原子荧光测定食品中总砷方法的改进与探讨

针对国标《GB 5009.11—2003食品中总砷及无机砷的测定》中的原子荧光-湿法消解测定总砷的方法中存在的难于控制完全消解样品、测定结果不稳定,试剂用量大的问题,对原方法进行了3点改进。一是利用浓硫酸沸点高,能脱水碳化破坏有机物的特性,通过高温浓缩硫酸对样品进行两次脱水碳化消解,使样品消解的更完全,且节省试剂;二是针对样品中砷形态的多样性,加强温度控制,低温消解、降低易挥发砷化合物的损失,高温加速样品消解,缩短操作时间;三是加盖小漏斗制造回流,减少易挥发砷化合物的损失,使方法易操作、节省试剂。用改进的方法测定菠菜粉(GBW10015)、海带粉(GBW08517)和虾粉(CNAS T0442)中的总砷,不少于6个平行样的测定结果均位于参考值范围的中间部分,且RSD值均小于7%,表明改进的方法准确、稳定。结果还表明,200℃的硫酸、高氯酸的混合酸和高温浓硫酸均能有效消解样品中砷甜菜碱和砷糖类化合物。     

������С����ƽ�����������

???t??????????ó?????????С????????????????????????????????1????????????????????????2????????????????????????????????????????????Э????????????????1??Э??????????????????????????????????????????????????????????????????????????????????????????????????????????????Ч???     

������Ƕ�Ȩ�ĵ������ݼ�Ȩ������С����ƽ������о�

?????????????????λ???????????????????????????????????С????????????????÷?????????????С??????????????????????????????????????и?????????????????????????????????????????3????????????????????????????????????С?????????????С??????????÷??????????????????????     

������С���˷������������о�

?????????????????????С??????????????????????????С????в????????С????в?????????????????????????Σ??о???????С?????????????С??????????С??????????????????????ó???????????????????ó?????????     

Performance Evaluation of a Self-Developed Ozonesonde and Its Application in an Intensive Observational Campaign

To make a detailed test on the reliability and detection performance of the electrochemical concentra- tion cell （ECC） type ozonesonde which had been devel- oped and preliminarily evaluated by the authors, an inten- sive ozonesonde release experiment was held at two sites in Beijing and Changchun in June 2013. The results showed that the mean background current and its standard deviation were 0.03 （0.04） pA and 0.02 （0.03） pA in Bei- jing （Changchun）. The average response time and its standard deviation were 27.8 s （30.4 s） and 4.0 s （3.7 s） in Beijing （Changchun）. The ozone partial pressure profiles at both sites showed a central peak in the stratosphere and a side peak in the boundary layer. Large variation in ozone partial pressure was observed at the middle levels of the atmosphere （10-17 kin）. A more marked gradient of ozone change was observed in Beijing （3.4 mPa km-1） at the lower atmosphere level, as compared to that in Changchun （0.4 mPa km-l）. The results presented in this paper indicate that this self-developed ozonesonde shows a high level of reliability and good performance. The ozonsonde is expected to play an important role in opera- tional observations of ozone profiles.     

Quantifying the Response Strength of the Southern Stratospheric Polar Vortex to Indian Ocean Warming in Austral Summer简

A previous multiple-AGCM study suggested that Indian Ocean Warming （IOW） tends to warm and weaken the southern polar vortex.Such an impact is robust because of a qualitative consistency among the five AGCMs used.However,a significant difference exists in the modeled strengths,particularly in the stratosphere,with those in three of the AGCMs （CCM3,CAM3,and GFS） being four to five times as strong as those in the two other models （GFDL AM2,ECHAM5）.As to which case reflects reality is an important issue not only for quantifying the role of tropical ocean warming in the recent modest recovery of the ozone hole over the Antarctic,but also for projecting its future trend.This issue is addressed in the present study through comparing the models＇ climatological mean states and intrinsic variability,particularly those influencing tropospheric signals to propagate upward and reach the stratosphere.The results suggest that differences in intrinsic variability of model atmospheres provide implications for the difference.Based on a comparison with observations,it is speculated that the impact in the real world may be closer to the modest one simulated by GFDL AM2 and ECHAM5,rather than the strong one simulated by the three other models （CCM3,CAM3 and GFS）.In particular,IOW during the past 50 years may have dynamically induced a 1.0℃ warming in the polar lower stratosphere （～100 hPa）,which canceled a fraction of radiative cooling due to ozone depletion.     

《西北地质》2001～2012年总被引频次的统计与分析

期刊的总被引频次在期刊的统计与分析中是十分重要的,笔者利用中国科学技术信息研究所出版的《中国科技期刊引证报告》(核心板)(CJCR)和万方数据出版的《中国期刊引证研究报告》(扩展版)(WD)等二家比较著名的统计机构的统计数据,对《西北地质》总被引频次进行了统计与分析。为了不断提高《西北地质》的办刊质量,笔者重点对《西北地质》2001~2012年的总被引频次及相关数据进行了统计与分析。结果表明:《西北地质》从2001~2012年在《中国科技期刊引证报告》(核心版)中的总被引频次增加了416,总被引频次增长率为660.32﹪。《西北地质》从2003~2012年在《中国科技期刊引证报告》中的总被引频次增加了782,总被引频次增长率为1133.33﹪。事实说明,《西北地质》多年来总被引频次一直在稳步上升。最后,笔者分析了影响期刊总被引频次的因素,对如何提高期刊的总被引频次提出了合理化的建议。     

平朔矿区杨涧煤矿90102工作面底板堵截技术研究

杨涧煤矿90102工作面底板隔水层厚度约50m,隔水层底板奥灰水压约1.8MPa,经煤矿开采该工作面揭露5个陷落柱,运输顺槽230~290m发生底鼓并多处开裂涌水,分析水源为底部砂岩水,底板隔水层发育的裂隙在近距离厚煤层回采条件下,必将加剧其底板破坏,为确保工作面安全开采,有必要实施底板堵截工程。为此,在矿区岩溶陷落柱发育规律探查、底鼓监测条件下,以XL1陷落柱和底鼓区为例,针对柱体下段、底板破坏带,采用水泥浆液来截断底板出水补给来源的同时加固底板隔水层强度。经钻探验证堵截效果较好。最后对治理方案、注浆层段、注浆参数等进行了详细总结,形成了适用于朔州矿区的注浆堵截技术,可为指导矿区今后防治水实践提供借鉴。     

三维坐标转换的通用整体最小二乘算法

三维坐标转换模型属于非线性EIV（errors-in-variables）模型,现有整体最小二乘算法均设定了某些特殊假设条件,如仅适用于小角度或者属于非统计意义上的数值解,并且不能用于结构性的系数矩阵等,算法适用性受到极大限制。本文提出了三维坐标转换模型的通用加权整体最小二乘算法,该算法适用于任意旋转角度以及一般性的权矩阵情况下的三维坐标转换模型,并且将结构性系数矩阵、同时包含随机和非随机元素的系数矩阵等情况纳入到了统一的坐标转换模型算法。实例计算表明,本文提出的算法具有通用性,适用于实际应用中的各类三维坐标转换模型。     

高精度边角网数据采集与处理系统的设计与实现

在水利、桥隧等工程施工和形变监测中,特别是在山区,GPS网的精度往往不能满足设计要求,一般需要布设地面边角网,采用高精度智能型全站仪进行数据的采集。本文从一体化测量作业模式的设计思想出发,基于VB．NET和数据库技术,研究设计了高精度地面边角网外业数据采集与处理系统,实现了边角数据的自动化采集和处理。