Products and Mechanism of the NO<Subscript>3</Subscript> Reaction with Thiophene

Products of the gas-phase reaction of the NO₃ radical with thiophene have been investigated using different experimental systems. On the one hand, experiments have been conducted in our laboratory using two different methods, a Teflon static reactor coupled to a gas chromatograph combined with mass-spectrometry (GC-MS) and a discharge flow tube with direct MS spectroscopic detection. A qualitative analysis in these cases indicates that possible products for the reaction of thiophene+NO₃ at room temperature include: sulphur dioxide, acetic and formic acids, a short-chain aldehyde, 2-nitrothiophene and 3-nitrothiophene. On the other hand, quantitative experiments have been performed in the European Photoreactor (EUPHORE) in Valencia, Spain. In this case, the major products were: HNO₃ (≈80%), nitrothiophenes (≈30%), SO₂ (≈20%), propanal (3%) and a fraction of particles (≈10%). The results obtained indicate that at least 70% of the reaction of NO₃ with thiophene proceeds by an H-abstraction process at room temperature. The mechanism of the reaction studied is proposed on the basis of experimental results.     

PROPERTIES OF PROTEOLYTIC TOXIN OF VIBRIO ANGUILLARUM FROM DISEASED FLOUNDER

Extracellular products(ECP)produced by Vibrio anguillarum strain M3 originally isolated from diseased flounder(Paralichthys olivaceus)were prepared.ECP of M3 showed gelatinase,casinase,amylase and haemolytic activity on agarose plates.High protease activity against azocasin was detected.Bacterium M3 showed highest growth and protease activity at 25℃。The Protease present in ECP showed maximal activity at pH 8 and 55℃；was completely inactivated by application of 80℃ heat for 30 min;was completely inhibited by EDTA and HgCl2,and was partially inhibited by PMSF,SDS,MnCl2 and iodoacetic acid;but not inhibited by CaCl2 and MgCl2.The ECP was toxic to flounder fish at LD50 values of 3.1 μg protein/g body weight.The addition of HgCl2 and application of heat at 50℃ decreased the lethal toxicity of ECP.When heated at 100℃,ECP lethality to flounder was completely in-hibited.After intramuscular injection of ECP into flounder,it showed evident histopathological changes including necrosis of muscle,extensive deposition of haemosiderin in the spleen,dilated bolld vessels congested with numerous lymphocytes in the liver.These results showed that ECP protease was a lethal factor produced by the baterium V.anguillarum M3.     

Metabolic changes in Phaeocystis poucheti (Hariot) Lagerheim during the spring bloom in Belgian coastal waters

Incorporation of ¹⁴C-bicarbonate into the major intracellular end-products of photosynthesis (protein, polysaccharide, lipid) and two classes of exoproducts (oligomers and polymers) was measured in Belgian coastal waters at different stages of the spring phytoplankton bloom, entirely dominated by the alga Phaeocystis poucheti. It was shown that intracellular protein synthesis contributed 20–42% of the total intracellular ¹⁴C fixed and was positively correlated with the inorganic nitrogen content of the surrounding medium. The decrease of protein synthesis following nitrogen depletion is balanced by an increase of intracellular polysaccharide synthesis, which varies from 22 to 42% of the intracellular ¹⁴C fixed, and by an increase in extracellular release of high molecular weight material (18–60% of total ¹⁴C fixed) which forms a mucous envelope where cells are embedded. Lipid synthesis is not correlated with the ambient inorganic nitrogen content and represents a rather constant proportion (about 20%) of the intracellular ¹⁴C fixed.     

高精度数字栅格地图的制作方法

分析了数字栅格地图制作过程中的误差来源和类型,提出了一套能够同时改正系统和局部几何畸变的制作方法和流程,开发了半自动、高精度的制作软件系统。     

"允许偏离"在检测、检定工作中的应用

通过对“允许偏离”的分析，说明“允许偏离”在测绘产品、测绘仪器检测、检定中的应用，如何保证质量而实事求是解决问题。     

从旅游产品角度分析雨花石的利用与开发

雨花石不仅具有特殊的美学观赏价值,而且还具有丰富的文化内涵。主要从旅游产品开发角度阐述雨花石开发为旅游产品的优势以及在开发过程中存在的一些问题并针对问题提出一些建议。     

