Nitrogen and Oxygen Isotope Balance in Tropospheric N2O—An Improved Budget

In steady state the stable isotopic composition of nitrogen and oxygen in tropospheric N2O is balanced by isotopically light N2O emitted from soils and oceans and isotopically heavy N2O as a return flux from the stratosphere.However,no such balance was reached in calculations given by Kim and Caig(1993).Modifications have been made on their calculations based on the most recent reports on annual global emission of N2O.It is considered that the nitrogen and oxygen isotope budget in tropospheric N2O are approximately in balance if isotopic fractionation effects during the production of N2O in soils and furthermore this paper puts forward further evidence for validating the above results.     

The Role of In Situ Photochemistry in the Control of Ozone during Spring at the Jungfraujoch (3,580 m asl) – Comparison of Model Results with Measurements

A photochemical box model has been used to model themeasured diurnal ozone cycle in spring at Jungfraujochin the Swiss Alps. The comparison of the modelleddiurnal ozone cycle with the mean measured diurnalozone cycle in spring, over the period 1988–1996,shows a good agreement both with regard to the shapeand amplitude. Ozone concentrations increase duringthe daytime and reach a maximum at about 16:00–17:00(GMT) in both the modelled and the mean observed ozonecycle, indicative of net ozone production during thedaytime at Jungfraujoch in spring. The agreement isbetter when the modelled ozone cycle is compared withthe mean measured diurnal cycle (1988–1996) filteredfor north-westerly winds >5 m/s (representative ofregional background conditions at Jungfraujoch). Inaddition to ozone, the modelled diurnal cycle of[HO₂] + [CH₃O₂] also shows rather goodagreement with the mean diurnal cycle of the peroxyradicals measured during FREETEX '96, a FREETropopsheric Experiment at Jungfraujoch in April/May1996. Furthermore, this mean diurnal cycle of the sumof the peroxy radicals measured during FREETEX '96 isused to calculate, using steady-state expressions, therespective diurnal cycle of the OH radical. Thecomparison of the OH diurnal cycle, calculated fromthe peroxy radical measurements during FREETEX '96,with the modelled one, reveals also good agreement.The net ozone production rate during the day-time is0.27 ppbv h^-1 from the model, and 0.13 ppbvh^-1 from the observations during FREETEX '96. Theobservations and model results both suggest that thediurnal ozone variation in spring at Jungfraujoch isprimarily of photochemical origin. Furthermore, theobserved and modelled positive net ozone productionrates imply that tropospheric in situphotochemistry contributes significantly to theobserved high spring ozone values in the observedbroad spring-summer ozone maximum at Jungfraujoch.     

A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone

A study of the oxidation mechanism of N-methyl pyrrolidinone (C₅H₉NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of cm³ molecule ^{− 1} s^{− 1}): k_NMP = (2.2 ± 0.4) × 10^{− 11}, k_NMS = (1.4 ± 0.3) × 10^{− 12} and k_FP = (6 ± 1) × 10^{− 12}. The results are presented and discussed in terms of the atmospheric impact.     

Distribution,speciation, and budget of atmospheric mercury

Total gaseous mercury (TGM) concentrations over the Atlantic Ocean and over Central Europe were measured repeatedly in the years 1978–1981. The latitudinal TGM distribution showed a pronounced and reproducible interhemispherical difference with higher TGM concentrations in the Northern Hemisphere. TGM was found to be vertically well mixed within the troposphere. The TGM concentration seems to increase with time at a rate of 10±8%/yr in the Northern and 8±3%/yr in the Southern Hemisphere. Measurements of mercury speciation showed that elemental mercury is the main TGM component contributing more than 92% and 83% of TGM in marine and continental air, respectively. The tropospheric mercury burden was calculated to be 6×10⁹g. The interhemispheric distribution and temporal and spatial variability of TGM imply a tropospheric residence time of TGM of about 1 yr. Sink strengths calculated independently from the measured mercury concentration on particles and in rainwater are consistent with the above figures.     

Global features of upper-tropospheric zonal wind and thermal fields during anomalous monsoon situations

Global analyses of mean monthly zonal wind component and temperature at 200, 150 and 100 mb levels have been made for the region between 60°N and 60°S, for the months May through September during two poor monsoon years (1972 and 1979) and a good monsoon year (1975). Prominent and consistent contrasting features of the zonal wind and thermal fields have been identified, with reference to the monsoon performance over India. It has been noticed that the areal spreading of easterlies over the tropics and extratropics is significantly more during a good monsoon year. Shifting of the axis of the tropical easterly jet stream to a higher level and generally stronger easterlies also characterize good monsoon activity. The upper troposphere has been found to be considerably cooler during poor monsoon years.     

