Role of buffer layer in electronic structures of iron phthalocyanine molecules on Au(111)

We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ～15° relative to the substrate plane along the nearest neighbour [101^-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111).     

Spatial and temporal patterns in the hyperbenthic community structure in a warm temperate southern African permanently open estuary

The spatial and temporal patterns in the hyperbenthic community structure (>500 μm) in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa was investigated monthly over a period of twelve months. Data were collected using a modified hyperbenthic sledge at six stations along the length of the estuary. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentration were evident. Total average hyperbenthic densities ranged between 0.4 and 166 ind.m⁻³ in the lower net and between 0.2 and 225 ind.m⁻³ in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m⁻³ in the lower net and between 0.02 and 17.4 mg.dry weight.m⁻³ in the upper net. Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoea) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, comprising up to 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis.     

Probabilistic Approach of Coastal Defense Against Typhoon Attacks for Nuclear Power Plant

With the global wanning and sea level rising, it is widely recognized that there is an increasing tendency of typhoon occurrence frequency and intensity. The defenses code against typhoon attacks for nuclear power plant should be calibrated because of the increasing threat of typhoon disaster and severe consequences. This paper discusses the probabilistic approach of definitions about "probable maximum typhoon" and "probable maximum storm surge" in nuclear safety regulations of China and has made some design code calibrations by use of a newly proposed Double Layer Nested Multi-objective Probability Model (DLNMPM).     

桐梓北部大竹坝井田含煤地层及可采煤层地质特征

大竹坝井田位于呈北东向展布的松坎复式向斜南东翼之次级褶皱-乐坪背斜南东翼,含煤地层为上二叠统龙潭组(P3l),厚45.61~71.53m,平均厚61.10m,含煤层(线)2~6层,全区可采煤层一层(C3),局部可采煤层二层(C2、C4)。C3煤层具有低挥发份、中灰、中高硫、高固定碳、高熔灰分、高热值的特点。可作工业用煤、动力用煤、气化用煤和化工用煤以及民用等。井田以含煤地层相对较薄,可采煤层少,煤层厚度小,含煤率低为其特征。     

水下收缩裂隙形成过程及裂缝充填模式研究

通过野外实地考察测试,对水下收缩裂隙整体形成过程、裂隙内充填物沉积模式、影响因素等进行了详细讨论,并且建立了相应的地质理论模型。水下收缩裂隙的形成共分4个阶段,依次为:泥水混合物进入低洼地带的初始混浊状态;沉积压实稳定阶段;水位线下降,盐度增大,裂隙形成阶段;沉积裂隙充填阶段。其中“异常高压作用”,对于初始裂隙的形成、沉积物孔隙水的有效排出以及主要渗流通道的发育起到了重要作用。单一泥质地层裂隙内充填物沉积模式与沙泥互层的多旋回地层略有差异,主要表现为沙层的润滑作用以及对早期裂隙内充填物类型的影响。上述两种地层裂隙内充填物沉积特征均与后期充注期次相对应,表现出很好的韵律性。裂隙纵剖面中生物发育层的出现,对裂隙内充填物的物理、化学性质将产生重要影响。     

层状地基端承桩扭转动力阻抗研究

本文采用Novak薄层法推导粘弹性地基的扭转动力阻抗,并将其用于考虑桩土相互作用的单桩扭转动力阻抗,又通过传递矩阵法将此公式推广到求取层状地基单桩扭转动力阻抗。而且本文以工程中常用的端承桩为例,推导了层状地基中端承桩扭转动力阻抗的简化计算公式。根据此公式,分析了频率、上覆软土层厚度、上覆软土层刚度等因素对单桩扭转动力阻抗的影响,分析结果表明,随着振动频率提高,层状地基中端承单桩的扭转动力阻抗的实部有缓慢下降的趋势,而虚部则增大;随着上覆土层厚度的增加,层状地基中端承单桩的扭转动力阻抗的实部和虚部均减小;随着上覆土层刚度的减小,层状地基中端承单桩的扭转动力阻抗的实部减小,虚部在低频段减小,而在较高频率段则增大。     

探地雷达宽角反射图形拟合方法

探地雷达共中心点(CMP)法仅用于局部速度测试,为使用宽角反射法进行剖面探测,可固定一个雷达天线而将另一个天线沿测线移动,从而获取整个地质界面的反射信号.本文提出宽角反射剖面探测方法,基于平直岩层界面导出其反射信号的关系式,并开发出解释软件,可精确计算岩层几何参数和层速度,从而进行地质分层.     

Analytical layer‐element method for non‐axisymmetric consolidation of multilayered soils

A numerically efficient and stable method is developed to analyze Biot's consolidation of multilayered soils subjected to non‐axisymmetric loading in arbitrary depth. By the application of a Laplace–Hankel transform and a Fourier expansion, the governing equations are solved analytically. Then, the analytical layer‐element (i.e. a symmetric stiffness matrix) describing the relationship between generalized displacements and stresses of a layer is exactly derived in the transformed domain. Considering the continuity conditions between adjacent layers, the global stiffness matrix of multilayered soils is obtained by assembling the inter‐related layer‐elements. Once the solution in the Laplace–Hankel transformed domain that satisfies the boundary conditions has been obtained, the actual solution can be derived by the inversion of the Laplace–Hankel transform. Finally, numerical examples are presented to verify the theory and to study the influence of the layered soil properties and time history on the consolidation behavior. Copyright © 2011 John Wiley & Sons, Ltd.     

Satellite-tracked drifting buoy observations in the south equatorial current in the Indian Ocean

Three satellite-tracked drifting buoys released in the south equatorial current in the Indian Ocean followed the path of the current moving westward approximately zonally in the vicinity of 10 S latitude. On nearing the east coast of Africa two buoys moved north and the third moved south. Over the open sea regime the buoys moved with a speed of approximately 30 cm/s at an angle of about 35° to the left of the wind. The overall tendencies seen in the buoy drift are similar to those observed elsewhere in the world oceans.     

岩浆包裹体化学成分研究

岩浆包裹体化学成分研究难度较大,为了获得可信的数据,应当注意:1.非演化型岩浆包裹体的化学成分可以代表其初始成分。演化型岩浆包裹体应先均一、淬火后再行测定。2.均一演化型岩浆包裹体应严格遵守加热规则,否则过热作用会使包裹体壁部分熔化,造成淬火后所测包裹体成分与其真正的初始成分并不相当。3.实测资料证明,“边界层效应”对于岩浆包裹体化学成分影响微不足道。4.岩浆包裹体的化学成分只能代表其主矿物结晶时周围岩浆的成分,即仅相当于岩浆液相线上的一个点。5。把显微冷热台测温、激光喇曼探针和电子探针分析技术结合使用,对查明单个包裹体中挥发组分的性状和浓度具有很大的潜力和前途。