河南赵岭构造蚀变岩型金矿床微量元素地球化学特征

赵岭金矿床是典型的受构造控制的构造蚀变岩型金矿床,位于外方山断隆与旧县-大章断陷盆地结合部位的东部.构造活动的多期性形成了构造岩的复杂性.脉动式、幔涌式的成矿作用导致金矿体在走向上、倾向上都具侧列再现、相互叠加等组合特征.每一次的脉动和幔涌形成的金矿体都表现了各自的地球化学特征和元素组合特征,成矿微量元素在垂向上具有各自的规律性.为本区的地质找矿提供了一个明显的找矿标志.     

会泽铅锌矿床中自然锑的发现及伴生元素的分布特征

文章对会泽铅锌矿床的主要矿体进行了系统观察、采样，对其矿石进行了岩矿鉴定、化学分析(包括部分单矿物)和电子探针分析，并对其成矿作用做了探讨。首次在矿石中发现了自然锑，初步查明整个矿床中Ag，Cd，Ge，Cu，Sb等伴生元素的平均含量(wB／10^-6)分别为121．77、660．99、62．10、203．78和169．87，认为它们是晚成矿阶段形成的。     

Modeling forced pool–riffle hydraulics in a boulder-bed stream, southern California

The mechanisms which control the formation and maintenance of pool–riffles are fundamental aspects of channel form and process. Most of the previous investigations on pool–riffle sequences have focused on alluvial rivers, and relatively few exist on the maintenance of these bedforms in boulder-bed channels. Here, we use a high-resolution two-dimensional flow model to investigate the interactions among large roughness elements, channel hydraulics, and the maintenance of a forced pool–riffle sequence in a boulder-bed stream. Model output indicates that at low discharge, a peak zone of shear stress and velocity occurs over the riffle. At or near bankfull discharge, the peak in velocity and shear stress is found at the pool head because of strong flow convergence created by large roughness elements. The strength of flow convergence is enhanced during model simulations of bankfull flow, resulting in a narrow, high velocity core that is translated through the pool head and pool center. The jet is strengthened by a backwater effect upstream of the constriction and the development of an eddy zone on the lee side of the boulder. The extent of flow convergence and divergence is quantified by identifying the effective width, defined here as the width which conveys 90% of the highest modeled velocities. At low flow, the ratio of effective width between the pool and riffle is roughly 1:1, indicating little flow convergence or divergence. At bankfull discharge, the ratio of effective width is approximately 1:3 between the pool and downstream riffle, illustrating the strong flow convergence at the pool head. The effective width tends to equalize again with a ratio of 1:1 between the pool and riffle during a modeled discharge of a five-year flood, as the large roughness elements above the pool become drowned out. Results suggest that forced pool–riffle sequences in boulder-bed streams are maintained by flows at or near bankfull discharge because of stage-dependent variability in depth-averaged velocity and tractive force.     

金在地幔矿物中的赋存形式及其赋存介质转化的可能模式:以中国北方一些地幔橄榄岩包体为例

采集中国北方玄武岩中橄榄岩包体样品21件。测定了其中的主元素、微量元素、稀土元素(REE)和Au等的含量。橄榄岩包体中的Au含量与CaO含量的相关性表明,其中的Au可能主要赋存于单斜辉石中,反映Au含量可能与地幔演化及熔融程度有关;橄榄岩包体后期受地幔流体交代作用的影响,Au转而以硫化物形式存在,这一过程是在橄榄岩包体原有Au的物质基础上进行的。     

电感耦合等离子体发射光谱法测定高铁三水铝土矿中的主量和次量元素

采用电感耦合等离子体发射光谱法,同时测定高铁三水铝土矿中的Si、Fe、Al、Ti、Mn、V、As、P等元素。对影响其光谱测量的各种因素进行了较为详细的研究,确定了最佳的试验测定条件。结果表明,该方法的检出限为0.0012-0.061μg/mL,回收率为95.4%-107.4%,主量元素相对标准偏差在1%-3%之间,次量元素相对标准偏差在2%-6%之间。该方法准确、快速、简便,应用于高铁三水铝土矿的测定,结果令人满意。     

