Shrinking Sphere Kinetics for Batch Dissolution of Mixed Particles of a Single Substance at High Under-Saturation: Validation with Sodium Chloride, but with Biogenic Silica in Mind

The cubic equation recently derived for the increase in concentration of a solute with time, as the solid dissolves in batch according to the shrinking sphere model at high under-saturation, is extended to dissolutions of mixtures of differently sized particles. This problem needs to be solved if batch dissolutions are to play their part in the proposed amelioration of global warming and associated climate change by accelerated ‘re-burial’ of excess CO₂ in ocean sediment. The upgraded model was tested using sodium chloride dissolved in 50% aqueous propanone, whence the model fitted two separate runs with 500 and 212 μm, and 212 and 38 μm, diameter crystals, respectively. The key to simulating dissolution in this way lies in the dissolutions being independent of each other. It is further shown that although this condition was implicit in the recent derivation of the cubic equation, it was not recognised at the time. The work should be applicable to any batch dissolution of mixed particles at high under-saturation, and hence, may find use in many industrial and laboratory dissolutions. Simulations show how agglomerated mixtures can yield a straight line on the plot of ln(1 − C/C _T) versus time, as was reported to occur recently with sodium chloride taken ‘straight from the bottle’. It is shown that this probably explains why exponential dissolutions may have seemed appropriate to the dissolution of biogenic silica in earlier literature. This study suggests that a new round of biogenic silica dissolutions, but with sieved samples, would be worthwhile, with the likelihood that shrinking sphere behaviour might well be found to characterise the kinetics. The opportunity is taken to investigate a number of aspects of the shrinking sphere model not generally discussed before, e.g. the graph for the change in surface area with time. The limitations of using cubic salt crystals with the shrinking sphere model are discussed.     

螺纹插装阀在煤矿坑道钻机中的应用

介绍了螺纹插装阀的技术特点及其在煤矿坑道钻机中的发展应用情况。煤矿坑道钻机应用螺纹插装阀技术不仅可以实现复杂的液压控制系统,还能简化管路,方便整机布局。通过几个典型实例展示了螺纹插装阀在煤矿坑道钻机中的具体应用情况,验证了螺纹插装阀技术在煤矿坑道钻机液压系统中的实用性和良好的应用前景。      

Sources of dissolved silica to the fjords of northern Patagonia (44–48°S): the importance of volcanic ash soil distribution and weathering

Dissolved silica (DSi) plays an important biogeochemical role in the fjords of northern Chilean Patagonia (44–48°S), where it drives high biogenic productivity and promotes carbon burial. It is generally believed that the DSi riverine input to lakes and coastal environments is controlled by a combination of factors including lithology, climate, topography, vegetation, and meltwater input. In northern Chilean Patagonia several authors have proposed that the postglacial volcanic ash soils (andosols) may play a significant role in the high supply of DSi to the regional fjords. To assess the influence of andosols on DSi concentrations in north Patagonian rivers, we mapped andosol thickness and compared our results with river chemistry. The mineralogical and geochemical composition of three representative andosol profiles was also examined to evaluate the efficiency of weathering processes. The andosol thickness map clearly demonstrates that volcanic ash was predominantly deposited on the eastern side of the regional volcanoes, reflecting the influence of the prevailing westerly winds on the distribution of pyroclastic material. Mineralogical and geochemical results show that the andosol parent material has the typical andesitic basaltic signature of the regional volcanoes, i.e. high amounts of amorphous material, plagioclase, K‐feldspar, and pyroxene. Down‐profile variations in soil mineralogy and geochemistry indicate increased leaching of silica with depth, resulting from weathering of the volcanic parent material. For the five studied watersheds, a highly positive correlation (R²=0.98) was found between average andosol thickness and DSi concentrations, suggesting that andosol thickness is the main parameter affecting DSi concentrations in north Patagonian river systems. On seasonal timescales, increased precipitation (winter) and glacial meltwater (summer) input can significantly reduce DSi concentrations. We argue that the weathering of andosols constitutes the most important source of DSi to the lakes and fjords of northern Chilean Patagonia, explaining the particularly high regional rates of biogenic silica production. Copyright © 2015 John Wiley & Sons, Ltd.     

