多金属结核中二氧化锰的测定

用过量的含有Ｈ２ＳＯ４的（ＮＨ４）２Ｆｅ（ＳＯ４）２溶液分解多金属结核的同时，还原了试样中的ＭｎＯ２，然后以Ｋ２Ｃｒ２Ｏ７标准溶液滴定测定了多金属结核中的ＭｎＯ２。就样品分解过程中的加热温度和时间对测定结果的影响及标准溶液的标定等问题进行了讨论，经多次测定，方法重现性好。应用此方法为新研制的多金属结核标准物质提供了ＭｎＯ２的定值数据，其结果与初定值相符，无剔除值，精密度（ＲＳＤ，ｎ＝８）小于０６％。     

静海地震台地磁短周期变化及其在地震短临预报中的应用

近年来的一些研究表明，由于地震前孕震区地下介质的电性结构的变化，将导致地磁短周期转换函数发生异常变化。通过对地震前后的地磁短周期转换函数的参数的计算、分析和研究，有可能提取出可靠的地震短临前兆异常（曾小苹等，１９９０）。为了进一步开展对该方法研究工作并使其在我区地震预测预报研究中得到应用，我们使用了静海台的地磁记录资料，分析计算了该台地磁短周期转换函数在地震前后的变化情况，确立了该方法应用天津地区地震预报的短临异常特征及指标，取得了较好的效果。     

深基础护坡桩的设计与施工中的几个问题

着重介绍了间隔式钻孔灌注桩在挡土护坡技术中的应用方法，设计时的主要参考依据，计算土压力理论的应用原则以及施工中需注意的几个问题，为进行深基础挡土护坡的工程提供了部分参考依据。     

云宵县5月暴雨客观预报模型

采用文献[1]提出的技术模型，研制了云宵县5月暴雨预报方法，建立了4个因子结构简单而天气学意义明了的客观预报模型。经2000～2003年试用，这种基于场量因子的预报模型，未漏报，严格评定的准确率为67％，明显优于主观预报。     

黄河上游梯级水电站施工洪水优化设计方法探讨--以黄河公伯峡水电站施工洪水优化设计为例

梯级水电站设计洪水方法一直是梯级水电站水文设计的难点．几十年来在黄河上游梯级电站设计中已总结出一套比较完整的设计洪水及施工洪水计算方法。通过黄河公伯峡水电站施工洪水优化设计过程，论述了该套方法．并就目前存在的一些观点及疑问给予了较为明确的回答。     

兰州CAWS600-R自动站与人工观测资料对比分析

利用2002年11月到2003年2月兰州CAWS600-R型自动站与人工观测的温度、本站气压、水汽压、相对湿度、5～320cm地温等资料，分析了对比观测资料的差值。结果表明：对气温、本站气压、水汽压、相对湿度及320cm地温等要素观测误差较小，5～160cm地温的观测误差较大。自动观测仪器的系统性偏差、测量元件的精度及对气象要素变化响应的灵敏度、观测时间的差异和人为因素的影响是造成对比观测误差的原因。     

基于GPRS的远程气象观测数据实时采集传输系统及其应用

通过对远程自动气象站数据实时采集传输通讯方式的比较，提出基于通用分组无线业务（GPRS）的远程自动气象站数据实时采集和传输系统的技术方案，以小数据流方式，实现野外自动气象站观测数据的实时采集、传输和对观测设备运行的监控，达到节约经费，提高数据传输时效的目的，并将此系统成功地用于苏通长江公路大桥施工期气象环境监测与预警系统中。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.