Homogenization of the Daily Land Surface Temperature over the Mainland of China from 1960 through 2017

Land surface temperature(LST) is one of the most important factors in the land-atmosphere interaction process. Raw measured LSTs may contain biases due to instrument replacement, changes in recording procedures, and other non-climatic factors. This study attempts to reduce the above biases in raw daily measurements and achieves a homogenized daily LST dataset over China using 2360 stations from 1960 through 2017. The high-quality land surface air temperature(LSAT)dataset is used to correct the LST warming biases especially evident during cold months in regions north of 40°N due to the replacement of observation instruments around 2004. Subsequently, the Multiple Analysis of Series for Homogenization(MASH) method is adopted to detect and then adjust the daily observed LST records. In total, 3.68 × 103 effective breakpoints in 1.65 × 106 monthly records(about 20%) are detected. A large number of these effective breakpoints are located over large parts of the Sichuan Basin and southern China. After the MASH procedure, LSTs at more than 80% of the breakpoints are adjusted within +/– 0.5°C, and of the remaining breakpoints, only 10% are adjusted over 1.5°C.Compared to the raw LST dataset over the whole domain, the homogenization significantly reduces the mean LST magnitude and its interannual variability as well as its linear trend at most stations. Finally, we perform preliminary analysis upon the homogenized LST and find that the annual mean LST averaged across China shows a significant warming trend [0.22°C(10 yr)–1]. The homogenized LST dataset can be further adapted for a variety of applications(e.g.,model evaluation and extreme event characterization).     

唐山地区干旱演变特征分析

研究区地处干旱和湿润气候的过渡地带,这一地区导致干旱发生的直接原因是干旱的气候和水资源的短缺,主要就是降水量的偏少.从简单实用角度考虑,本文根据唐山地区1956～2005年的水文和气象资料,采用降水距平、径流系数、她表湿润度指数等指标对唐山地区的干旱演变趋势进行分析,揭示出该地区近50年的干旱演变特征.     

晶体及矿物颗粒大小对岩土材料力学性质的影响

岩石常见较大的晶体或者矿物颗粒,混凝土中是骨料,通过团簇模拟大颗粒的力学行为、团簇可以破裂。根据设计的相同数量、相同位置、不同半径的大颗粒数值单轴压缩试验,在虚拟试验条件下,考察了颗粒大小对材料力学响应的影响。通过分析颗粒材料的破裂形态、裂纹扩展过程、应力-应变曲线和破裂能量演化规律发现：大颗粒具有明显的增强特性,有阻止裂纹扩展的作用,破裂多绕大颗粒发展;增强幅度随颗粒半径的增加呈单增趋势,半径较小时,增强效果不明显。     

南黄海中部隆起印支面剥蚀量恢复与演化过程——来自CSDP-2井的证据

南黄海中部隆起是下扬子地块向海域的延伸,是当前海相盆地海域资源调查的潜力区。中部隆起自印支期以来经历多期构造隆升、挤压及剥蚀作用,显著影响了盆地油气资源的形成和分布。2016年底完钻的大陆架科学钻探CSDP-2井首次在中部隆起钻穿印支不整合面,该不整合面在中部隆起既是新近系-第四系底界,又是下三叠统灰岩的顶界,横向延伸平缓,上、下地层产状差异巨大,下伏地层具有强烈的挤压变形及逆冲推覆,呈现显著的角度不整合接触关系。本次研究基于泥岩声波时差法计算的印支面地层剥蚀量约为1200 m,镜质体反射率法计算的剥蚀量约为1400 m,与地层趋势面估算的剥蚀量基本一致。结合南黄海盆地演化过程分析,认为中部隆起大致于晚三叠世开始隆升,至晚白垩世期间经历快速剥蚀,并可能延续到渐新世末期。在当前南黄海盆地资源调查逐步转向中、古生界海相残留盆地之际,依托实际钻探资料进行印支不整合面研究及剥蚀量恢复对于恢复盆地构造-热演化史及评价油气资源等均具有重要的现实意义。     

沉积岩中蒙脱石-伊利石混层矿物的SEM/EDAX分析

本文利用扫描电子显微镜与X射线能量色散分析联合法,对沉积岩中蒙脱石-伊利石混层矿物进行系统微区成分分析,求出混合层中伊利石的百分含量。     

利用探地雷达观测分析早春融雪前后沙丘表层土壤含水量的时空分布

积雪融水是古尔班通古特沙漠春季植物发育的重要水源, 快速获取早春沙丘的土壤水分变化具有十分重要的生态学意义. 2010年3、 4月分别使用探地雷达进行了多次测量实验, 结果显示: 1)融雪初期, 沙丘顶部土壤的自由水含量最大, 阳坡次之, 且融雪水在重力作用下沿坡面侧向缓慢流动, 在坡底汇集, 主导了融雪初期乃至整个春季沙丘表层土壤水分的分布格局; 2)融雪后期, 由于阴坡积雪和冻土消融相对滞后, 表层土壤含水量略高于阳坡, 而沙丘顶部由于融雪最早且融雪期间水分转移最多而表面最为干燥; 3)通过与时域反射仪的同步测量结果对比, 探地雷达的测量精度被有效控制在0.03范围内, 且探地雷达提供的连续数据更有利于从细节上把握土壤含水量的变化趋势, 为中小尺度土壤水分的动态研究提供了一种科学、 有效的技术手段.     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

瑞雷波勘探在地下洞穴探测中的应用

利用瑞雷波勘探方法进行地下洞穴探测，在实际处理过程中，对场地所测得的面波频散曲线进行分类、归纳，并利用动力触探曲线对各种特征曲线所反映的地下洞穴情况进行标定，从而确定整个测区洞穴的空间分布规律。     

利用面波频散反演场地参数的Occam法

将Constable等人1987在解释大地电磁测深资料时提出的Occam反演方法应用到面波频散反演之中，其思路是求满足一定的残差条件下的最光滑的模型。从文中反演的几组数据结果来看，该方法在面波反演中的应用效果是令人满意的。     

Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD

 The kinetics of the dehydroxylation of chrysotile was followed in situ at high temperature using real-time conventional and synchrotron powder diffraction (XRPD). This is the first time kinetics parameters have been calculated for the dehydroxylation of chrysotile. The value of the order of the reaction mechanism calculated using the Avrami model indicates that the rate-limiting step of the reaction is a one-dimensional diffusion with an instantaneous nucleation or a deceleratory rate of nucleation of the reaction product. Hence, the rate-limiting step is the one-dimensional diffusion of the water molecules formed in the interlayer region by direct condensation of two hydrogen atoms and an oxygen atom. The calculated apparent activation energy of the reaction in the temperature range 620–750 °C is 184 kJ mol⁻¹. The diffusion path is along the axis of the fibrils forming the fibers. The amorphous or short-range ordered dehydroxylate of chrysotile is extremely unstable because forsterite readily nucleates in the Mg-rich regions. Moreover, it is less stable than the dehydroxylate of kaolinite, the so-called metakaolinite, which forms mullite at about 950 °C. This difference is interpreted in terms of the different nature of the two ions Mg²⁺ and Al³⁺ and their function as glass modifier and glass-forming ion, respectively. Received: 10 April 2002 / Accepted: 7 January 2003 Acknowledgements This work is part of a COFIN project (04 Scienze della Terra, NR 17, 2000) supported by MURST. Dr Dapiaggi is kindly acknowledged for help during the data collection at the Dipartimento di Scienze della Terra, University of Milan.