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561.
Jianwei Wang 《Earth and Planetary Science Letters》2004,222(2):517-527
Molecular dynamics (MD) modeling of the 10-Å phase, Mg3Si4O10(OH)2·xH2O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures. 相似文献
562.
Preliminary Study on Cenozoic Group and Fault Activity in the Sea Area Near the Yangtze River Mouth 总被引:2,自引:0,他引:2
By shallow seismic prospecting, the Cenozoic Group in the sea area near the Yangtze Rver Mouth can be divided into five seismic sequences. They correspond to the Quaternary,Pliocene, Upper Miocene, Lower Miocene and Eocene respectively. The Quaternary System covers all the detecting area. The Tertiary System overlaps and thins out from NE to SW. The sedimentary basement mainly consists of volcanic rock (J3) and acidic rock (r35). Paleogene or Late Cretaceous basins are not found there. The faults that have been detected are all normal faults. They can be divided into three groups (NE, NW, near EW) by their trend. The NE and NW-trending faults are predominant, and agree with aeromagnetic anomaly. Their length and displacement are larger than that of the EW-trending faults. The activity of the NEtrending faults is different in different segments. The SW segment is a Quaternary fault, the middle segment is a Neogene fault, The NE is Paleogene. But the segment of the NW-trending fault is not obvious. The average vertical displacement rate is about 0.015mm/a. 相似文献
563.
As a result of the left-lateral strike-slipping of the Altyn Tagh fault in Neotectonic period, a contra-rotational structure, namely the Zhaobishan vortex structure, has developed at the juncture of the main Altyn Tagh fault and the northern fringe fault of the Qilian Mountains.Preliminary analysis on the deformation and evolution of the Zhaobishan vortex structure. In combination with the previous data, suggests that the tectonic transform between the Altyn Tagh fault and the northern fringe fault of the Qilian Mountains attributes to the deformation of the rotational structure. The existence of a series of rotational structures along the Altyn Tagh fault and on the northeastern edge of the Qinghai-Xizang(Tibet) plateau indicate that as the substance in the northern Qinghal-Xizang (Tibet) plateau moves clockwise around the eastern tectonic knot of the Himalayas, rotational structures become the principal mode on the northern marginal zone of the Plateau of transforming and absorbing tectonic deformation. 相似文献
564.
该文分析了1885~2000年长江中下游梅雨特征量的基本统计特征及其相互关系,在此基础上研究了梅雨较长时间尺度的变化特征。结果发现:①梅雨量的大小与梅雨期的长短和出梅日期的早晚为显著的正相关;②梅雨的主要周期为3 a、6 a和8 a,它们分别与低纬100 hPa高度场、热带系统以及全球陆地温度的变化有关;③控制入梅、出梅和梅雨期6 a左右周期的气候因素是相同的,而3 a左右的周期可能受到不同气候因素的影响;④长江中下游梅雨在近116年期间,经历了6个不同的气候阶段。 相似文献
565.
文中重点分析了中国科学院大气物理研究所LASG最新发展的全球大气环流谱模式(R42L9)与一全球海洋环流模式(T63L30)耦合形成的全球海洋-大气-陆面气候系统模式(GOALS/LASG)新版本已积分30 a的模拟结果,通过与多种观测资料的对比分析,讨论了赤道太平洋海表温度(SST)的年际变化及其纬向传播、赤道东太平洋SST异常与其他洋面SST变化之间的遥相关关系、赤道太平洋浅表层海温的年际变化特征等研究内容.结果表明,COALS模式模拟出了赤道太平洋SST异常出现不规则的年际变化特点;赤道东太平洋SST异常的向西传播过程;赤道太平洋混合层海温变化由西向东、由深层向浅层的传播过程;同时也模拟出了赤道东太平洋SST变化与赤道西太平洋以及与西南太平洋海温之间的反相关关系,与南印度洋和副热带大西洋SST之间的正遥相关关系等实际观测现象.但COALS模式也存在明显的不足,如对赤道东、中太平洋SST异常的年际变化幅度明显偏小,没能模拟出赤道东太平洋的SST变化比赤道中太平洋强的特点;赤道太平洋SST从东向西的传播速度明显比实际观测慢得多,但混合层海温极值变化由西向东的传播速度明显比实际情况快得多;没能模拟出赤道东太平洋SST变化同西北太平洋SST的负相关和北印度洋海温变化的正相关现象,因此也影响了对南亚、东南亚降水年际变化的模拟能力. 相似文献
566.
青藏高原影响亚洲夏季气候研究的最新进展 总被引:40,自引:6,他引:40
文中回顾了近 10a来吴国雄等在青藏高原影响亚洲夏季气候研究方面的最新进展。通过分析东西风交界面的演变证明 ,由于青藏高原的春季加热 ,亚洲季风区对流层低层冬季盛行偏东风转变为夏季偏西南风最早发生在孟加拉湾东部 ,与其相伴随的激烈对流降水出现在其东面。因此孟加拉湾东部至中印半岛西部是亚洲季风最早爆发的地区。同时也指出盛夏伊朗高原和青藏高原加热所激发的同相环流嵌套在欧亚大陆尺度的热力环流中 ,从而加强了东亚的夏季风 ,加剧了中西亚的干旱 ;并通过其所激发的波动对夏季东亚的气候格局产生重要影响。文中还比较了夏季南亚高压的伊朗模态和青藏模态性质的异同及其对亚洲夏季降水异常分布的不同影响。 相似文献
567.
568.
569.
通过对 2 0 0 0年 4月 6日和 4月 9日北京地区两次沙尘 (暴 )天气过程的对比分析认为 :蒙古气旋型和不伴有气旋的西北槽型所造成的北京沙尘天气的严重程度不同 ;沙源地区中低层较强上升运动的主要作用是将当地沙尘垂直输送到空中 ,然后在70 0hPa较强西北气流的引导下将卷起的沙尘水平输送到下游地区 ;不稳定层结又加强了沙尘天气 ;沙尘暴区上空z 螺旋度分布的特征是高层为负值 ,低层为正值 ,对流层中低层螺旋度正的大值区与卫星云图显示的沙尘暴区具有较好的一致性 ,对沙尘暴的预报有一定的指示意义 相似文献
570.