煤矿井下碎软煤层泡沫钻进技术及应用

针对煤矿井下碎软煤层瓦斯抽采中风压空气钻进施工中排粉能力有限,易造成粉尘污染问题,提出采用煤矿井下泡沫灌注系统及宽翼螺旋钻杆进行高效泡沫钻进的技术方案。通过对钻孔环空间隙流场的数值模拟,研究宽翼螺旋钻杆结构对泡沫钻进高效排粉的影响,确定头数3、槽宽26 mm、螺距110 mm为宽翼螺旋钻杆的优化结构参数。在淮北某矿3204工作面碎软煤层中进行了深度达195 m的本煤层钻孔试验,结果表明,相对于中风压空气钻进工艺,钻进回转阻力降低了42%~48%,表现出高效的排粉效果,可提高煤矿井下碎软煤层钻孔深度和成孔率。该工艺可为类似煤矿井下深钻孔施工提供借鉴。     

Removal of Cu(Ⅱ) from Wastewater Using Acidified Sewage Sludge Ash

Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions.     

Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.     

基于无抽样小波的遥感影像薄云检测与去除

针对全色波段遥感影像提出了一种基于无抽样小波变换的薄云去除算法。对实际的卫星影像和航空影像所进行的试验结果表明,该方法是十分有效的。     

弹性填料处理河道污水实验研究

采用弹性填料曝气生物膜法对污染的河道水体进行处理的实验研究,结果表明,在2m/h的流速、水温为16℃~18℃、气水比为1∶1的条件下,采用弹性填料的生物膜处理系统运转正常,不易发生堵塞或系统短流,系统此时的水力停留时间为3.5h左右,污水中的COD和NH3-N去除率稳定,其均值分别为49.4%和19.1%。     

XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.     

海水人工湿地系统脱氮效果与基质酶活性的相关性

利用海水人工湿地系统处理海水养殖外排水,分析了人工湿地对不同形态氮的净化效果,探讨了人工湿地表层基质酶活性变化及其对系统脱氮效果的影响。选取互花米草作为人工湿地植物,煤渣、珊瑚石和细砂作为人工湿地基质,实验期间连续进水,系统运行稳定。研究结果表明:海水人工湿地系统对氨氮(NH4-N)、亚硝态氮(NO2-N)、硝态氮(NO3-N)、总氮(TN)和可溶性有机氮(DON)去除效果显著,去除率分别为(99.6±0.7)%、(99.9±0.0)%、(98.2±2.0)%、(92.6±1.5)%和(86.1±4.8)%。人工湿地表层基质下行池脱氢酶、硝酸还原酶和脲酶的酶活性均高于上行池,下行池对污染物的去除效果更好。脱氢酶活性与海水人工湿地系统氨氮的去除有关;硝酸还原酶活性影响着海水人工湿地硝态氮的去除;脲酶活性与人工湿地总氮和硝态氮的去除存在明显相关趋势。下行池硝酸还原酶和脲酶的酶活性间具有显著相关性(r=0.76, P0.05)。人工湿地微生物种类丰富,下行池微生物多样性高于上行池,植物根部微生物多样性最高,提高了系统脱氮的效率。上述研究结果将有助于阐明海水人工湿地系统中不同形态氮的迁移转化机理。     

改进HOT的高分影像自动去薄云算法

为了有效去除薄云对高分光学影像造成的干扰,解决传统算法自动化程度低、去薄云效果不理想的问题,提出改进的薄云最优化变换(Improved Haze-Optimized Transformation,IHOT)算法。首先采用暗原色先验知识从薄云影像中自动选取晴空区,运用薄云最优化变换检测薄云,再创新性地利用植被区域云检测精度较高的特点改进检测结果,最终使用虚拟云点法进行薄云去除。利用高分一号影像进行实验,证明该文提出的算法能够有效地去除薄云对高分影像的影响,尤其对人造地物的色彩和纹理信息恢复效果优于传统算法。     

利用多分辨率半边进行全球多分辨率DEM无缝表达

矢量化的复杂建筑平面图纸受各类图元的干扰,其空间布局识别难度非常高,然而在5G基站建设、智能家居以及AR/VR（augmented reality/virtual reality）中广为应用。提出了一种结合栅格图像和矢量表示的高性能融合对偶识别方法。首先,采用建筑平面图纸的栅格化表示,提取建筑图纸的主要发展方向,构建分割的若干个封闭区域空间。然后,采用建筑平面图纸的矢量化表示,利用空间识别的有向性和邻接特性,创新地提出使用半墙数据结构进行墙体几何位置和拓扑关系的计算,从而根据空间对偶原理高精度地整体重建墙体布局。最后,获取包含各类墙体布局的矢量建筑平面图数据集,并进行方法的实验验证。实验结果证明了所提出的先空间后墙体的融合对偶识别算法对于各类建筑模型类型均具有可用性和有效性。与传统先墙体后空间的识别方法相比,所提方法具有更高的鲁棒性,受特定建筑图纸类型的干扰更少。     

生物去除地下水中硫酸盐的实验研究

使用平皿夹层厌氧法分离得到纯化的硫酸盐还原菌,通过对比封口、敞口两种情况下细菌培养过程中产生的现象和细菌的生长曲线,表明SRB并非严格的厌氧菌,能耐受一定浓度的环境溶解氧.将该菌用于去除溶液中的SO42-,发现SRB在还原SO42-的过程中,随着SO42-去除率的增加,溶液的pH值会减小,而当SO42-去除率降低时,溶液的pH有增加的趋势;COD/SO42-比值对SO42-的去除率有很重要的影响,在封口情况下,COD/SO42-=0.75时SO42-的最大去除率约为48.60%,COD/SO42比值增加至2.5时,SO42-最大去除率可以达到89.72%,要达到SO42-高去除率,必须增加COD/SO42-比值.