Experimental characterization of the impact of temperature and humidity on the breakdown of soil water repellency in sandy soils and composts

Soil water repellency is a widespread phenomenon with the capacity to alter hydrological and geomorphological processes. Water repellency decays with time, and the consequences are only of concern during the timescale at which the water repellency persists. This study aimed to characterize the influence of temperature and humidity on the breakdown of water repellency. Apparent contact angle measurements were carried out on samples consisting of sand treated with stearic acid as well as naturally repellent dune sands and composts. Temperature and humidity were controlled using a cooled incubator and a purpose designed enclosed box in which humidity could be raised or lowered. Results showed the contact angle of the stearic‐acid‐treated sands decayed with time and that there was a significant increase with stearic acid concentration. For all samples, the decay in apparent contact angle could be described with a continuous breakdown model. The stearic‐acid‐treated sands showed a significant increase in contact angle with relative humidity at a temperature of 10 and 20 °C. These differences diminished with increasing temperature. Similar results were seen for the dune sands and composts. Despite the influence of temperature and humidity on contact angles, there was no significant change in the rate at which the contact angle decayed in any sample. Absolute humidity was found to provide a more relevant indicator than relative humidity when assessing the influence of humidity on repellency over a range of temperatures. The contact angle initially increased with absolute humidity before plateauing owing to the confounding effect of temperature. Copyright © 2014 John Wiley & Sons, Ltd.     

A long‐term study of stable isotopes as tracers of processes governing water flow and quality in a lowland river basin: the upper Thames,UK

A long‐term study of O, H and C stable isotopes has been undertaken on river waters across the 7000‐km² upper Thames lowland river basin in the southern UK. During the period, flow conditions ranged from drought to flood. A 10‐year monthly record (2003–2012) of the main River Thames showed a maximum variation of 3‰ (δ¹⁸O) and 20‰ (δ²H), although interannual average values varied little around a mean of –6.5‰ (δ¹⁸O) and –44‰ (δ²H). A δ²H/δ¹⁸O slope of 5.3 suggested a degree of evaporative enrichment, consistent with derivation from local rainfall with a weighted mean of –7.2‰ (δ¹⁸O) and –48‰ (δ²H) for the period. A tendency towards isotopic depletion of the river with increasing flow rate was noted, but at very high flows (>100 m³/s), a reversion to the mean was interpreted as the displacement of bank storage by rising groundwater levels (corroborated by measurements of specific electrical conductivity). A shorter quarterly study (October 2011–April 2013) of isotope variations in 15 tributaries with varying geology revealed different responses to evaporation, with a well‐correlated inverse relationship between Δ¹⁸O and baseflow index for most of the rivers. A comparison with aquifer waters in the basin showed that even at low flow, rivers rarely consist solely of isotopically unmodified groundwater. Long‐term monitoring (2003–2007) of carbon stable isotopes in dissolved inorganic carbon (DIC) in the Thames revealed a complex interplay between respiration, photosynthesis and evasion, but with a mean interannual δ¹³C‐DIC value of –14.8 ± 0.5‰, exchange with atmospheric carbon could be ruled out. Quarterly monitoring of the tributaries (October 2011–April 2013) indicated that in addition to the aforementioned factors, river flow variations and catchment characteristics were likely to affect δ¹³C‐DIC. Comparison with basin groundwaters of different alkalinity and δ¹³C‐DIC values showed that the origin of river baseflow is usually obscured. The findings show that long‐term monitoring of environmental tracers can help to improve the understanding of how lowland river catchments function. Copyright © NERC 2015. Hydrological Processes © 2015 John Wiley & Sons, Ltd.     

Investigation of the elevation of saltwater wedge due to subsurface dams

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.     

Divergence and flow direction as indicators of subsurface heterogeneity and stage‐dependent storage in alluvial floodplains