氢化物发生-原子荧光光谱法则定锑精矿中的微量砷

使用氢化物发生—原子荧光光谱法测定锑精矿中的微量砷在国内外报道较少。文章在锑干扰状况试验、高锰酸钾溶液消除干扰的最佳条件选择试验、锑精矿中共存元素的干扰和消除试验的基础上,对样品进行了实测,并就其灵敏度、准确度和精密度进行了讨论。研究表明,该方法是测定锑精矿中微量砷的有效方法。     

重庆城口地区早前寒武系黑色岩系研究:(1)铂族元素成矿潜力评估

重庆城口地区从震旦统到下寒武统发育有丰富的黑色岩系,20世纪末期在该地区黑色岩系中开展了大量的铂族元素(PGE)的找矿工作,但是由于种种原因,关于该地区是否存在PGE矿化异常,还没有得到最终的结论.本次研究在PGE分析方法论证的基础上,进行了大量样品的PGE分析和微量元素分析.主要结论如下①区域上上震旦统槽区和断块区两套黑色岩系在原始的沉积环境和物源供给上有较大的差异,虽然槽区上震旦统的黑色岩系具有和下寒武统黑色岩系相似但强度较低的V-Cu-Y-Mo-U异常,但基本上不具有明显的PGE-Au-Ag异常.②断块区水井沱组黑色岩系和平剖面西段新发现的U-V-Mo-PGE异常可能是今后工作的重点,Pt＋Pd最高达248.9×10-9,局部U-V都达到了工业品位.③槽区巴山组硅质岩四个剖面都揭示了在硅质岩中广泛存在连续的PGE异常,87个碳质硅质岩平均含Pt＋Pd 57.2×10-9,有10个样品Pt Pd》100×10-9,最高达196.5×10-9;大部分碳质硅质岩都具有不同程度的V-Cu-Y-Mo-Tl-U组合异常,V都达到了独立矿床的品位要求,其中猪草河、燕子河等剖面还存在厚度较大的富矿地段,特别是燕子河剖面,局部还存在REE＋Y的高异常,值得深入研究.④城巴地区下寒武统黑色岩系存在广泛的PGE异常,但没有达到PGE的矿化要求,建议加强该地区的钒矿和铀矿勘探研究,PGE可以综合评价.     

Physical and chemical environments of abnormal vitrinite reflectance evolution in the sedimentary basins

Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure is regarded as not the only factor to retard the increase of vitrinite reflectance (R _o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment (fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins. This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R _o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R _o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry. Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报]     

Archaean high-K granitoids produced by remelting of earlier Tonalite–Trondhjemite–Granodiorite (TTG) in the Sangmelima region of the Ntem complex of the Congo craton,southern Cameroon

We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.     

PGE fractionation in seafloor hydrothermal systems: examples from mafic- and ultramafic-hosted hydrothermal fields at the slow-spreading Mid-Atlantic Ridge

The distribution of platinum group elements (PGEs) in massive sulfides and hematite–magnetite±pyrite assemblages from the recently discovered basalt-hosted Turtle Pits hydrothermal field and in massive sulfides from the ultramafic-hosted Logatchev vent field both on the Mid-Atlantic Ridge was studied and compared to that from selected ancient volcanic-hosted massive sulfide (VHMS) deposits. Cu-rich samples from black smoker chimneys of both vent fields are enriched in Pd and Rh (Pd up to 227 ppb and Rh up to 149 ppb) when compared to hematite–magnetite-rich samples from Turtle Pits (Pd up to 10 ppb, Rh up to 1.9 ppb). A significant positive correlation was established between Cu and Rh in sulfide samples from Turtle Pits. PGE chondrite-normalized patterns (with a positive Rh anomaly and Pd and Au enrichment), Pd/Pt and Pd/Au ratios close to global MORB, and high values of Pd/Ir and Pt/Ir ratios indicate mafic source rock and seawater involvement in the hydrothermal system at Turtle Pits. Similarly shaped PGE chondrite-normalized patterns and high values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides at Logatchev likely reflect a similar mechanism of PGE enrichment but with involvement of ultramafic source rocks.