磺基水杨酸光度法连续测定岩石中的铁和钛

本文提出用磺基水杨酸(SSA)作显色剂,在不同pH值和同一波长下.于一分试液中连续测定铁和钛的分析方法。测定波长为420nm,测铁的pH值为8—11,Fe量在0—10μg/ml范围内服从比尔定律;测钛的pH值为2,TiO_2量在0—14μg/ml范围内服从比尔定律。     

Dynamic analysis of a cylindrical casing–cement structure in a poroelastic stratum

The transient response of a cylindrical casing–cement structure in a poroelastic stratum under dynamic radial tractions is one of the significant issues during the analysis of downhole operations and the selection of safe material. Based on the Biot theory and general elastic mechanics, this paper gives a set of exact solutions for radial displacement, stresses for the casing–cement system and the pore pressure of the infinite surrounding poroelastic stratum in the Laplace transform space. Solutions are presented for three different types of transient radial loadings acting on the surface of casing, i.e., suddenly applied constant load, gradually applied step load and triangular pulse load. Time domain solutions are obtained using a reliable numerical method of inverse Laplace transforms. A detailed parametric study about the transient response is presented both at the casing–cement interface and the cement–stratum interface, and the distributions of the pore pressure and the effective stresses in the stratum are also examined. Copyright © 2017 John Wiley & Sons, Ltd.     

Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

缝洞型油藏超大规模酸压技术

塔河油田缝洞型油藏主要的储集体空间类型为溶蚀的裂缝及大型的溶洞,连通关系极其复杂,70％的钻井需要酸压才能投产.为进一步沟通远井地带的缝洞储集体,室内模拟及现场监测结果表明,超大规模酸压技术能够提高造缝长度,沟通井眼远处的储集体.通过多口井的研究及现场试验,在油气富集带上具有明显的地震反射异常,生产过程中供液不足的井进...     

变荷载下双层地基一维非线性固结近似解析解

目前考虑土体非线性压缩及渗透特性的双层地基非线性固结解均假定土体固结系数保持不变,能反映固结系数变化的双层地基非线性固结解还很鲜见。引入经典的e- 和e- 非线性关系描述土体的非线性压缩、渗透特性,在假定双层地基上、下土层压缩指数与渗透指数比值 相等且不等于1的基础上,得到变荷载下考虑土体固结系数变化的双层地基一维非线性固结近似解。该解答在 1条件下可退化为已有的 1时双层地基一维非线性固结解。基于此解探讨了双层地基上、下土层参数的相对比值对非线性固结性状的影响。结果表明：单面排水条件下 越小,下层土与上层土的相对压缩性越低、相对渗透性越高,则双层地基非线性固结速率越快;减小 值,增加双层地基中压缩性小、渗透性高的土层的厚度,会加快地基的固结速率。     

CdTe量子点荧光猝灭法测定赤泥中痕量镍

Cd Te量子点具有荧光强度高和稳定性好的优点,应用Cd Te量子点荧光猝灭法分析基体复杂的样品,需要有效分离对测定干扰的金属元素和高效富集待测元素。本文以巯基乙酸(TGA)作稳定剂,采用水相合成法制备了巯基乙酸修饰的Cd Te量子点,基于镍离子在p H=10.0硼砂缓冲溶液中对Cd Te量子点的荧光具有较强猝灭作用,建立了一种测定赤泥中痕量镍的荧光光度方法。荧光猝灭反应的最佳实验条件为:Cd Te量子点的浓度3.0×10-4mol/L,反应温度为室温,反应时间10 min,在此条件下镍离子浓度在2.0×10-7~7.8×10-5mol/L范围内与Cd Te量子点的相对荧光强度呈良好的线性关系;方法检出限为1.5×10-7mol/L。本方法针对Fe3+、Co2+、Cu2+等主要基体金属元素允许量低的问题,采用25%的2-羟基-4-仲辛氧基二苯甲酮肟(N530)磺化煤油萃取回收滤液中的Ni2+,镍回收率达到99%以上;赤泥中痕量镍的测定结果与催化光度法相符,加标回收率为98.3%-104.2%。     

Humic Ion-Binding Model VI: An Improved Description of the Interactions of Protons and Metal Ions with Humic Substances

Humic Ion-Binding Model VI, a discrete site/electrostatic model of the interactions of protons and metals with fulvic and humic acids, is applied to 19 sets of published data for proton binding, and 110 sets for metal binding. Proton binding is described with a site density, two median intrinsic equilibrium constants, two parameters defining the spread of equilibrium constants around the medians, and an electrostatic constant. Intrinsic equilibrium constants for metal binding are defined by two median constants, log K_MA and log K_MB, which refer to carboxyl and weaker-acid sites respectively, together with a parameter, LK₁, defining the spreads of values around the medians. A further parameter, LK₂, takes account of small numbers of strong binding sites. By considering results from many data sets, a universal average value of LK₁ is obtained, and a correlation established between log K_MB and log K_MA. In addition, a relation between LK₂ and the equilibrium constant for metal-NH₃ complexation is tentatively suggested. As a result, metal-binding data can be fitted by the adjustment of a single parameter, log K_MA. Values of log K_MA are derived for 22 metal species. Model VI accounts for competition and ionic strength effects, and for proton-metal exchange.     