SAR图像多尺度积增强的目标检测算法

合成孔径雷达（SAR）成像系统的热噪声和海杂波严重影响SAR图像自动目标检测的性能,去噪和均匀背景杂波是提高SAR图像目标检测性能的重要课题。根据SAR图像噪声功率一般存在于信号小尺度,没有跨尺度特征,而目标信号的边缘具有跨尺度的特点,本文提出了一种多尺度积信号增强和去噪的SAR图像船舰目标检测算法。本算法对SAR图像进行小波变换,应用多尺度积在小波域增强SAR图像船舰信号和均匀背景杂波,再对SAR图像进行目标检测。ERS SAR图像用于验证本文算法。仿真实验结果表明,新算法同传统的双参数CFAR检测算法、基于K-分布背景杂波的检测算法以及基于小波软阈值增强的检测算法相比,在虚警数和品质因数性能指标上均优于后几种检测算法。     

“21世纪海上丝绸之路”沿线国家水产品贸易网络分析

水产品贸易是海洋经济的重要组成部分,是保证水产品有效供给、维护渔业产业链的重要措施。优化水产品贸易网络对保障中国粮食安全和扩展国际贸易具有重要意义。文章借助联合国商品贸易数据库,选取2000—2019年“21世纪海上丝绸之路”沿线国家水产品贸易数据,利用社会网络分析方法,测度“21世纪海上丝绸之路”沿线国家水产品贸易网络结构特征,进而分析沿线国家水产品贸易市场结构和产品结构。研究发现：1）2000—2019年“21世纪海上丝绸之路”沿线国家的水产品贸易变化可划分为2个阶段,其中第一阶段（2000—2008年）为平稳增长期,第二阶段（2009—2019年）为波动发展期。2）水产品贸易网络密度逐渐增大,空间集聚和网络凝聚力逐渐增强,网络的可达性不断提高,呈现小世界的特性。3）水产品贸易网络的核心—边缘结构较为稳定,核心国家的贸易联系紧密,贸易额占整体的一半以上,多边、双边贸易流存在差异,贸易网络的空间非均质性特征凸显;地理区位及距离对其组团有间接的影响,社团划分呈现层级性和地理临近组团的特点。4）水产品贸易网络的空间分异特性较为明显,重要节点国家主要集中在中国和东南亚国家,中间中心度高的国家和接近中心度排名靠前的国家具有趋同性,非洲东部及红海沿岸国家的网络中心性影响力较弱。5）在核心国家的水产品市场结构中,中国占据较大份额;国家间的关系变化引起市场结构发生调整;中国水产品进出口品种结构比较单一,进口和出口产品分别主要集中在冻鱼和水产品制品。     

Economic Contribution of Forestry Sector to National Economy in Nepal

Forests are major sources of energy, timber and non-timber forest products, medicinal and aromatic plants, hydrological functions, biodiversity conservation, and also fundamental sources of revenue collection to the nation. Studies indicate that forests could significantly enhance economic growth and create employment opportunities for local communities under intensive management. This paper aims to predict the contribution of the forest sector to the national economy. The economic facets of forestry considered in this paper are revenue generated from timber, non-timber forest products (NTFPs) and medicinal and aromatic plants (MAPs), and protected areas. The ARIMA model was used to forecast the economic contribution of the forestry sector. The study found that the total revenue generated from the selling of timber and fuelwood (USD 50.19 million) was higher than the total revenue collected from protected areas (USD 37.58 million) and NTFPs/MAPs (USD 6.9 million) in the past 15 years. The model projected that the mean revenue for the timber and fuelwood sale will USD 3.5 million for the next ten years. Similarly, the mean revenue will be generated about USD 0.5 million and USD 6.2 million from NTFPs/MAPs and protected areas, respectively, for the next ten years. The study limits to take account the in-kind use of forest products such as timber, fodder, fuelwood, etc., as used by community people within a forest users’ groups. Thus, practicing sustainable forest management, enabling policy documents, establishing forest-based industries, establishing forestry nurseries, conducting agroforestry practices, and tenure security could enhance the forestry sector's economic aspects.     

地质调查产品有效供应理论分析

传统公共经济学中关于公共产品有效供应的分析在理论假设和数学模型上都存在问题。这种理论难以指导现实中公共产品的有效提供,尤其是日益重要的地质调查产品的有效供应。利用一般概率模型和信息经济学模型对地质调查产品的供应进行分析后可以得出对中国地质调查产品有效供应的更清晰的认识。