煤中硫研究现状

从煤中的无机硫、有机硫、亲硫元素及煤中硫成因等四方面总结了煤中硫的研究现状。     

中国硫的供求现状和展望

从工业和农业两个方面供需现状分析，中国目前硫的供需基本平衡，且供略大于求。展望２０００年，中国硫的供求关系将出现缺口，需进一步开拓硫的潜在资源。从总体上看，目前中国土壤供硫情况尚好，但一些地区已开始出现缺硫和严重缺硫的状况，预测今后土壤缺硫状况将会加剧，希望各有关部门对此应给予充分注意     

微波炉在重量法测定硫中的应用

采用玻璃砂芯坩埚过滤BaSO_4沉淀,微波炉代替马弗炉恒重坩埚、沉淀,重量法测定了矿石中的硫。方法准确,精密度好。微波炉不需预先升温,加热6min可达恒重,省时、省电。     

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.     

Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan

 Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically. Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve the accuracy of future groundwater-simulation and management models in the plain. Received, April 1996 Revised, March 1997, November 1997 Accepted, March 1998     

Solute and isotope constraint of groundwater recharge simulation in an arid environment,Abu Dhabi Emirate,United Arab Emirates

A simple, well-constrained simulation of solute increases in a downgradient direction was used in the shallow unconfined aquifer of eastern Abu Dhabi Emirate (United Arab Emirates). The simulation indicates that the observed exponential increase in solute concentrations results from a combination of upward transport of solutes from underlying mudstones and evaporites, and groundwater losses by evaporation. Groundwater recharge and discharge flux in unconfined regional aquifers in arid regions commonly are difficult to estimate because there are few constraints on the flux of water lost or gained from the system. Total dissolved solids (TDS) and deuterium isotopes (δ²H) in groundwater are used to constrain estimated fluxes to the shallow aquifer of eastern Abu Dhabi Emirate. Vertical upward transport of solutes from underlying mudstones and evaporites accounts for solute increases along approximately the first 80 km of the simulated flow path, but a combination of upward solute transport and evaporation is necessary to explain observed solute concentrations beyond 80 km. Mobilization and transport of solutes in the unsaturated zone by recharging precipitation is not a significant factor.

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Résumé Une simulation simple et bien contrainte de l’augmentation des solutés dans la direction de l’écoulement a été réalisée sur l’aquifère phréatique et libre de l’Est de l’émirat d’Abu Dhabi (émirats Arabes Unis). La simulation indique que l’augmentation observée de solutés, de forme exponentielle, est le produit de la combinaison du transport ascendant de solutés provenant des mudstones et des évaporites sous-jacents, et de l’évaporation des eaux souterraines. La recharge des eaux souterraines et les flux de vidange dans les aquifères régionaux libres des régions arides sont habituellement difficiles à estimer du fait du peu de contraintes agissant sur la perte ou le gain d’eau dans le système. La charge dissoute totale (TDS, en anglais) et les isotopes deutérium (δ²H) des eaux souterraines sont utilisés pour contraindre l’estimation des flux en direction de l’aquifère phréatique de l’Est de l’émirat d’Abu Dhabi. Le transport vertical ascendant des solutés à partir des mudstones et des évaporites fait parti des processus qui concentrent les solutés approximativement le long des 80 premiers kilomètres du trajet des écoulements simulés, mais une combinaison du transport ascendant des solutés et de l’évaporation est nécessaire pour expliquer les concentrations observées en soluté au delà des 80 km. La mobilisation et le transport des solutés par les précipitations efficaces dans la zone non saturée ne représentent pas des facteurs significatifs.

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Resumen Se utilizó una simulación simple y muy restringida, de incrementos de soluto en la dirección del flujo, en el acuífero libre poco profundo del Emirato oriental de Abu Dhabi, (Emiratos árabes Unidos). La simulación indica que el aumento exponencial observado en las concentraciones del soluto, resulta de una combinación de transporte ascendente de solutos desde las evaporitas y lodolitas subyacentes, y por pérdidas del agua subterránea por evaporación. Los flujos de recarga y descarga de agua subterránea, en los acuíferos libres regionales en regiones áridas, normalmente son difíciles estimar, porque hay algunas restricciones en el flujo de agua perdido o ganado por el sistema. Los sólidos disueltos totales (TDS) y los isótopos de deuterio (δ²H) en el agua subterránea, se usan para forzar los flujos estimados hacia el acuífero poco profundo del Emirato oriental de Abu Dhabi. El transporte ascendente vertical de solutos desde las lodolitas y evaporitas subyacentes, involucra los aumentos del soluto a lo largo de aproximadamente los primeros 80 Km. de la dirección de flujo simulada, pero es necesaria una combinación de transporte ascendente del soluto y la evaporación para explicar las concentraciones del soluto observadas más allá de 80 Km. La movilización y transporte de solutos en la zona no saturada, por recarga debida a precipitación, no es un factor significante.

