Land subsidence caused by compression of clay layers in Ojiya City, Japan was measured by global positioning system (GPS) between 1 April 1996 and 31 December 1998.
Three baselines were selected in and around the city, and height difference on a WGS-84 ellipsoid was measured by GPS on each baseline. The ground at the GPS station in the city subsides and rebounds 7 cm every winter and spring, respectively. Measurement accuracy was 9.5 mm standard deviation. Ground water level was observed at a well near the GPS station. Regression analysis between total strain, calculated as ratio of the height difference displacement to the total thickness of the clay layers, and the layers' effective stress change with ground water level change gave good correlation. The slope of regression line 7.0×10−11 m2/N was obtained as an average apparent coefficient of volume compressibility of the layers. 相似文献
A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis. 相似文献
The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1). 相似文献
The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption
of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the
topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process.
To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have
been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order
to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of
these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field,
yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary
harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given.
A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic
Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results
show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative
geoid accuracy compared to the GPS/levelling geoid.
Received: 3 October 2001 / Accepted: 20 September 2002
Correspondence to: H.A. Abd-Elmotaal 相似文献