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111.
氢气被认为是反应断裂活动最灵敏的地球化学组分之一。研究影响断裂带氢浓度动态变化的主要因素,是科学分析断裂带氢与构造活动关系的基础工作。本文基于河南内乡马山口断层气氢气浓度与辅助测项的连续观测资料,重点分析了氢浓度变化与地温、气温、气压的相关关系,确定了主要影响因素。结果表明,氢气浓度日变化极值介于气温和地温之间,极值点靠近地温一侧。使用逐步回归方法分析进一步证明,地温、温度对氢气浓度均有影响,但地温影响更显著,气压影响不显著。总体来讲,氢浓度会受到地温和气温的双重影响,但与地温关系更为密切。 相似文献
112.
N. Sultan M. Voisset T. Marsset A.M. Vernant E. Cauquil J.L. Colliat V. Curinier 《Marine Geology》2007,240(1-4):235-255
We present a new method to characterize free gas, gas hydrates and carbonate concretions occurrence which are considered as high-risk factors for sub-sea developments in the Niger delta. This method is based on the combination of 3D seismic data to the geotechnical site characterizations using piezocone CPTU tests (Cone Penetration Test with additional measurement of the pore water pressure). A special processing of the 3D seismic data has enabled the determination of the interval compressional velocity. Using the effective-medium theory, velocity anomalies (negative and positive) within the first 15 m were translated in gas hydrate and free gas distribution. The calibration of the P wave velocity anomalies was done thanks to in-situ geotechnical testing carried out during two oceanographic surveys (2003 and 2004). Comparison between in-situ testing, recovered cores and the prediction of the gas and the gas hydrate distribution based on the compressional wave velocity have shown that 3D seismic data is a valuable tool to identify heterogeneous areas but the use of the piezocone was essential to discriminate between gas hydrate occurrences and carbonate concretions' presence. Furthermore, in-situ compressional wave velocity (Vp) measurements have clearly demonstrated what it was suspected from the 3D seismic data, the co-existence in the study area between gas hydrate and free gas. 相似文献
113.
本研究利用吸收光谱和荧光激发-发射矩阵光谱-平行因子分析(EEMs-PARAFAC),研究了养马岛附近海域海水中有色溶解有机质(CDOM)的浓度、组成、来源和生物可利用性,并估算了浮游植物生长繁殖对CDOM及具有生物可利用性CDOM的贡献。结果表明,表、底层海水中CDOM浓度(以吸收系数a350计)平均值分别为1.62±0.42 m-1和1.30±0.47 m-1,光谱斜率(S275-295)平均值分别为0.022±0.003 nm-1和0.023±0.003 nm-1。利用PARAFAC模型识别出4种荧光组分,分别为陆源类腐殖酸C1、类色氨酸C2、类酪氨酸C3和微生物源类腐殖酸C4。荧光指数(FIX)、腐殖化指数(HIX)和生物指数(BIX)显示,CDOM受陆源输入和海洋自生源的综合影响。降解实验结果显示,表、底层海水中生物可利用性CDOM百分比(%△a350)平均值分别为(23.36%±17.94%)和(8.93%±20.30%)。C1、C2和C4组分的荧光强度在培养之后降低,而C3组分的荧光强度上升。各荧光组分生物可利用性依次递减的顺序为:%△C1(23.75%±8.96%)>%△C4(20.83%±11.71%)>%△C2(11.67%±38.87%)>%△C3(-29.61%±39.90%),显示培养之后CDOM的平均分子量和腐殖化程度降低。表层海水中a350、%△a350与Chl a之间存在显著线性相关关系,据此可以估算出浮游植物生长繁殖对CDOM的贡献为36.9%,对具有生物可利用性CDOM的贡献为85.0%。 相似文献
114.
为了研究近岸海带养殖活动对水体光学特性的影响,本文选取山东半岛黑泥湾海域为典型研究区,利用2021年4月和8月在该区的9站同步观测数据,分析其总悬浮颗粒物、藻类颗粒物、非藻类颗粒物以及有色溶解有机物的吸收特性,并计算各组分对总吸收系数的贡献率,同时采用Quasi-analytical algorithm (QAA)算法借助MODIS影像反演了水体总吸收系数,结合实测数据获得了黑泥湾水体吸收特性的季节变化情况。结果表明,有海带养殖季节表层水体藻类颗粒物、非藻类颗粒物、总颗粒物和有色溶解有机物的吸收系数明显大于无海带养殖季节,且春季海带养殖区水体的总吸收系数大于无海带养殖区;海底表层沉积物的再悬浮造成底层吸收系数较大,而在春季成熟期的海带汇聚较大量的有机物质导致中层藻类颗粒物吸收系数相对较高;参考波长向红波移动,QAA_v5算法能够较好地估算该区表层水体吸收系数,且在海带养殖季节水体组分会影响到更长的波段特征。本研究可为深入了解海带养殖对水体各组分浓度和分布、碳循环以及水生生态系统的结构和功能的影响提供参照,并有助于提高近岸水体组分的遥感反演精度。 相似文献
115.