应用钻石观测仪-红外光谱仪-激光诱导击穿光谱仪鉴定无机材料充填翡翠

通过走访翡翠市场得知存在无机材料充填的翡翠,目前与其相关的研究资料较少,对无机材料充填翡翠缺少鉴定依据.本模拟实验使用水玻璃和硅溶胶这两类无机材料对低档翡翠进行充填以了解其鉴定特征.利用常规宝石学测试、钻石观测仪荧光观察、红外光谱分析(FTIR)、激光诱导击穿光谱分析(LIBS)对无机充填翡翠样品进行测试.结果表明:①...     

A 2000 year record of climatic change at Ongoke Lake,southwest Alaska

We analyzed sediments of the past 2000 years from Ongoke Lake, southwest Alaska, for organic carbon, organic nitrogen, biogenic silica (BSi), and diatom assemblages at decadal to centennial resolution to infer limnological changes that may be related to climatic variation in southwestern Alaska. The chronology is based on a ²¹⁰Pb profile from bulk sediments and nine AMS ¹⁴C ages from terrestrial plant macrofossils. Four of the ¹⁴C ages span a core depth interval of 60.5 cm but are statistically indistinguishable from one another with a mean of ~1300 AD, which compromises the determination of temporal trends at Ongoke Lake and comparison with other paleoclimate records. The diatom record suggests changes in the duration of ice cover and strength of thermal stratification that are probably related to temperature variation. This variation includes a cold interval around the first millennium cooling (FMC) and a warm interval spanning the medieval climate anomaly (MCA). However, the lake-sediment record shows no clear signals of temperature variation for the period of the Little Ice Age (LIA) or the twentieth century. Climatic changes during these periods may have been manifested through effective-moisture (precipitation minus evapotranspiration) variation in the Ongoke Lake area. We estimate water depths and infer effective-moisture fluctuations by applying a regional transfer function to our diatom record. Together with inferences from diatom autecologies, this water-depth reconstruction suggests that effective moisture increased steadily from 50 BC to 350 AD, which was followed by relatively dry conditions between 550 and 750 AD and relatively wet conditions between 750 and 1450 AD. Effective moisture was low from ~1450 to 1850 AD, coinciding with the LIA; an alternative age model places this interval between ~1315 and 1850 AD. During the past 150 years, effective moisture increased, with estimated water depths reaching peak values in the second half of the twentieth century. This study offers the first paleolimnological record for inferring centennial-scale climatic variation over the past two millennia from southwestern Alaska.

The genesis of the carbonatized and silicified ultramafics known as listvenites: a case study from the Mihalıççık region (Eskişehir), NW Turkey

The Mihalıççık region (Eskişehir) in NW Turkey includes an ophiolitic assemblage with a serpentinite‐matrix mélange. The serpentinites of this mélange host silica‐carbonate metasomatites which were previously named as listvenites. Our mineralogical and geochemical studies revealed that these alteration assemblages represent members of the listvenitic series, mainly the carbonate rocks, silica‐carbonate rocks and birbirites, rather than true listvenites (sensu stricto). Tectonic activity and lithology are principal factors that control the formation of these assemblages. Carbonatization and silicification of the serpentinite host‐rock is generated by CO₂, SiO₂‐rich H₂O hydrothermal fluid which includes As, Ba, Sb and Sr. Low precious metal (Au, Ag) contents of the alteration assemblages indicate lack of these metals in the fluid. Primary assemblages of the alteration are carbonate rocks that are followed by silica‐carbonate rocks and birbirites, respectively. Petrographic studies and chemical analyses suggested an alkaline and moderate to high temperature (350–400°C) fluid with low oxygen and sulphur fugacity for the carbonatization of the serpentinites. The low temperature phases observed in the subsequent silicification indicated that the fluid cooled during progressive alteration. The increasing Fe‐oxide content and sulphur phases also suggested increasing oxygen and sulphur fugacity during this secondary process and silica‐carbonate rock formation. The occurrence of birbirites is considered as a result of reactivation of tectonic features. These rocks are classified in two sub‐groups; the Group 1 birbirites show analogous rare earth element (REE) trends with the serpentinite host‐rock, and the Group 2 birbirites simulate the REE trends of the nearby tectonic granitoid slices. The unorthodox REE trend of Group 2 birbirites is interpreted to have resulted from a mobilization process triggered by the weathering solutions rather than being products of enrichment by the higher temperature hydrothermal activity. Copyright © 2006 John Wiley & Sons, Ltd.     