夏季南亚高压对流层中上层异常暖中心时空分布特征及其激发的大气波动

利用1979年1月至2016年12月ERA-interim月平均再分析资料和CAMP全球月降水资料,分析夏季（6—8月）南亚高压下方500 hPa到100 hPa暖中心的时空分布,从三维结构来揭示夏季南亚高压暖心特征.回归分析进一步探讨青藏高原上空暖中心对全球大气环流产生的可能影响.结果表明：南亚高压在150 hPa达到最强,这一层也是异常冷暖中心分界面,150 hPa以下有一强大异常暖中心,异常暖中心位于300 hPa附近,150 hPa以上为异常冷中心,中心位置位于70 hPa附近.异常暖中心从500 hPa向上逐渐向西向北倾斜,异常暖中心面积200 hPa达最大,150 hPa异常暖中心消失,100 hPa以上转变为异常冷中心.500~200 hPa异常暖中心表现出不断增暖的长期趋势（1979—2016）,100 hPa异常冷中心则表现出不断变冷的长期趋势（1979—2016）.去掉长期趋势的时间序列表现出明显的"准两年振荡"特征,异常暖中心位置在纬向上较稳定,在经向上表现出年际的"东西振荡".300 hPa异常暖中心是整个南亚高压的关键层.300 hPa异常暖中心对全球其他变量场进行回归分析.高度回归场表明,青藏高原上空异常暖中心在北半球中高纬度高度场上激发出3波的行星波,波特征在对流层中上层表现明显,波振幅随高度增高不断加强,在对流层中下层逐渐减弱并消失.纬向风回归场在对流层中上层表现出横跨南北半球的波列,这个波列在200 hPa振幅最大.经向风回归场在北半球中纬度（30°N—60°N）表现出7波型,说明南北能量交换频繁.降水回归场表明,东亚地区长江中下游至日本降水偏少,而其南北两侧降水偏多.     

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热带平流层与对流层之间相互作用的研究进展

以热带平流层和对流层大气中的准两年振荡和ENSO现象,以及热带平流层和对流层交换（STE）过程为主轴,介绍了热带平流层和对流层大气相互作用方面的一些研究进展。众多的研究结果表明,平流层准两年振荡（QBO）和对流层准两年振荡（TBO）存在潜在联系,但二者之间相互作用的物理机制还不是很清晰。QBO对平流层大气中化学成分的空间分布具有显著的影响,但其中的化学-辐射-动力反馈作用目前还未得到充分的研究。以往的研究提供了ENSO影响热带平流层大气令人信服的证据,但影响的程度和范围还未形成一个共识,其中一个原因是平流层内的ENSO信号受到火山喷发和太阳活动的干扰。一些研究指出ENSO事件通过改变行星波的强度和传播对极地平流层大气产生影响,而平流层过程也会对ENSO的发生、发展和演变产生影响,但其可靠性需要进一步的确证。目前,一个较一致的结论是全球变暖会导致热带上涌增强,STE加快。然而,影响热带STE的大气过程较多,特别是季风系统和热带深对流系统对STE的贡献还需要深入的分析研究。      

我国高空风速的气候学特征

利用全国119个探空站1980~2006年13个等压面和地面附近的月平均风速资料,分析了不同高度年、季节平均风速的气候学特征。结果表明,全国平均200hPa以下风速随高度增加而增加,200hPa~30hPa之间风速随高度增加而降低,30hPa以上风速随高度增加而再呈增加趋势;春、秋季平均风速随高度变化与年平均相似,但冬、夏季的垂直分布差异明显;700hPa及其以上最大风速出现在1月,最小风速在7月或8月;850hPa和地面最大风速发生在4月;对流层风速年较差从下向上增加,在200hPa附近风速年较差最大。我国地面风速在东、西部地区较大,中部地区较小;500hPa年平均风速分布呈西低东高态势,最大中心出现在辽东半岛东部;200hPa年平均风速在江淮地区出现高值中心;500hPa冬季最大风速区在大陆南部,夏季北移并向西扩展;200hPa各季强风速区基本呈东西走向的带状分布,其中春季在江淮地区,夏季移至西北,秋季位于黄淮地区,冬季位置最南。     

Radiosonde observations of high-latitude planetary waves in the lower atmosphere

The characteristics of high-latitude planetary waves (PWs) in the troposphere and lower stratosphere (TLS) are studied by using the data from radiosonde observations during 1998 to 2006 at three Alaskan stations in USA (Nome, 64.50°N, 165.43°W; McGrath, 62.97°N, 155.62°W; Fairbanks, 64.82°N, 147.87°W). It is found that strong PWs exist in two regions. One is around tropopause, and the other is in the polar night jet (PNJ) in winter. The PW activities are rather intermittent, and their lifetimes are no longe...