福建省第三产业发展的区域比较分析

运用可拓工程方法和主成分分析方法建立了福建省第三产业发展水平的综合评判物元模型。模型的输出结果表明：福建省各地区第三产业发展水平差距悬殊；综合关联度将第三产业发展水平划分成4个等级，单指标关联度则揭示了各地区第三产业发展的优、劣势。     

黄河影响下开封城市的历史演变

河流对城市的形成和发展起着重要的作用,古人形象地把其比喻为“城市之血脉”。文章从不同的历史时期黄河及其分支对开封城市演变的影响进行分析,得出黄河与开封城市的关系存在着利与害的统一。开封城市的历史发展,即得益于黄河充足的水源,又受害于其频繁的决溢、泛滥、改道。因此,要采用先进的科学技术对黄河进行综合治理开发,使其恢复它应有的美好环境,更好地造福于人民。     

青藏高原腹地湖泊沉积对第四纪晚期古季风变化的响应

通过对青藏高原腹地的综合科学考察和对中心钻孔岩芯剖面的最新研究,用层序地层学与年代地层学和气候地层学相结合的方法,分辨出可可西里地区湖泊沉积记录(孔深7.25 m)的第四纪晚期距今3万余年以来的古气候变化,沉积物磁化率等因子综合表征的高原古季风变化是波动发展的,发生在仙女木期地质环境事件中的季风活动具有强烈暴发的特点,是高原季风发展中的突变事件,而且地表热点效应对其起到了激发作用。综合分析的研究成果表明,它的变化频谱与激变因子及其运行机制是伴随着青藏高原地质效应的演变而发展的,为研究第四纪冰消期以来的气候变化提供了新的信息。     

High-resolution sedimentary record of lead in the coastal mud of the East China Sea in the past one hundred and fifty years

In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.     

SPATIAL DISTRIBUTION OF NUTRIENTS OF SHALLOW LAKE IN THE ZHALONG WETLAND

1 INTRODUCTIONNitrogen and phosphorus in the water are the nu-trients limited in natural wetlands,which seriously in-fluence on the ecosystem production and the biodiver-sity(Mitsch,Grosselin,2000).Nitrogen and phos-phorus recycles have been interrupted b…     

Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,     

Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Damage Survey of Water Supply Systems and Fragility Curve of PVC Water Pipelines in the Chi–Chi Taiwan Earthquake

Substantial damage to water supply systems, including water delivery pipelines, water treatment plants, reservoirs, and water storage tanks, was reported after the 1999 Chi–Chi Taiwan Earthquake. This paper first summarizes the damage survey and then presents the results of seismic fragility analysis for underground pipelines. Construction blueprints of the water delivery pipelines and repair work orders of 11 townships and cities in the disastrous area were digitized into a Geographical Information System (GIS) for analysis and assessment. With the aid of the GIS system, we found that PVC pipes made up 86% of water delivery pipelines while steel, cast iron, ductile iron, PE and others took the rest. Therefore, this paper focuses on the fragility analysis of PVC pipes. Three different methods were applied to derive the fragility relations between the PVC water pipes having nominal diameters (approximately inner diameters) greater than or equal to 65 mm and earthquake intensity parameters such as peak ground acceleration and peak ground velocity. The results were then examined with those of other countries. The discrepancy between our results and the empirical equation used by HAZUS, an earthquake loss estimation software developed by the Federal Emergency Management Agency was not significant.