116.
117.
南海北部藻类粒级结构及色素成分对浮游植物吸收系数的影响 总被引:2,自引:0,他引:2
在珠江口、广东沿岸及南海北部三个航次生物-光学数据的基础上,研究了色素打包效应和色素成分的变化对浮游植物吸收系数的影响,结果表明,两种因素对吸收系数都有较大的贡献,但在不同的水体它们的影响程度各有不同.对网采浮游植物含量较高的珠江口和广东沿岸的水体而言,色素打包效应较强,对675 nm处比吸收系数的贡献平均分别为40%和20%;对微型浮游植物占主导地位的南海北部航次的水体,打包效应较弱,对675 nm处比吸收系数的影响平均仅为6%.采用多元线性回归的方法对吸收光谱进行分析,发现除叶绿素a之外的辅助色素对吸收系数的贡献主要表现在蓝绿光波段,三个航次440 nm波长处对总吸收的贡献平均分别为44%,43%和53%,其中对珠江口和广东沿岸航次的水体主要是光合类胡萝卜素的吸收贡献,而对南海北部航次的水体除了光合类胡萝卜素以外还要受到光保护类胡萝卜素的影响.由于河口、近岸和外海水体藻类粒级结构和辅助色素成分对浮游植物吸收系数的贡献有明显的差异,在南海北部水体建立比较精确的生物光学模型时,需考虑藻类粒级结构及色素成分对浮游植物吸收系数的影响. 相似文献
118.
Spatial and seasonal variations in depth profile of trace metals in saltmarsh sediments from Sapelo Island, Georgia, USA 总被引:1,自引:0,他引:1
This study was undertaken to elucidate the impact of early diagenetic processes on the accumulation of trace metals in Sapelo Island saltmarsh sediments as a function of time, space and sediment properties. Samples were collected from three sites in summer (May 1997) and winter (January 1998) along a transect from an unvegetated Creek Bank through a vegetated Tidal Levee to the vegetated midmarsh with evident lateral heterogeneity caused by hydrologic regime, macrophytes and microbial and macrofaunal activities. A suite of trace metals (As, Ba, Cr, Co, Cu, Cd, Mo, Ni, Pb, Th, Ti, U, V, Zn and Zr) was analyzed to obtain their depth-distribution at the three sites. Spatially marked differences were observed, that were primarily related to hydraulic flushing of trace metals away from the sites in high-energy regimes, rapid downward mixing and reworking of sediment via bioturbation, and below-ground degradation and production of Spartina biomass. Although sulfate reduction and the formation of acid volatile sulfide and pyrite were dominant processes throughout the marsh, the trace metal scavenging role of sulfides was not apparent. However, possible sulfurization of organic matter, leading to enhanced trapping of trace metals with organic carbon, may have played an important role in sequestration of trace metals.No similarity was observed visually between the depth trends of trace metals and sediment properties (grain size, iron-oxyhydroxide content, acid volatile sulfides and pyrite content) that are known to play a major role in trace metal partitioning. Only organic carbon content closely followed the trace metal profiles at all the three sites. Minor variation in depth-integrated sediment trace metal content was observed seasonally at each of the three sites. Furthermore, the depth trend of profiles of individual trace metals also did not vary significantly over the seasons either. 相似文献
119.
A multidisciplinary study in the Gulf of Cadiz is revisited, using additional diagnostic modelling tools. The dissolved trace metal (Cu, Ni, Zn, Co) distributions in the Gulf of Cadiz are analysed using modelled tracer evolutions, field observations and the concept of tracer ages. This study shows that a significant part of the observed metal distributions can be explained by the metal inputs of three river systems (Guadiana, Rio Tinto and Odiel, Guadalquivir) discharging into the Gulf of Cadiz, while the remainder of the signal is most likely associated with the benthic metal remobilisation along the shelf of this coastal region. 相似文献
120.
Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia 总被引:1,自引:0,他引:1
Christophe Migon Sylvain Ouillon Xavier Mari Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756
Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L−1), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L−1 near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources. 相似文献