有机坡缕石黏土对活性染料的吸附性能

由阴、阳离子表面活性剂对坡缕石黏土改性,通过静态吸附实验研究了有机坡缕石黏土对活性红的吸附性能,探讨了吸附平衡和吸附机理。结果表明,表面活性剂改性可增强坡缕石黏土表面的疏水性,影响ζ电位,适当配比的阴阳离子表面活性剂改性坡缕石黏土对活性红有协同吸附作用,吸附等温线呈非线性,符合Langmuir方程和Freundlich方程,ΔH为-12.23 k J/mol,吸附不存在强化学作用,是分配作用和氢键力、偶极间力及范德华力等多种作用的结果。     

A kinetic approach for simulating redox‐controlled fringe and core biodegradation processes in groundwater: model development and application to a landfill site in Piedmont,Italy

A three‐dimensional model for predicting redox controlled, multi‐species reactive transport processes in groundwater systems is presented. The model equations were fully integrated within a MODFLOW‐family reactive transport code, RT3D. The model can simulate organic compound biodegradation coupled to different terminal electron acceptor processes. A computational approach, which uses the spatial and temporal distribution of the rates of different redox reactions, is proposed to map redox zones. The method allows one to quantify and visualize the biological degradation reactions occurring in three distinct patterns involving fringe, pseudo‐core and core processes. The capabilities of the numerical model are demonstrated using two hypothetical examples: a batch problem and a simplified two‐dimensional reactive transport problem. The model is then applied to an unconfined aquifer underlying a leaking landfill located near the city of Turin, in Piedmont (Italy). At this site, high organic load from the landfill leachate activates different biogeochemical processes, including aerobic degradation, denitrification, manganese reduction, iron reduction, sulfate reduction and methanogenesis. The model was able to describe and quantify these complex biogeochemical processes. The proposed model offers a rational framework for simulating coupled reactive transport processes occurring beneath a landfill site. Copyright © 2008 John Wiley & Sons, Ltd.     

The relationships between particulate and soluble alkaline phosphatase activities and the concentration of phosphorus dissolved in the seawater of Toulon Bay (NW Mediterranean)

The activities of particulate and soluble phosphatase were analyzed monthly for 1 year in the coastal ecosystems of the NW Mediterranean Sea. The mean contribution of the particulate activity increased from 56% at an MUF-P concentration of 30 μM to 77% at 0.04 μM. This particulate activity was negatively correlated with the DIP, DOP and TDP concentrations when the activities were related to the seawater volume, chlorophyll a or the protein concentration. The TDP correlations were highly significant (p: 0.001). The DOP correlations were significant (p: 0.04) and became highly significant (p: 0.009) at low DIP concentrations (<0.13 μM). The DIP correlations were significant (p: 0.04) only at low DOP concentrations (<0.18 μM). Thus, the effects of seawater DIP and DOP were found to be linked. The soluble activity exhibited distinct phosphatase fractions with high (0.5–29.5 μM) and low (0.02–2 μM) Km values, but none exhibited significant correlations with phosphorus compounds.     

Finite volume model for reactive transport in fractured porous media with distance- and time-dependent dispersion

Abstract

There are very few studies of fractured porous media that use distance- and time-dependent dispersion models, and, to the best of our knowledge, none which compare these with constant dispersion models. Therefore, in this study, the behaviour of temporal and spatial concentration profiles with distance- and time-dependent dispersion models is investigated. A hybrid finite volume method is used to solve the governing equations for these dispersion models. The developed numerical model is used to study the effects of matrix diffusion coefficient, groundwater velocity and matrix and fracture retardation factor on concentration profiles in the application of constant, distance-dependent and time-dependent dispersion models. In addition, an attempt is made to evaluate the applicability of these dispersion models by using the models to simulate experimental data. It was found that a better fit to the observed data is obtained in the case of distance- and time-dependent dispersion models as compared to the constant dispersion model. Thus, these numerical experiments indicate that distance- and time-dependent dispersion models have better simulation potential than the constant dispersion model.     

