Estimation of pH optima and tolerances of diatoms in lake sediments by the methods of weighted averaging,least squares and maximum likelihood,and their use for the prediction of lake acidity

Ecological optima and tolerances with respect to autumn pH were estimated for 63 diatom taxa in 47 Finnish lakes. The methods used were weighted averaging (WA), least squares (LS) and maximum likelihood (ML), the two latter methods assuming the Gaussian response model.WA produces optimum estimates which are necessarily within the observed lake pH range, whereas there is no such restriction in ML and LS. When the most extreme estimates of ML and LS were excluded, a reasonably close agreement among the results of different estimation methods was observed. When the species with unrealistic optima were excluded, the tolerance estimates were also rather similar, although the ML estimates were systematically greater.The parameter estimates were used to predict the autumn pH of 34 other lakes by weighted averaging. The ML and LS estimates including the extreme optima produced inferior predictions. A good prediction was obtained, however, when prediction with these estimates was additionally scaled with inverse squared tolerances, or when the extreme values were removed (censored). Tolerance downweighting was perhaps more efficient, and when it was used, no additional improvement was gained by censoring. The WA estimates produced good predictions without any manipulations, but these predictions tended to be biased towards the centroid of the observed range of pH values.At best, the average bias in prediction, as measured by mean difference between predicted and observed pH, was 0.082 pH units and the standard deviation of the differences, measuring the average random prediction error, was 0.256 pH units.     

郑州市酸雨变化特征及影响因素分析

通过对1992-2006年郑州酸雨观测站数据以及2001年4月-2006年12月郑州空气质量逐日数据进行统计分析,发现郑州市降水酸性呈现增强趋势,主要发生在秋、冬两个季节,频率在40%以上,冬季酸雨发生天数要多于秋季,降水酸度在秋末至12月较强。影响酸雨的主要因子为PM10、SO2与NO2浓度和降水量,PM10主要通过与酸性气体的化学反应来影响降水电导率K值,降水对大气中PM10的净化有较强的作用。连续性降水过程中降水pH值有减小趋势的占57.14%,主要在于降水对地面的湿润作用有效地阻止了来自地面的可溶性微粒进入大气中,不能足够吸收大气中酸性物质,致使酸性物质直接进入降水中造成降水持续酸化。     

The GEOMON network of Czech catchments provides long-term insights into altered forest biogeochemistry: From acid atmospheric deposition to climate change

In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO₂, NO_x and NH₃ emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH₄) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO₃) concentration declined by 60%, considerably more than N deposition. Stream NO₃ concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.     

Shenandoah Watershed Study-Virginia Trout Stream Sensitivity Study (SWAS-VTSSS): Stream water quality and hydrologic monitoring data for mid-Appalachian headwater streams

The Shenandoah Watershed Study (established in 1979) and the Virginia Trout Stream Sensitivity Study (established in 1987) serve to increase understanding of hydrological and biogeochemical changes in western Virginia mountain streams that occur in response to acidic deposition and other ecosystem stressors. The SWAS-VTSSS program has evolved over its 40+ year history to consist of a temporally robust and spatially stratified monitoring framework. Currently stream water is sampled for water quality bi-hourly during high-flow events at three sites and weekly at four sites within Shenandoah National Park (SHEN), and quarterly at 72 sites and on an approximately decadal frequency at ~450 sites within the wider western Virginia Appalachian region. Stream water is evaluated for pH, acid neutralizing capacity (ANC), base cations (calcium, magnesium, sodium and potassium ion), acid anions (sulphate, nitrate and chloride), silica, ammonium, and conductivity with a subset of samples evaluated for monomeric aluminium and dissolved organic carbon. Hourly stream discharge (four sites) and in-situ measurements of conductivity, water and air temperature (three sites) are also measured within SHEN. Here we provide an overview and timeline of the SWAS-VTSSS stream water monitoring program, summarize the field and laboratory methods, describe the water chemistry and hydrologic data sets, and document major watershed disturbances that have occurred during the program history. Website links and instructions are provided to access the stream chemistry and time-series monitoring data in open-access federal databases. The purpose of this publication is to promote awareness of these unique, long-term data sets for wider use in catchment studies. The water chemistry and hydrologic data can be used to investigate a wide range of biogeochemical research questions and provide key inputs for models of these headwater stream ecosystems. SWAS-VTSSS is an ongoing program and quality assured data sets are uploaded to the databases annually.     

Variability of Raindrop Size Distribution during a Regional Freezing Rain Event in the Jianghan Plain of Central China

The characteristics of the raindrop size distribution(DSD) during regional freezing rain(FR) events that occur throughout the phase change(from liquid to solid) are poorly understood due to limited observations. We investigate the evolution of microphysical parameters and the key formation mechanisms of regional FR using the DSDs from five disdrometer sites in January 2018 in the Jianghan Plain(JHP) of Central China. FR is identified via the size and velocity distribution measured from a disdrom...     