     

Sediment budget-based estimates of trace metal inputs to a Chesapeake estuary

This article evaluates whether a sediment budget for the South River, Maryland, can be coupled with metals data from sediment cores to identify and quantify sources of historic metal inputs to marsh and subtidal sediments along the estuary. Metal inputs to estuarine marsh sediments come from fluvial runoff and atmospheric deposition. Metal inputs to subtidal sediments come from atmospheric deposition, fluvial runoff, coastal erosion, and estuarine waters. The metals budget for the estuary indicates that metal inputs from coastal erosion have remained relatively constant since 1840. Historical variations in metal contents of marsh sediments have probably resulted primarily from increasing atmospheric deposition in this century, but prior to 1900 may reflect changing fluvial sources, atmospheric inputs, or factors not quantified by the budget. Residual Pb, Cu, and Zn in the marsh sediments not accounted for by fluvial inputs was low to moderate in 1840, decreased to near zero circa 1910, and by 1987 had increased to levels that were one to ten times greater than those of 1840. Sources of variability in subtidal cores could not be clearly discerned because of geochemical fluxes, turbulent mixing, and bioturbation within the cores. The sediment-metal budgeting approach appears to be a viable method for delineating metal sources in small, relatively simple estuarine systems like the South River and in systems where recent deposition (for example, prograding marshes) prevents use of deep core analysis to identify background levels of metal. In larger systems or systems with more variable sources of sediment and metal input, however, assumptions and measurement errors in the metal budgeting approach suggest that deep core analysis and normalization techniques are probably preferable for identifying anthropogenic impacts.Field and laboratory research conducted at the Department of Geography, University of Maryland, College Park, Maryland, 20742, USAField and laboratory research conducted at the Marine and Estuarine Environmental Science Program, University of Maryland, College Park, Maryland, 20742, USA     

内蒙古乌拉山石英－钾长石脉金矿床铅和硫同位素研究

内蒙古乌拉山金矿床是近年在我国北方发现的大型金矿床之一。矿床主要由赋存在太古界乌拉山群变质岩地层中一系列石英－钾长石脉和石英脉组成。矿区范围内晚古生代—中生代花岗岩类分布广泛并且同金矿化具密切时、空分布关系。本文对乌拉山金矿床，大桦背花岗岩体和变质岩地层的硫、铅同位素比值进行了系统测定，并解释了不同地质体硫、铅同位素变化特征。研究表明：金成矿作用发生在２４０×１０￣６ａ，成矿物质主要来自大桦背花岗岩体及有关的岩脉，乌拉山金矿床形成过程中，亦有部分非岩浆物质混入。     

Estimate of shallow groundwater recharge in the Hadejia–Nguru Wetlands, semi-arid northeastern Nigeria

 The Hadejia–Nguru Wetlands are annually inundated flood plains in semi-arid northeastern Nigeria. The area has a unique ecosystem that forms a natural barrier against the encroachment of the Sahara desert. Both the rich wetland vegetation and local farmers using shallow tube wells depend on a groundwater mound (with a water table less than 6 m below the surface) that is present in the unconfined aquifer under the flood-plain area. Using well records (1991–97) and a hydrogeologic profile based on piezometers that were monitored for two years, it is shown that recharge through the annually inundated flood plains is the source of the groundwater mound. Maintenance of the groundwater-recharge function of the flood plains depends on wet-season releases from two large upstream dams. On the basis of a water-budget method, the mean (1991–97) wet-season unconfined groundwater recharge in the flood-plain area between Hadejia and Nguru and in the immediate vicinity (1250 km²) is estimated to be 132 mm (range, 73–197 mm). Outflow from the unconfined flood-plain aquifer to the unconfined upland aquifer is approximately 10% of the wet-season flood-plain recharge. The unconfined groundwater outflow from the flood-plain area can provide a significant contribution to the present-day rural water supply in the surrounding uplands, but it does not offer much potential for additional groundwater abstraction. In addition to outflow to the upland aquifer (∼14 mm), the distribution of the annually recharged water volume of the shallow flood-plain aquifer is (1) domestic uses (3 mm), (2) small-scale irrigation (∼15 mm), and (3) evapotranspiration ( 1 100 mm). Along the hydrogeologic profile, the recharge in the upland (i.e., outflow from the unconfined flood-plain aquifer and possibly diffuse rain-fed recharge) is in balance with the water uses (i.e., domestic uses, groundwater outflow, and evapotranspiration). The absence of a seasonal water-level trend in the two piezometers in the upland indicates that no rain-fed recharge occurs through preferential path-way (macropore) flow. Received, June 1998 / Revised, November 1998, January 1999 / Accepted, January 1999     

