合成磷灰石的去氟机理研究

用固相反应法和sol-gel法合成了不同类型的磷灰石（AP），并采用TEM、XRD、IR、BET比表面积法及静、动态吸附等方法研究了不同AP的比表面积、结晶度、晶胞参数、结晶尺寸、晶格缺陷度、Ca/P摩尔比和煅烧温度等与吸氟能力的关系，结果表明：结晶度高、晶粒大的AP有较小的吸氟量，属表面单分子层化学络合吸附机理；酸活化的AP有较大的吸氟量，属溶解-沉淀与沉淀物表面纳米尺寸效应吸附的复合去氟机理；具纳米尺寸的HAP在常温、常压、无二次污染、小于11mg/L的低含氟浓度废水中且不酸化情况下有较大吸氟量，属纳米尺寸效应吸附机理。     

AHP及模糊综合评判法在路基长期稳定性评价中的应用

根据对一低液限粉土路基的现场工程地质调查及检测,确定了影响该路基长期稳定性的主要影响因素,并结合AHP法,应用两级模糊综合评判的方法对该路基的长期稳定性进行了评价。     

钛磁铁矿的制备及其异相Fenton反应催化性能

在水相中合成了钛磁铁矿（Fe3-xTixO4）,并用XRD、MSssbauer、TG-DSC和SEM等手段对合成的Fe3-xTixO4进行了表征。结果表明,合成的Fe3-xTixO4为立方晶系尖晶石结构,样品中的钛离子都已经进入其晶格中;钛掺杂有抑制钛磁铁矿进一步向钛磁赤铁矿转化和稳定尖晶石结构的作用。此外,以亚甲基蓝降解为探针反应,考察了钛磁铁矿异相Fenton反应的催化性能。实验表明,钛含量较高的钛磁铁矿是一种性能优越的异相Fenton反应催化剂。     

温和水热法制备MZr2(PO4)3(M=Na,K,Rb)

在温和的水热条件下分别制备出纯净的磷酸锆钠 [NaZr2 (PO4) 3 ]、磷酸锆钾 [KZr2 (PO4) 3 ]和磷酸锆铷 [RbZr2 (PO4) 3 ]。研究了原料配比、矿化剂 (氟离子 )、反应时间和温度等水热晶化条件对产物生成的影响。发现在较宽的温和水热条件下可以制得这三种磷酸锆盐 ;随着碱金属离子的增大 ,产物的生成条件越来越窄 ;最佳制备条件是 :F- ZrO2 =2、P2 O5 ZrO2 =3 (均为摩尔比 )、[ZrOCl2 ]=0 6mol L、反应温度 1 5 0℃、反应时间 2天。用水热法没有制备出同一系列磷酸锆盐中的磷酸锆锂 [LiZr2 (PO4) 3 ]和磷酸锆铯 [CsZr2 (PO4) 3 ]。采用XRD、SEM、IR、Raman和XPS等现代物化仪器对产物的结构与物相纯度进行了测定与表征     

A seismic reconnaissance survey of the northern Congo Fan

To study the time-varying influence of the Congo River and the Benguela Current on the deposition at the Angola Continental Margin, a high-resolution reflection seismic survey was carried out on the northern Congo Fan. Four seismostratigraphic units have been defined for the upper 800 m (1000 ms TWT) of the data. The units record different depositional environments, ranging from pre-establishment of the Congo River drainage system to the influence of the Benguela Current. An indication of a general change in the turbidite system is provided by a shift in channel distribution and a relocation of the depocentre of coarse material. The ascent of salt is recorded up to the Pliocene. Gas that has migrated out of Lower Cretaceous shales and that was produced from large quantities of organic matter in the younger sediments can be found on the flanks and on top of the salt domes. In a few places, this gas even ascends to the ocean floor along structural pathways through the topmost unit.     

Detection, excision and statistics of interference at the Mauritius radio telescope

A technique to detect man-made interference in the visibility data of the Mauritius Radio Telescope (MRT) has been developed. This technique is based on the understanding that the interference is generally ‘spiky’ in nature and has Fourier components beyond the maximum frequency which can arise from the radio sky and can therefore be identified. We take the sum of magnitudes of visibilities on all the baselines measured at a given time to improve detectability. This is then high-pass filtered to get a time series from which the contribution of the sky is removed. Interference is detected in the high-pass data using an iterative scheme. In each iteration, interference with amplitudes beyond a certain threshold is detected. These points are then removed from the original time series and the resulting data are high-pass filtered and the process repeated. We have also studied the statistics of the strength, numbers, time of occurrence and duration of the interference at the MRT. The statistics indicate that most often the interference excision can be carried out while post-integrating the visibilities by giving a zero weight to the interference points.     

基于高斯烟羽模型的船舶尾气扩散研究

为有效对港区大气污染进行治理、分析船舶尾气,本文详细介绍了一种基于高斯烟羽模型,通过MATLAB模拟仿真模型,其包括实验仿真过程、技术原理及理论模型对船舶尾气扩散进行的研究。该模型是在传统的高斯烟羽模型的基础上,通过对实源像源进行加权选择输入参数;通过矢量合成确定了气体扩散的方向,利用合成后的"风速"进行计算仿真,有效模拟了船舶尾气在港区或者海洋环境中的气体扩散模型。其模型简单且可以有效模拟船舶尾气扩散。并且进一步对后续模型的精确优化进行分析。     

利用高铁钾长石粉合成13X沸石分子筛的实验研究

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。     

Production of methyl bromide and methyl chloride in laboratory cultures of marine phytoplankton II

Methyl halides (monohalomethanes), especially methyl bromide, are known to contribute significantly to ozone destruction in the stratosphere. Budgets of natural and anthropogenic methyl bromide suggest that marine organisms may be the source of a significant proportion of the total global production. Since phytoplankton are abundant in surface waters, they are obvious candidates. Cultures of nine phytoplankton species were grown in CO₂-enriched, nitrate-limited medium in sealed glass vessels. Species tested include Chaetoceros calcitrans, Isochrysis sp., Porphyridium sp., Synechococcus sp., Phaeodactylum tricornutum, Tetraselmis sp., Prorocentrum sp., Emiliania huxleyi and Phaeocystis sp. Methyl bromide (CH₃Br) and methyl chloride (CH₃Cl) concentrations were determined by bubbling the cultures with high-purity air, cryotrapping the effluent and analyzing it on a gas chromatograph with an electron capture detector. The Phaeocystis sp. samples were monitored with GCMS. Cell population, bacterial population, Chl a, pH, and nitrate concentration were monitored for periods of at least two weeks. CH₃Cl was produced by all cultures. CH₃Br was absent in Tetraselmis sp. and Isochrysis sp. cultures, but present in all the others. Methyl iodide (CH₃I) was present in most cultures but could not be quantified due to analytical limitations. CH₃I and CH₃Br production was fastest in stationary phase and continued long after cell division had ceased. Axeic cultures of Phaeocystis sp. achieved almost identical production rates of CH₃Cl and CH₃Br as xenic cultures of the same species. Species from tropical waters had faster CH₃Cl and CH₃Br production rates than temperate species. Scaling the observed production rates using global standing stock estimates for Chl a and particulate nitrogen indicate that phytoplankton can account for only a fraction of the CH₃Cl and CH₃Br believed to be produced in the ocean. Calculations based on the estimated global biomass of Phaeocystis sp. and E. huxleyi blooms show that their contribution is insignificantly small.     

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。