Hydraulic and Thermal Conductivities of Kaolin–Silica Mixtures under Different Consolidation Stresses

Stable backfill materials for the heat sensitive structures of buried power cables, hot water pipes, and gas pipelines are suggested to have low permeability and high heat transfer characteristics. The hydraulic and thermal conductivities of backfill materials or clay liners are important parameters in proper design and construction of geotechnical structures involved with heat transfers. In this study, to investigate the optimal natural backfill or liner materials, thermal and hydraulic conductivities of kaolin–silica mixtures examined based on the results from laboratory tests under different consolidation conditions. From the experiment results, the thermal conductivity increases while hydraulic conductivity decreases with increasing density during consolidation process. As a result, back-fill materials with high kaolin content under low consolidation stress were desirable materials for burial of heat sensitive structures.     

生物硅早期成岩作用研究进展

硅质浮游生物是海洋初级生产力的主要提供者,其死亡后所产生的硅质残骸(生物硅)向海底的传输,是保持海洋硅循环动态平衡的重要环节。由于海洋沉积物中的硅质微体生物化石记录了古海洋初级生产力的变化及其时空分布,因而生物硅也成为古环境重建的重要替代指标。本文对生物硅在水柱沉降和表层沉积物埋藏过程中所发生的早期成岩转变及其主要影响因素进行了综述,为全面了解最近几十年来该领域的研究进展提供参考。     

Oligocene biogenic siliceous deposits on the slope of the northern South China Sea

The abundance of radiolarian, diatom and sponge spicule and H₄SiO₄ in pore-waters increase abruptly at the boundary between Early and Late Oligocene (about 30-27.5 Ma) at Site 1148 of the northern South China Sea (SCS), indicating high biogenic silica accumulation during this time. At the same time (about 30-28 Ma), high biogenic silica deposition occurred in the central equatorial Pacific. Comparison of the biogenic silica accumulation at Site 1148 of the SCS with that at Site 929 of the Atlantic verifies that the biogenic silica accumulation between the low latitude Pacific and Atlantic oceans expresses the evident relationship of compensation during the Oligocene. Biogenic silica accumulation decreased in the Atlantic, whereas it increased in the Pacific at the boundary between the Early and Late Oligocene. It resulted from the formation and presence of North Atlantic deep water (NADW) in the Atlantic basin, indicating an intensive basin-basin fractionation. XRD analysis and SEM observation of the samples from Site 1148 demonstrate that most of radiolarian, diatom and sponge spicule have suffered from dissolution and reprecipitation, suggested by the opal-A→opal-CT transformation. As a result of the transformation, porosity increased, but dry and bulk densities decreased, reflecting the consequence of diagenesis on the physical property of sediment.     

南海南部表层沉积物中生物硅的分布及其环境意义

对南海南部25个表层沉积样进行了生物硅的测定分析,试图揭示南海南部表层沉积生物硅的分布及其对现代海洋环境的指示意义,以便为古海洋学研究提供进一步的科学依据。研究发现,表层沉积物中生物硅含量与其所处水深呈显著正相关关系,相关系数达到0.782。陆架浅水区表层沉积物中生物硅含量非常低,不能反映表层水体中硅质生物生产力情况,这可能与沉积类型和陆源物质输入影响有关。深水区表层沉积物中生物硅的含量分布表明,其不仅能反映表层水体中硅质生物的古生产力水平,而且还能指示上升流的强弱,从而进一步证实了利用沉积物中生物硅含量来追踪上升流发育和变化的有效性与可信度。研究结果还显示,在研究区域中北部表层沉积生物硅中放射虫和海绵骨针较硅藻占有更大的比重,这可能是由于硅藻易被溶解并易被其他生物体摄食的缘故。在有上升流发育的海域,放射虫、硅藻和海绵骨针基本上表现出较高的丰度,这与高的生物硅含量相一致。     

Fluid Inclusion Microthermometry and Implications for the Mechanisms of Ore-Grade Gold Mineralization in Epithermal System, Lalab Orebody, Sibutad, Zamboanga del Norte, Philippines

The Sibutad gold deposit has gold associated in quartz veins. The most important of these is the Lalab orebody, which contains ore‐grade gold, predominantly, in milky quartz veins and veinlets. Here, alteration quartz and fine‐grained crystalline clear and milky quartz were formed from hydrothermal fluids in three stages, namely stages I, II and III. Fluid inclusion microthermometry was carried out on stage I milky quartz, stage II fine‐grained alteration quartz and stage III milky quartz ± barite veins and veinlets. Homogenization temperatures (T_H) are >248°C in stage I, 214–232°C in stage II and 186–239°C in stage III. These fluid inclusions have salinity between 1 and 2 wt% NaCl equivalent. In terms of gold assay, stage I drill‐core samples have gold grades 0.53–0.76 g/ton Au, stage II samples have 1.12–3.70 g/ton Au and stage III samples have 9.06–23.88 g/ton Au. This correlation suggests that gold was precipitated from the stage II and III fluids.     