地表水酸化的研究进展及其湖泊酸化的环境信息研究

通过对发达资本主义国家在其工业化进程中产生的地表水酸化、资源与环境的破坏以及相关研究进展等的简介 ,审视我国大气污染、酸雨的发展趋势 ,预估部分酸雨区存在地表水酸化的潜在危险性。据此以云南高原湖泊洱海和阳宗海为例 ,从湖水矿化度、SO2 -4 离子浓度的动态变化和沉积记录的磁化率变化等分析研究 ,评述湖泊酸化的早期表现和判别标志。     

庐山一次积冰天气过程冻雨滴谱及下落末速度物理特征个例研究

利用PARSIVEL激光雨滴谱仪和自动气象站观测资料及MICAPS数据,对2014年2月7~15日庐山地区积冰天气期间持续时间在5 h以上的2次冻雨过程[2月10日（个例1）和2月13日（个例2）]降水谱分布特征及下落末速度粒径分布进行研究。所观测到的两次个例均是以冻雨为主体的混合相态降水,下落末速度粒径分布偏离G-K曲线,与常规液态降水存在差异,低落速的冻雨滴随降水过程会逐渐向冰粒和干雪转化。结果表明:（1）个例1总降水粒子谱谱宽大于个例2,但峰值数密度比个例2小:个例1谱宽为10 mm,个例2谱宽为4.25 mm,两者峰值粒径均为0.5 mm;个例1降水粒子谱宽为干雪>冻雨>冰粒,个例2降水粒子谱宽为冻雨>干雪>冰粒。（2）Gamma分布更适合描述混合相态降水粒子谱以及冻雨滴谱,个例1中总降水粒子谱Gamma分布为:N（D）=20D-3.61exp（-0.08D）,冻雨Gamma分布:N（D）=76D-2.18exp（-1.11D）;个例2中总降水粒子谱Gamma分布为:N（D）=30D-4.68exp（-0.75D）,冻雨Gamma分布:N（D）=30D-4.67exp（-0.75D）。（3）混合相态降水因混有干雪或冰粒而使得下落末速度粒径谱分布表现出不同程度地向大粒径小落速方向或小粒径大落速方向延展的趋势,这为今后依据下落末速度粒径谱区分同时期降水类型提供了新的思路。     

天津地区一次对流性降水过程雨滴谱特征分析

激光雨滴谱仪是天津人影部门近年新引入的探测设备,它对降水过程的即时监测具有重要意义。本文基于LPM-THIES激光雨滴谱仪探测资料,对天津地区2015年7月19日的对流性降水过程进行了分析。研究显示:雨滴谱仪和翻斗雨量计所获取的逐时降水其变化趋势存在一致性,但雨滴谱仪获得的累积雨量要偏大;降水过程的时空差异性大,不同测站雨强差异明显,4站降水粒子平均直径介于0.40~0.64mm,且2.0mm以下的降水粒子占到了粒子总数的95%以上;降水时段的雨强与雷达反射率的起伏变化十分明显,雨滴数浓度基本上处于103量级;蓟县站3个时次的瞬时谱均呈现单峰型分布,且峰值位于0.5mm附近。     

Temporal and spatial trends of lake acidity in northern Sweden

Changes in lake-water pH, alkalinity and colour were inferred from diatoms in surface sediment samples and sediment samples from pre-industrial times from 118 northern Swedish lakes. This palaeolimnological study does not support the hypothesis that there is a large-scale modern acidification in the two northernmost counties of Sweden; pH had decreased significantly in eight lakes, while five had a significant increase. Partial least-squares regression of changes in water chemistry in relation to catchment characteristics was performed to evaluate the causes of the acidity status. Furthermore, temporal trends were assessed from long sediment cores from five acidic lakes. The results suggest that the presently acid lakes have faced a long-term acidification trend over several thousand years due to soil-forming processes and vegetation development. However, due to the acid sensitivity of the region, future acidification trends in northern Swedish lakes should be carefully observed and assessed.     

Effects of rainfall,overland flow and their interactions on peatland interrill erosion processes

Interrill erosion processes on gentle slopes are affected by mechanisms of raindrop impact, overland flow and their interaction. However, limited experimental work has been conducted to understand how important each of the mechanisms are and how they interact, in particular for peat soil. Laboratory simulation experiments were conducted on peat blocks under two slopes (2.5° and 7.5°) and three treatments: Rainfall, where rainfall with an intensity of 12 mm h^?1 was simulated; Inflow, where upslope overland flow at a rate of 12 mm h^?1 was applied; and Rainfall + Inflow which combined both Rainfall and Inflow. Overland flow, sediment loss and overland flow velocity data were collected and splash cups were used to measure the mass of sediment detached by raindrops. Raindrop impact was found to reduce overland flow by 10 to 13%, due to increased infiltration, and reduce erosion by 47% on average for both slope gradients. Raindrop impact also reduced flow velocity (80–92%) and increased roughness (72–78%). The interaction between rainfall and flow was found to significantly reduce sediment concentrations (73–85%). Slope gradient had only a minor effect on overland flow and sediment yield. Significantly higher flow velocities and sediment yields were observed under the Rainfall + Inflow treatment compared to the Rainfall treatment. On average, upslope inflow was found to increase erosion by 36%. These results indicate that overland flow and erosion processes on peat hillslopes are affected by upslope inflow. There was no significant relationship between interrill erosion and overland flow, whereas stream power had a strong relationship with erosion. These findings help improve our understanding of the importance of interrill erosion processes on peat. Copyright © 2017 John Wiley & Sons, Ltd.