Extractable and total Fe and Mn contents of three sand dune soils in NW Nigeria

The profile distribution of total, diethylene triamine penta-acetic acid (DTPA)- and 0·1 HCl-extractable Fe and Mn were determined in 12 pedons formed on three contiguous sand dunes in the semi-arid savanna of Nigeria. The total Fe and Mn contents varied from 100 to 3750 and 40 to 11,375 μg g⁻¹, respectively. Values of 0·1 HCl-extractable Fe and Mn varied from 8·0 to 123 and 1·5 to 43·5 μg g⁻¹, respectively. The corresponding values of DTPA-extractable Fe and Mn were 4·5 to 16·0 and 1·0 to 38·8 μg g⁻¹. Total Fe and Mn correlated significantly with clay in nearly all the dunes (p≤ 0·01) but were not significantly correlated with organic matter. The 0·1 HCl-extractable Mn had a positive significant correlation with soil pH (r= 0·58*) in Illela dunes but a negative significant correlation with pH in the Sangiwa dunes (r= −0·75***). The values of extractable Fe and Mn in the sand dune soils are above the critical limits reported in other literature, thus deficiencies of these micronutrients do not pose a problem to crop production in the study area.     

Modern diatom, cladocera, chironomid, and chrysophyte cyst assemblages as quantitative indicators for the reconstruction of past environmental conditions in the Alps. II. Nutrients

Surface sediments from 68 small lakes in the Alps and 9 well-dated sediment core samples that cover a gradient of total phosphorus (TP) concentrations of 6 to 520 g TP l^-1 were studied for diatom, chrysophyte cyst, cladocera, and chironomid assemblages. Inference models for mean circulation log₁₀ TP were developed for diatoms, chironomids, and benthic cladocera using weighted-averaging partial least squares. After screening for outliers, the final transfer functions have coefficients of determination (r², as assessed by cross-validation, of 0.79 (diatoms), 0.68 (chironomids), and 0.49 (benthic cladocera). Planktonic cladocera and chrysophytes show very weak relationships to TP and no TP inference models were developed for these biota. Diatoms showed the best relationship with TP, whereas the other biota all have large secondary gradients, suggesting that variables other than TP have a strong influence on their composition and abundance. Comparison with other diatom – TP inference models shows that our model has high predictive power and a low root mean squared error of prediction, as assessed by cross-validation.     

Chemical ozone loss in the Arctic vortex in the winter 1995–96: HALOE measurements in conjunction with other observations

Severe chemical ozone loss has been detected in the Arctic in the winter and spring of 1995–96 by a variety of methods. Extreme reductions in column ozone due to halogen catalysed chemistry were derived from measurements of the Halogen Occultation Experiment (HALOE) on board the Upper Atmosphere Research Satellite in the Arctic vortex. Here, we discuss further aspects of the HALOE observations in the Arctic over this period. Potential problems, both in the data themselves and in the methodology of the data analysis are considered and the reason for the differences between the Arctic ozone losses deduced from HALOE data version 17 and 18 is analysed. Moreover, it is shown that HALOE measurements in the Arctic in winter and spring 1995–96 compare well with observations by other ground-based and satellite instruments.     

钢管高强混凝土叠合柱的抗震性能研究

通过周期性往复试验,研究了钢管高混凝土叠合柱柱的破坏形态,耗能能力、延性、承载力以及各种组成部分共同工作等内容,并与钢管高强混凝土核心柱进行了对比;随后通过计算,讨论了叠合柱中有关参数对其极限承载力和影响;最后给出了叠合柱正截面极限承载力的简化计算方法。     