Statistical evaluation of tectonomagmatic discrimination diagrams for granitic rocks and proposal of new discriminant-function-based multi-dimensional diagrams for acid rocks

The four tectonic discrimination diagrams of Pearce et al. [Journal of Petrology, v. 25, p. 956–983] for granitic rocks were first evaluated using the literature cited by these authors as well as from our new database. The first diagram (Y?Nb) cannot discriminate volcanic-arc and collision settings. Both Y?Nb and Yb?Ta diagrams have an overlapping field for within-plate and ocean-ridge granitoids. The remaining two diagrams (Y?+?Nb?Rb and Yb?+?Ta?Rb) use a mobile element (Rb) in their y-axis. Although these diagrams successfully discriminate volcanic-arc and within-plate granites, they perform less well for collision tectonics. Besides, felsic or acid rocks are scarce in ocean-ridge settings, which limits the usefulness of these diagrams for this geological environment. Therefore, using an extensive database, we proposed a set of five new discriminant-function-based multi-dimensional diagrams for acid magmas from four tectonic settings (island arc, continental arc, continental rift, and collision). The very similar tectonic settings of island and continental arcs are discriminated for the first time. These diagrams are based on correct statistical treatment of compositional data, because they use natural logarithm transformation of major-element ratios and linear discriminant analysis (LDA). The use of discordant outlier-free samples prior to LDA improved the success rates by about 3–5%. Success rates of these diagrams as inferred from a testing set were between 76% and 88% for island arc, 60% and 92% for continental arc, and 72% and 84% for both continental rift and collision settings. Finally, application of these new diagrams to case studies not compiled in our initial database used for constructing these diagrams provided the following results: a collision setting for the Himalayas at about 30 Ma; an island arc setting for Quaternary acid rocks from geothermal boreholes in El Salvador; an island- or continental-arc setting for northern Italy at 35–52 Ma; a continental-arc setting for the Italy–Austria border at about 30 Ma; either a rift or a collision setting for northern Nigeria at about 164 Ma; a collision setting for central Nigeria at about 144 Ma and for the Cretaceous Masirah ophiolites of Oman; and an island arc setting for the Cretaceous Semail ophiolites of Oman. In spite of the relative mobility of major elements, these applications suggest utility of the new discrimination diagrams for all four tectonic settings.     

Physical sedimentology experiments with sulfuric acid solutions: Implications for Mars?

Physical sedimentology experiments have shown that sulfuric acid solutions may have formed some surface features seen on Mars. Recent data returned from Mars show the presence of jarosite, sulfate salts, hematite, phyllosilicates, and opaline silica, all of which precipitate from some terrestrial sulfuric acid solutions. There is a plethora of geochemical, mineralogical, and sedimentological data indicative of past sulfuric acid systems on Mars, but there has never been a comprehensive study published regarding sulfuric acid as a physical sedimentological agent. In the laboratory, we ran liquids of various compositions over sediments in order to test how these liquids entrain, transport, and deposit sediments. Pure water and concentrated sulfuric acid solutions produced the same general features, such as channels, gullies, and alluvial fans. However, sulfuric acid solutions yielded some distinct sedimentary features not produced by pure water runs. These features, narrow, deeply incised channels of consistent widths, rounded discrete fans, and air bubble “craters”, are similar to some Martian landscape features. These experimental results indicate that acid solutions should be considered a possible sedimentological agent on Mars.     

Simulation of the dissolution of weathered versus unweathered limestone in carbonic acid solutions of varying strength

A simulation was undertaken within a climatic chamber to investigate limestone dissolution under varied carbonic acid (H₂CO₃) strengths as a possible analogue for future increases in atmospheric CO₂ arising from global warming. Twenty‐eight samples cut from a block of Bath (Box Hill) limestone from Somerville College, Oxford, which had been removed during restoration after 150 years in an urban environment, were weighed and placed in closed bottles of thin plastic containing varying concentrations of H₂CO₃. Half of the stone samples were derived from exposed surfaces of the stone block (weathered) while the others were obtained from the centre of the block on unexposed surfaces (unweathered). The purpose of this was to compare dissolution of previously weathered versus unweathered surfaces in strong (pH 4·73) versus weak (pH 6·43) solutions of H₂CO₃. A temperature of c. 19 °C was maintained within the chamber representing a plausible future temperature in Oxford for the year 2200 given current warming scenarios. The simulation lasted 25 days with a few stone samples being removed midway. Stone samples show reduced weight in all cases but one. There was greater dissolution of stone samples in a strong H₂CO₃ solution as conveyed by higher concentrations of total hardness and Ca²⁺ in the water samples as well as enhanced microscopic dissolution features identified using SEM. The simulation confirms that enhanced atmospheric CO₂ under global warming, given adequate moisture, will accelerate dissolution rates particularly of newly replaced limestone building stones. However, previously weathered surfaces, such as those on historical stone exposed for a century or more, appear to be less susceptible to the effects of such increased rainfall acidity. Conservation techniques which remove weathered surfaces, such as stone cleaning, may accelerate future decay of historical limestone structures by increasing their susceptibility to dissolution. Copyright © 2006 John Wiley & Sons, Ltd.