South-North America tropical region and the low-lati-tude African region; (ii) UTWV band BT clearly reveals the water vapor temporal / spatial features as well as the at-mospheric circulation structure over the low-latitude during the monsoon onset; and (iii) there is a remarkable rela-tionship between the interannua] variation of the UTWV band BT over the monsoon regions and the sea surface tem-perature anomaly in the eastern equatorial Pacific.     

Mechanistic and Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Cyclohexanone using an Absolute and a Relative Technique; Influence of Temperature

The reaction of Cl with cyclohexanone (1) was investigated, for the first time, as a function of temperature (273–333 K) and at a low total pressure (1 Torr) with helium as a carrier gas using a discharge flow-mass spectrometry technique (DF-MS). The resulting Arrhenius expression is proposed, k ₁= (7.7 ± 4.1) × 10^–10 exp[–(540 ± 169)/T]. We also report a mechanistic study with the quantitative determination of the products of the reaction of Cl with cyclohexanone. The absolute rate constant derived from this study at 1 Torr of total pressure and room temperature is (1.3 ± 0.2) × 10^–10 cm³ molecule^–1 s^–1. A yield of 0.94 ± 0.10 was found for the H-abstraction channel giving HCl. In relative studies, using a newly constructed relative rate system, the decay of cyclohexanone was followed by gas chromatography coupled with flame-ionisation detection. These relative measurements were performed at atmospheric pressure with synthetic air and room temperature. Rate constant measured using the relative method for reaction (1) is: (1.7 ± 0.3) × 10^–10 cm³ molecule^–1 s^–1. Finally, results and atmospheric implications are discussed and compared with the reactivity with OH radicals.     

The photochemistry of synoptic-scale ozone synthesis: Implications for the global tropospheric ozone budget

The oxidation of nonmethane hydrocarbons represents a source of tropospheric ozone that is primarily confined to the boundary layers of several highly industrialized regions. (Each region has an area greater than one million km²). Using a photochemical model, the global tropospheric ozone budget is reexamined by including the in-situ production from these localized regimes. The results from these calculations suggest that the net source due to this photochemistry, which takes place on the synoptic scale, is approximately as large as the amount calculated for global scale photochemical processes which consider only the oxidation of methane and carbon monoxide. Such a finding may have a considerable impact on our understanding of the tropospheric ozone budget. The model results for ozone show reasonable agreement with the climatological summer distribution of ozone and the oxides of nitrogen at the surface and with the vertical distribution of ozone and nonmethane hydrocarbons obtained during a 1980 field program.     

Nonmethane hydrocarbons in an oceanic atmosphere

C₂–C₆ Nonmethane hydrocarbons (NMHC) and radioactive continental tracers were measured during two oceanographic cruises, in June 1982 in the Mediterranean and Red Sea, and in November 1982 across the North Atlantic and South Pacific oceans. Typical concentrations in marine atmosphere are between 0.05 and 0.2 ppbv. Owing to their similar lifetimes, propane and radon-222 are found to be well correlated. This relationship establishes that propane is mainly produced over lands and enables us to estimate its continental source strength at about 60×10⁶ tons of carbon per year.Also at Université de Picardie     

Photochemical aspects of tropospheric iodine behaviour

The I-atom sensitised decomposition of ozone in air at 1 atm pressure and ambient temperature has been investigated. Iodine atoms were produced by photolysis of I₂ using visible light or of CH₃I using ultraviolet light. In both cases, the quantum yield for O₃ decomposition was 1.25 (±0.11) per I atom. An important role is proposed for the self-reaction of IO radicals leading to higher oxides of iodine, IO+IO(+M)I₂O₂(+M)higher oxides, which predominated over the bimolecular reaction leading to regeneration of I atoms, IO+IO2I+O₂, with k _2a/k _2b4. Simple computer modelling calculations indicate that reaction (2a) may be important in determining the fate of photolabile iodine species in the atmosphere. The consequences for the behaviour of radioiodine releases are also discussed.     

测站气温与气压对GPS定位结果的影响

分别利用全球气压气温模型GPT和GPT2处理相同的连续观测站数据。对比两组测站位置估值（简称位置）发现,测站气压偏差所导致的先验天顶延迟偏差不能完全被延迟参数所吸收,导致测站垂向位置出现偏差,且偏差的大小与测站纬度及数据处理中所采用的数据权重有关。测站气温偏差对测站位置的影响可忽略不计,但GPS定位结果的内符合精度随着测站气温的升高而降低。     

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