Assuming homogeneity in alluvial aquifers is convenient, but limits our ability to accurately predict stream‐aquifer interactions. Research is needed on (i) identifying the presence of focused, as opposed to diffuse, groundwater discharge/recharge to streams and (ii) the magnitude and role of large‐scale bank and transient storage in alluvial floodplains relative to changes in stream stage. The objective of this research was to document and quantify the effect of stage‐dependent aquifer heterogeneity and bank storage relative to changes in stream stage using groundwater flow divergence and direction. Monitoring was performed in alluvial floodplains adjacent to the Barren Fork Creek and Honey Creek in northeastern Oklahoma. Based on results from subsurface electrical resistivity mapping, observation wells were installed in high and low electrical resistivity subsoils. Water levels in the wells were recorded real time using pressure transducers (August to October 2009). Divergence was used to quantify heterogeneity (i.e. variation in hydraulic conductivity, porosity, and/or aquifer thickness), and flow direction was used to assess the potential for large‐scale (100 m) bank or transient storage. Areas of localized heterogeneity appeared to act as divergence zones allowing stream water to quickly enter the groundwater system, or as flow convergence zones draining a large groundwater area. Maximum divergence or convergence occurred with maximum rates of change in flow rates or stream stage. Flow directions in the groundwater changed considerably between base and high flows, suggesting that the floodplains acted as large‐scale bank storage zones, rapidly storing and releasing water during passage of a storm hydrograph. During storm events at both sites, the average groundwater direction changed by at least 90° from the average groundwater direction during baseflow. Aquifer heterogeneity in floodplains yields hyporheic flows that are more responsive and spatially and temporally complex than would be expected compared to more common assumptions of homogeneity. Copyright © 2012 John Wiley & Sons, Ltd.     

Exploring the interaction of surface roughness and slope gradient in controlling rates of soil loss from sloping farmland on the Loess Plateau of China

Surface roughness and slope gradient are two important factors influencing soil erosion. The objective of this study was to investigate the interaction of surface roughness and slope gradient in controlling soil loss from sloping farmland due to water erosion on the Loess Plateau, China. Following the surface features of sloping farmland in the plateau region, we manually prepared rough surfaces using four tillage practices (contour drilling, artificial digging, manual hoeing, and contour plowing), with a smooth surface as the control measure. Five slope gradients (3°, 5°, 10°, 15°, and 20°) and two rainfall intensities (60 and 90 mm/hr) were considered in the artificial rainfall simulation experiment. The results showed that the runoff volume and sediment yield increased with increasing slope gradient under the same tillage treatment. At gentle slope gradients (e.g., 3° and 5°), the increase in surface roughness prevented the runoff and sediment production, that is, the surface roughness reduced the positive effect of slope gradient on the runoff volume and sediment yield to a certain extent. At steep slope gradients, however, the enhancing effect of slope gradient on soil erosion gradually increased and surpassed the reduction effect of surface roughness. This study reveals the existence of a critical slope gradient that influences the interaction of surface roughness and slope gradient in controlling soil erosion on sloping farmland. If the slope gradient is equal to or less than the critical value, an increase in surface roughness would decrease soil erosion. Otherwise, the increase in surface roughness would be ineffective for preventing soil erosion. The critical slope gradient would be smaller under higher rainfall intensity. These findings are helpful for us to understand the process of soil erosion and relevant for supporting soil and water conservation in the Loess Plateau region of China.     

相对湿度和PM2.5浓度对大气能见度的影响研究:基于小时资料的多站对比分析

为了全面分析浙江省不同区域能见度变化基本特征及影响机理,基于杭州、宁波、温州3个国家基本气象站2013-2014年逐时能见度观测资料,比较分析了3市能见度变化的基本特征。发现3市不同等级能见度出现频率基本一致,随着能见度等级的提高,出现频率逐渐降低;从能见度的日变化来看,07时（北京时）前后最低,之后缓慢上升,14-15时达到最高,随后逐渐下降;全年有两个能见度较低时段,分别出现在12月-次年2月和5-6月;总体而言,宁波能见度最优,杭州和温州大体相当。功率谱分析结果表明,3市能见度均有显著的日周期,高频波段呈现出多个显著谱峰,低频波段存在若干显著谱峰。进一步开展机理分析,发现相对湿度和PM_2.5浓度是调制大气能见度的关键因子,相对湿度增大、PM_2.5浓度升高导致能见度降低。在同一相对湿度等级下,初始阶段能见度随PM_2.5浓度的升高迅速降低,到达“拐点”之后降低速率趋于缓慢。在同一PM_2.5浓度水平下,相对湿度越大,能见度越低,说明水汽对能见度也有重要影响。基于相对湿度和PM_2.5浓度两个因子,采用非线性拟合方案构建了大气能见度定量统计模型,总体而言模型拟合效果较好。最后针对研究中存在的不足和未来值得进一步发掘的科学问题进行了讨论。     