岩石圈流变性与沉积盆地以辽西-辽北-松辽盆地区为例

岩石圈流变性取决于岩石圈的地热状态、物质组成和结构,并量化为岩石圈总强度。沉积盆地的沉降和抬升是地球最上层流变带形变的响应,岩石圈板块对构造应力的响应在很大程度上取决于岩石圈流变性在横向和纵向上的不均一性。辽西、辽北、松辽盆地区岩石圈流变性存在明显差异,因而岩石圈总强度明显不同,在晚中生代伸展过程中,变形方式、变形幅度不同,分别形成了断陷盆地、多断少坳型盆地和断坳型盆地。     

Intercomparison of New Zealand filter ozonometer and Dobson spectrophotometer total ozone measurements

A commercial version of the prototype New Zealand narrowband interference filter instrument has been run at Garmisch-Partenkirchen since autumn 1977. The vicinity of the Dobson stations Hohenpeissenberg and Arosa permitted a check of the filter instrument's utility, reliability and long-term stability in total ozone measurement by (i) station to station-or short-range intercomparisons of daily means and (ii) a several days' direct intercomparison at Arosa in spring 1978.The regression analysis with the Hohenpeissenberg data-covering the five month autumn-winter 1977/78 period with highly variable ozone-shows that the filter instrument's direct-sun modeX _AD total ozone values were systematically too low by a conversion factor of 0.93. The excellent proportionality between the instruments is indicated by the standard deviation of only 1,3%. The (–7.0±1.3%) bias perfectly agrees with the result reported byBasher [1] for a similar, yet direct, intercomparison.During the direct Arosa intercomparison the filter instrument also tracked down short-time variations in a remarkable, though biased, parallelism with the Dobson instruments, and theX _AD daily means fit well into the prognostic relationship derived from the preceding autumn-winter short-range intercomparison.A creeping deterioration of the characteristics of the 305.5 nm double filter then prevented any furtherX _AD total ozone intercomparison. No final decision is possible whether this behaviour after a half year's run is typical or just an unusual exception. The otherwise excellent long-term stability is demonstrated by the comparison of theX _CD daily means with the HohenpeissenbergX _AD data for a 1 1/2 year's period (autumn 1977–spring 1979), resulting in the same bias relationship as for theX _AD total ozone measurements.     

Upper Limit of Iodine Oxide in the Lower Stratosphere

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.     

A Study of Ozone Laminae Using Diabatic Trajectories, Contour Advection and Photochemical Trajectory Model Simulations.

In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.     

9608号台风登陆北上总能量变化及渤海高压维持

首先分析了属于台风与西风槽的相互作用型的９６０８号台风在其登陆泊台风核心区总能量及其组成部分的变化。结果指出,决定总能量再度增长的主要是潜热能,而此时潜热能的增长是同台风东侧低层偏南急流有密度关系。台风的东北象限内潜热能增长最盛,特大暴雨区恰也在这个象限。其次利用对流层高层散度风场与旋转风场的配置,从散度风动勇与旋转风动能之间的转换关系,半定量地估计台风东侧黄海、渤海、日本海高压上空反气旋环流的增     

Equal strain consolidation for stone columns reinforced foundation

Column consolidation and deformation are considered by assuming that the quantity of water flowing through the disturbed soil zone into the column is not equal to that flowing out from the column and the difference between them is equal to the volume change of the column. In addition, three patterns of distribution of the horizontal permeability of soil in the disturbed zone are also considered to account for the disturbance effect of columns construction on the surrounding soil. These three patterns include the constant distribution pattern (Pattern I), the linear distribution pattern (Pattern II) and the parabolic distribution pattern (Pattern III). By incorporating the aforementioned characteristics into the analyses, the governing equations containing two variables (i.e. the average excess pore-water pressures within the column and within the entire foundation at any depth) for the consolidation of a composite foundation are derived. The solutions of the governing equations are then obtained using a new initial condition derived from the assumption of equal strain and the equilibrium condition. On the basis of the solutions for excess pore-water pressures, the average degree of consolidation of a composite foundation is obtained and discussed. Finally, a comparison is made of some available solutions. Copyright © 2009 John Wiley & Sons, Ltd.