高温高压下电解质溶液热力学性质的研究进展

高温高压下电解质溶液热力学性质的研究不仅对探讨地球内部流体的作用具有重要意义，而且在很多实际工业过程中也都有广泛应用。本综述了近10年来高温高压下电解质溶液热力学参数的实验测量和理论计算的进展，实验设备还有待进一步的改进和完善，以获得更高温度和压力下的数据，理论计算不仅有待于实验的发展，也与溶液的结构理论密切相关。     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。     

含油玄武岩中绿泥石的形成温度

以苏北盆地高邮凹陷闵桥地区含油玄武岩中的绿泥石为研究对象，探讨了其成因和形成温度，认为玄武岩中绿泥石有两种形成方式、五条形成途径：其一为蚀变演化，包括：火山玻璃、斜长石、辉石的蚀变，交代橄榄石斑晶，以及皂石的进一步演化；其二为沉淀结晶，包括从热液中直接沉淀生长和胶体溶液充填后的结晶。计算结果显示，蚀变演化形成的绿泥石，其形成温度为128－271℃；沉淀结晶形成的绿泥石，其形成温度为31－63℃。玄武岩中绿泥石形成温度与埋藏深度间没有明显的线性相关。进一步研究表明，本区玄武岩作为储油层，其进油时的温度为62－118℃，不超出48－137℃。     

三原井水位固体潮加卸载响应比的地震异常

讨论了三原井水位在泾阳4．8级地震前的变化特征，重点是泾阳地震前水位对固体潮响应的变化，即固体潮加卸载响应率与加卸载响应比的变化，对水位观测资料的计算分析表明，震前加卸载响应率及响应比有“平稳－升高－恢复”的特征，说明水位固体潮加卸载响应比方法有可能捕捉5级左右近震的前兆信息。     

隔震及超高层建筑的地震反应观测

2001年5月24日和6月20日分别发生了宜良4.2级和呈南3.6级两次地震，架设在云南省抗震培训中心隔震大楼和昆明佳华广场的结构强震观测台阵记录了这两栋建筑物对这两次地震反应。本介绍了获取的记录，并分析了两栋建筑物的地震反应情况。     

Principal axes of m-DOF structures PartⅠ:Static loading

This paper is the first in a two-part series that discusses the principal axes of M-DOF structures subjected to static and dynamic loads. The primary purpose of this series is to understand the magnitude of the dynamic response of structures to enable better design of structures and control modification devices/systems. Under idealized design conditions, the structural responses are obtained by using single direction input ground motions in the direction of the intended control devices/systems,and by assuming that the responses of the structure is decoupleable in three mutually perpendicular directions. This standard practice has been applied to both new and retrofitted structures using various seismic protective systems. Very limited information is available on the effects of neglecting the impact of directional couplings (cross effects - of which torsion is a component) of the dynamic response of structures. In order to quantify such effects, it is necessary to examine the principal axes of structures under both static and dynamic loading.This first paper deals with quantitative definitions of principal axes and "cross effects" of three-dimensional structures under static load by using linear algebra. It shows theoretically that, for three-dimensional structures, such principal axes rarely exist. Under static loading conditions, the cross effect is typically small and negligible from the viewpoint of engineering applications. However, it provides the theoretical base for subsequent quantification of the response couplings under dynamic loads, which is reported in part Ⅱ of this series.     

Horizontal and vertical components of earthquake ground motions at liquefiable sites

Field observations on ground motions from recent earthquakes imply that current knowledge is limited with regard to relating vertical and horizontal motions at liquefiable sites. This paper describes a study with the purpose of clarifying this emerging issue to some extent. A series of numerical analyses is carried out on a liquefiable soil deposit with a verified, fully coupled, nonlinear procedure. It is shown that the transformation of vertical motions in the deposit differs considerably from the transformation of horizontal motions. Both the amplitude and frequency content of the horizontal motions are strongly dependent on the shaking level or the associated nonlinear soil behavior. The transfer function for vertical motions is however likely to be independent of the intensity of input motions; no reduction in the amplitude occurs even in the case of strong shaking. The results are shown to be in consistence with the laboratory observations on shaking table tests and recent field observations that less nonlinearity exists for vertical motions. It is also shown that the possibility exists for using information on spectral ratios between the horizontal and vertical surface motions to quickly identify in situ soil behavior and liquefaction that are not readily covered by conventional field or laboratory experimentation procedures.     

Torsional vibrations of elastic foundation on saturated media

A comprehensive analytical solution is developed to examine the torsional vibration of an elastic foundation on a semi-infinite saturated elastic medium for the first time. First, the governing equations of saturated media are solved by use of Hankel transform techniques. Then, based on the assumption that the contact between the foundation and the half-space is perfectly bonded, this dynamic mixed boundary-value problem can lead to dual integral equations, which are further reduced to the standard Fredholm integral equations of the second kind and solved by numerical procedures. Numerical examples are given at the end of the paper. The numerical results indicate that the response of the elastic foundation strongly depends on the material and geometrical properties of both the saturated soil-foundation system and the load acting on the foundation. In most of the cases, the dynamic behavior of an elastic foundation on saturated media significantly differs from that of a rigid plate bearing on the elastic half-space.     

Viscous damping formulation and high frequency motion propagation in non-linear site response analysis

Non-linear time domain site response analysis is widely used in evaluating local soil effects on propagated ground motion. This approach has generally provided good estimates of field behavior at longer periods but has shortcomings at relatively shorter periods. Viscous damping is commonly employed in the equation of motion to capture damping at very small strains and employs an approximation of Rayleigh damping using the first natural mode only. This paper introduces a new formulation for the viscous damping using the full Rayleigh damping. The new formulation represents more accurately wave propagation for soil columns greater than 50 m thick and improves non-linear site response analysis at shorter periods. The proposed formulation allows the use of frequency dependent viscous damping. Several examples, including a field case history at Treasure Island, California, demonstrate the significant improvement in computed surface response using the new formulation.