Evolution of Hydrothermal System at the Dizon Porphyry Cu-Au Deposit, Zambales, Philippines

Abstract. Evolution of hydrothermal system from initial porphyry Cu mineralization to overlapping epithermal system at the Dizon porphyry Cu‐Au deposit in western central Luzon, Zambales, Philippines, is documented in terms of mineral paragen‐esis, fluid inclusion petrography and microthermometry, and sulfur isotope systematics. The paragenetic stages throughout the deposit are summarized as follows; 1) stockwork amethystic quartz veinlets associated with chalcopyrite, bornite, magnetite and Au enveloped by chlorite alteration overprinting biotite alteration, 2) stockwork quartz veinlets with chalcopyrite and pyrite associated with Au and chalcopyrite and pyrite stringers in sericite alteration, 3) stringer quartz veinlets associated with molybdenite in sericite alteration, and 4) WNW‐trending quartz veins associated with sphalerite and galena at deeper part, while enargite and stibnite at shallower levels associated with advanced argillic alteration. Chalcopyrite and bornite associated with magnetite in quartz veinlet stockwork (stage 1) have precipitated initially as intermediate solid solution (iss) and bornite solid solution (bnss), respectively. Fluid inclusions in the stockwork veinlet quartz consist of gas‐rich inclusions and polyphase inclusions. Halite in polyphase inclusions dissolves at temperatures ranging from 360d?C to >500d?C but liquid (brine) and gas (vapor) do not homogenize at <500d?C. The maximum pressure and minimum temperature during the deposition of iss and bnss with stockwork quartz veinlets are estimated to be 460 bars and 500d?C. Fluid inclusions in veinlet stockwork quartz enveloped in sericite alteration (stage 2) consist mainly of gas‐rich inclusions and polyphase inclusions. In addition to the possible presence of saturated NaCl crystals at the time of entrapment of fluid inclusions that exhibit the liquid‐vapor homogenization temperatures lower than the halite dissolution temperatures in some samples, wide range of temperatures of halite dissolution and liquid‐vapor homogenization of polyphase inclusions from 230d?C to >500d?C and from 270d?C to >500d?C, respectively, suggests heterogeneous entrapment of gaseous vapor and hypersaline brine. The minimum pressure and temperature are estimated to be about 25 bars and 245d?C. Fluid inclusions in veinlet quartz associated with molybdenite (stage 3) are dominated by gas‐rich inclusions accompanied with minor liquid‐rich inclusions that homogenize at temperatures between 350d?C and 490d?C. Fluid inclusions in vuggy veinlet quartz associated with stibnite (stage 4) consist mainly of gas‐rich inclusions with subordinate polyphase inclusions that do not homogenize below 500d?C. Fluid inclusions in veinlet quartz associated with galena and sphalerite (stage 4) are composed of liquid‐rich two‐phase inclusions, and they homogenize into liquid phase at temperatures ranging widely from 190d?C to 300d?C (suggesting boiling) and the salinity ranges from 1.0 wt% to 3.4 wt% NaCl equivalent. A pressure of about 15 bars is estimated for the dilute aqueous solution of 190d?C from which veinlet quartz associated with galena and sphalerite precipitated. In addition to a change in temperature‐pressure regime from lithostatic pressure during the deposition of iss and bnss with stockwork quartz veinlets to hydrostatic pressure during fracture‐controlled quartz veinlet associated with galena and sphalerite, a decrease in pressure is supposed to have occurred due to unroofing or removal of the overlying piles during the temperature decrease in the evolution of hydrothermal system. The majority of the sulfur isotopic composition of sulfides ranges from ±0 % to +5 %. Sulfur originated from an iso‐topically uniform and homogeneous source, and the mineralization occurred in a single hydrothermal system.