中国中东部冬季霾日的形成与东亚冬季风和大气湿度的关系

利用1961-2013年中国地面台站长期观测资料和同期NCEP/NCAR再分析资料,以华北、江淮和华南为研究区,分析了中国中东部冬季霾日的形成与东亚冬季风以及大气湿度的关系。结果表明:(1)冬季霾日与东亚冬季风强度成显著的负相关。首先,东亚冬季风强度的减弱使得地面风速减小,进而导致冬季霾日增多。其中,华北7-8 m/s最大风速日数和江淮6-8 m/s最大风速日数的减少,及华南≤2 m/s最大风速日数的增多对各区冬季霾日的增多作用较大。其次,东亚冬季风减弱引起冬季气温的持续升高,易导致冬季霾日的增多,这在华北地区较之在江淮和华南更为明显。(2)由于气候变暖,冬季气温升高,使得近地面相对湿度减小。在江淮和华南地区,冬季霾日的增多与近地面相对湿度的减小显著相关,而在华北地区这种相关较弱。(3)冬季气温升高也有利于大气层结稳定度的增强,3个区域冬季霾日的增多均与大气层结稳定度的增强显著相关,特别是与对流层中低层(850-500 hPa)大气饱和度的降低显著相关。(4)冬季霾日数变化与区域水汽输送关系密切。其中,华北地区的冬季霾日数与水汽总收入成显著正相关,江淮地区与纬向水汽收入成显著正相关,与经向水汽收入成显著负相关,华南地区与经向水汽收入成显著负相关。     

中国东部夏季暴雨的年代际跃变及其大尺度环流背景

本文利用1960~2011年中国东部地面测站的逐日降水资料和JRA-55再分析资料探讨了夏季暴雨分布的年代际跃变及其相关联的大尺度环流异常特征。基于暴雨频数和占比(夏季暴雨占比是指5~8月暴雨降水量对总降水量的贡献百分比)的分析结果表明:中国东部夏季暴雨分布在20世纪70年代末和90年代初经历两次反相的经向"三极子"跃变。中国东部夏季暴雨的年代际演变过程可分为三个时段:1960~1979年为华南和华北暴雨偏多、江淮流域暴雨偏少的经向"三极子"分布;1980~1991年为南方和华北暴雨偏少、江淮流域暴雨偏多的经向三极子"分布;1992~2011年为南方暴雨显著偏多、华北暴雨持续偏少,逐渐形成经向"偶极子"分布,并导致近十多年我国夏季"南涝北旱"的整体格局。1970年代末(1990年代初)跃变相关联的大尺度环流异常配置:东亚夏季风的减弱(增强),西太平洋副高的增强西伸但南撤(北抬),南亚高压的减弱南缩(增强东扩),以及蒙古高原中低层的气旋式(反气旋式)环流异常。与此同时,低层局地环流也发生调整:华北和黄淮地区以及华南和江南地区均为反气旋式(气旋式)环流异常,而江淮流域和四川盆地受控于风场切变式辐合(辐散)异常;涡度场发生相应变化,南北方大部分地区的负(正)涡度异常不(有)利于低涡的发展,而江淮流域和四川盆地的正(负)涡度异常有(不)利于低涡的发展,进而引发江南和华南暴雨减少(增加)、江淮流域和四川盆地暴雨增加(减少)、黄淮和华北暴雨减少(增加)的经向"三极子"跃变。     

南海海岛自动气象站防护应用技术探索

立足海南及南海的自然条件,结合海岛自动气象站在南海高温、高湿、高盐雾、强辐射、强风等恶劣气候环境下使用情况,通过对历年来海岛自动气象站故障及失效模式的统计和分析,总结分析故障原因。根据设备维护人员多年气象设备保障工作积累总结的经验,从海岛自动气象站结构和防护要求出发,集成应用市场上优质材料、先进工艺和多种成熟、关键设备防护技术,形成一些气象设备防护的有效方法措施,以提高海岛自动气象站对海洋环境的适应性和性能,延长设备使用寿命。     

利用引力梯度数据计算径向梯度的优化方法

根据重力梯度观测各分量的方差及协方差信息,提出了利用GOCE梯度数据计算径向重力梯度的优化方法。首先给出了径向重力梯度的计算方法,并深入分析了误差传播规律,通过建立相应的条件极值问题,给出了计算径向重力梯度最优组合因子的方法;通过模拟数据验证了本文所提出的优化因子的优越性。实际数据计算表明:相对于传统方法,采用优化组合因子可使反演所得引力位模型的累积大地水准面精度在250阶时提高约2 cm。由于径向重力梯度不仅可以用于地球引力场模型的求解,也可直接应用于地球物理问题的讨论,因此本文所提出的优化方法也可对部分地球动力学问题的讨论提供方便。