Analytical expressions for the hydraulic design of continuous permeable reactive barriers

Various analytical expressions describing the hydraulic behavior of a continuous permeable reactive barrier (PRB) are developed based upon a two-dimensional approximation of the local groundwater flow system. The fully penetrating PRB is represented as an arbitrarily oriented elliptical “analytic element” with a hydraulic conductivity different from that of the aquifer. The validity of this elliptical geometry approximation as a surrogate for rectangular PRB performance is evaluated and put into context. Closed-form expressions for solute travel time distributions along the extent of the barrier and PRB capture zone geometry are evaluated for general barrier dimension (length and width), hydraulic conductivity, and orientation with respect to regional flow. These expressions are used as the foundation of a simple PRB design process, and provide some interesting insights into the hydraulic behavior of continuous permeable reactive barriers.     

地下水有机污染控制及就地恢复技术研究进展（三）

本文是关于地下水有机污染控制及其就地恢复技术进展概况的第3篇文章，文中主要介绍渗以应格栅中的氧化－还原反应格栅和生物降解反应格栅。     

Active Nitrogen in Surface Ozone Depletion Events at Alert during Spring 1998

Measurements of NO_x,y were made at Alert, Nunavut, Canada (82.5° N, 62.3° W) during surface layer ozone depletion events. In spring 1998, depletion events were rare and occurred under variable actinic flux, ice fog, and snowfall conditions. NO_y changed by less than 10% between normal, partially depleted, and nearly completely depleted ozone air masses. The observation of a diurnal variation in NO_x under continuous sunlight supports a source from the snowpack but with rapid conversion to nitrogen reservoirs that are primarily deposited to the surface or airborne ice crystals. It was unclear whether NO_x was reduced or enhanced in different stages of the ozone depletion chemistry because of variations in solar and ambient conditions. Because ozone was depleted from 15–20 ppbv to less than 1 ppbv in just over a day in one event it is apparent that the surface source of NO_x did not grossly inhibit the removal of ozone. In another case ozone was shown to be destroyed to less than the 0.5 ppbv detection limit of the instrument. However, simple model calculations show that the rate of depletion of ozone and its final steady-state abundance depend sensitively on the strength of the surface source of NO_x due to competition from ozone production involving NO_x and peroxy radicals. The behavior of the NO/NO₂ ratio was qualitatively consistent with enhanced BrO during the period of active ozone destruction. The model is also used to emphasize that the diurnal partitioning of BrO_x during ozone depletion events is sensitive to even sub ppbv variations in O₃.     

工业控制计算机在高压无功自动补偿中的应用

介绍了工业控制计算机在高压无功自动补偿中的控制原理、技术特点和软件流程.详细阐述了工业控制计算机进行数据采集和控制的实现,以满足变电站无功补偿的需要.     

两种废物材料在地下水环境治理中的应用

实验利用粉煤灰和矿化垃圾两种废物材料作为反应屏障的反应介质用于修复受渗滤液污染的地下水环境。所设计的两个反应器A、B分别填充矿化垃圾和粉煤灰,利用它们的吸附能力、阳离子交换能力以及微生物的作用去除污染质。试验结果表明:A、B两柱COD的去除率最高可达66%和59%,对铵氮的去除率柱A明显优于柱B,最高可达92.7%,并在81%左右保持稳定。另外柱A对硝酸盐氮和亚硝酸盐氮的去除效果也优于柱B。说明矿化垃圾作为反应屏障介质更加经济可行,可以达到以废治废的目的。     

水体溶解无机氮对角毛藻胞内活性氮组分的影响

本文研究了水体中不同形式溶解无机氮(NH_4~+,NO_3~-,NH_4~++NO_3~-)及其含量对牟氏角毛藻和钙质角毛藻胞内活性氮组分(NH_4~+,NO_3~-,AA,Pr,RNA及DNA)的影响。结果表明:角毛藻胞内无机氮储量的大小体现了水体中无机氮的营养水平;培养角毛藻采用混合无机氮比之单一无机氮,其胞内AA和Pr含量较高,AA/Pr值可定量标志水体无机氮的营养水平及藻类本身氮的营养状况;RNA/DNA值是藻类生长增殖状况的指标之一。