The role of diatoms, dissolved silicate and Antarctic glaciation in glacial/interglacial climatic change: a hypothesis

A new theory is proposed to explain global cooling at the onset of Pleistocene glacial periods. Atmospheric CO₂ drawdown is considered to be the driving force behind global cooling, brought about by heightened productivity at the equatorial divergences and along continental margins, particularly in upwelling regions. Eutrophication appears to be triggered when global warming during late interglacial periods causes accelerated melting of the West Antarctic Ice Sheet. This would release large reserves of silicate-enriched subglacial meltwaters into the surrounding oceans where entrainment would take place into deep and intermediate currents forming in Antarctic and subantarctic waters. Subsequent advection, mixing and upwelling of silicate-enriched deep and intermediate waters into the coastal zones and open-ocean divergences results in the proliferation of large, rapidly-sinking diatom species with a high affinity for dissolved silicate. These blooms enhance rates of recycling of N and P in upwelling regions and accelerate rates of organic carbon production, export and sequestration in shelf and slope sediments and in the deep sea. The resultant atm. CO₂ drawdown initiates global cooling. Consequent expansion of Northern Hemisphere glaciers lowers sea level, while increased temperature and pressure gradients between equatorial and polar regions intensify meridional winds. The former process exposes nutrient-enriched coastal sediments to wave erosion, thereby releasing new nutrient supplies, while the latter process enhances upwelling. The combined effect is to greatly increase rates of org. C production and export from continental margins and further accelerate atm. CO₂ drawdown. Glacial-period cooling is also enhanced by a number of other positive feedbacks, including changes in albedo, water vapour and cloud cover. Episodic warming intervals during glacial periods may be related to insolation changes associated with orbital precession and tilt cycles, but processes involved in deglaciation and reversion to the interglacial climatic regime are complex and not yet fully understood.     

On the Stability of the <Emphasis Type="Italic">AlOSi</Emphasis>(<Emphasis Type="Italic">OH</Emphasis>)<Stack><Subscript>3</Subscript><Superscript>2+</Superscript></Stack> Complex in Aqueous Solution

Summary The complexation of aluminium(III) and silicon(IV) was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25 °C. The measurements were performed as potentiometric titrations using a hydrogen electrode with OH ⁻ ions being generated coulometrically. The total concentrations of Si(IV) and Al(III) respectively [Si _tot ] and [Al _t ot], and −log[H ⁺] were varied within the limits 0.3 < [Si _tot ] < 2.5 mM, 0.5 < [Al _tot ] < 2.6 mM, and 2 ≤ -log[H ⁺] ≤ 4.2. Within these ranges of concentration, evidence is given for the formation of an AlSiO(OH) ₃ ²⁺ complex with a formation constant log β_1,1-1 = −2.75 ± 0.1 defined by the reaction Al ³⁺+Si (OH)₄ ↔ AlOSi(OH) ₃ ²⁺ +H ⁺ An extrapolation of this value to I=0 gives log β_1,1-1 = −2.30. The calculated value of log K (Al ³⁺+SiO(OH) ₃ ⁻ ↔ AlOSi(OH) ₃ ²⁺ ) = 6.72 (I=0.6 M) can be compared with corresponding constants for the formation of AlF ²⁺ and AlOH ²⁺ , which are equal to 6.16 and 8.20. Obviously, the stability of these Al(III) complexes decreases within the series OH ⁻>SiO(OH) ₃ ⁻  > F ⁻