Kinetic Study of the Reactions of Ozone with Polycyclic Aromatic Hydrocarbons Adsorbed on Atmospheric Model Particles

In this experimental study, rate constants were measured for the reactions of ozone with 13 polycyclic aromatic hydrocarbons (PAHs) adsorbed on different types of particles. Graphite and silica were chosen to model, respectively, carbonaceous and mineral atmospheric particles. The pseudo-first order rate constants were obtained from the fit of the experimental decay of particulate PAH concentrations versus time. Second order rate constants were calculated considering the ozone gaseous concentration. At room temperature, rate constants varied, in the case of graphite particles, between (1.5 ± 0.5) × 10⁻¹⁷ and (1.3 ± 0.7) × 10⁻¹⁶ cm³ molecule⁻¹ s⁻¹ for chrysene and dibenzo[a,l]pyrene, respectively, and, in the case of silica particles, between (1.5 ± 0.3) × 10⁻¹⁷ and (1.4 ± 0.3) × 10⁻¹⁶ cm³ molecule⁻¹ s⁻¹ for fluoranthene and benzo[a]pyrene, respectively. Different granulometric parameters (particle size, pore size) and different PAH concentrations were tested in the case of silica particles. Heterogeneous reactions of ozone with particulate PAHs are shown to be more rapid than those occurring in the gas-phase, and may be competitive with atmospheric photodegradation.     

Interpreting the hydrological history of a temporary pond from chemical and microscopic characterization of siliceous microfossils

The hydrological history of a temporary pond in South Carolina was inferred from a 5500-year record of siliceous microfossils, including diatoms, freshwater sponge spicules, chrysophyte cysts, plates of testate amoebae and plant phytoliths. Microfossil abundance was estimated by microscopic quantification of siliceous particles and by chemical extractions of silica. Diatom, sponge and mineral particle volumes were correlated with silica concentrations attributable to these fractions. Both techniques suggested a sequence of four distinct community types. Basal sediments (4630–5520 ¹⁴C YBP) containing phytoliths and sponge spicules indicative of a wetland community were covered by sediments dominated by the remains of planktonic protists (3750–4630 ¹⁴C YBP) suggesting a transition from a vegetated marsh to an open-water, permanently flooded pond. Microfossil assemblages above this zone indicate the return of a wetland community ca. 3750 YBP that persisted until recently, when pond water levels stabilized as a result of seepage from a reservoir constructed nearby in 1985. This study suggests that the suite of siliceous microfossils commonly found in pond sediments can be used to infer historical alternations between macrophyte and plankton-dominated states in shallow basins. Regional climate inferences from this record include a mid-Holocene hydrological maximum and the onset of the modern climate ca. 3500 YBP.     

Character of sediments entering the Costa Rica subduction zone: Implications for partitioning of water along the plate interface

Abstract   Sediments deposited off the Nicoya Peninsula advect large volumes of water as they enter the Costa Rica subduction zone. Seismic reflection data, together with results from Ocean Drilling Program Leg 170, show that hemipelagic mud comprises the upper ∼135 m of the sediment column (ranging from 0 to 210 m). The lower ∼215 m of the sediment column (ranging from 0 to 470 m) is pelagic carbonate ooze. We analyzed samples from 60 shallow (<7 m) cores to characterize the spatial variability of sediment composition on the incoming Cocos Plate. The bulk hemipelagic sediment is 10 wt% opal and 60 wt% smectite on average, with no significant variations along strike; the pelagic chalk contains approximately 2 wt% opal and <1 wt% smectite. Initially, most of the water (96%) in the subducting sediment is stored in pore spaces, but the pore water is expelled during the early stages of subduction by compaction and tectonic consolidation. Approximately 3.6% of the sediment's total water volume enters the subduction zone as interlayer water in smectite; only 0.4% of the water is bound in opal. Once subducting strata reach depths greater than 6 km (more than 30 km inboard of the subduction front), porosity drops to less than 15%, and temperature rises to greater than 60°C. Under those conditions, discrete pulses of opal and smectite dehydration should create local compartments of fluid overpressure, which probably influence fluid flow patterns and reduce effective stress along the plate boundary fault.     

Determining Biogenic Silica in Marine Samples by Tracking Silicate and Aluminium Concentrations in Alkaline Leaching Solutions

This study introduces an alkaline leaching technique for the simultaneous analysis of biogenic silica and aluminium in sediments. Measuring aluminium facilitates the discrimination between silica from the biogenic (BSiO₂) and the non-biogenic fraction, because it originates almost solely from the lithogenic phase. The method was tested using fine-grained silicagel, standard clay minerals, artificial sediments, and natural samples ranging from fresh diatoms to aged sediment from different depositional settings. To determine the BSiO₂ content, four different models each describing the dissolution curves, but of increasing complexity, were applied and for each different type of sample the optimum model was selected on the basis of F-test statistics. For mixtures of silicagel and clay minerals, the contribution of Si from the dissolution of clay was negligible compared to Si originating from silicagel. For natural samples with high clay content, complex dissolution curves were observed and single-phase first order dissolution was the exception. This deviation from `ideal' behavior could only be recognized because of high-resolution sampling, especially in the first 20 minutes of the experiment. For most of the samples, the distinction between the biogenic silica fraction and the silica originating from dissolution of clays could be made on the basis of the Si/Al ratios and reactivity constants of the dissolving phases calculated with the models. Clay minerals typically dissolve slowly at a Si/Al ratio close to 1–2, depending on the type of clay mineral. In contrast, biogenic silica displays a wide range of reactivities and Si/Al ratios. Fresh biogenic silica from the water column usually has a high reactivity and a low Al content. Aged biogenic silica from the sediments has a lower reactivity, but Si/Al ratios as low as 5 were found. The method as described here therefore presents an accurate method to analyze biogenic silica in marine sediments with a relatively high clay mineral content.