Determination of Irgarol-1051 and its related s-triazine species in coastal sediments and mussel tissues by HPLC-ESI-MS/MS

A mild, low-temperature analytical approach based on sonication assisted extraction coupled with HPLC electrospray ionization triple quadrupole tandem mass spectrometry has been developed for the simultaneous qualitative and quantitative determination of the four Irgarol-related s-triazine species, namely Irgarol-1051, M1, M2 and M3, in coastal sediments and Green-lipped mussel samples. Mild extraction conditions were necessary for the preservation of the thermally unstable M2. The Multiple Reaction Monitoring (MRM) mode of detection by ESI-MS/MS enabled reliable qualitative identification and sensitive quantitative determination of those s-triazines. This determination method was applied to evaluate the degree of Irgarol-1051 contamination in the sediments and biota of the coastal environment of Hong Kong - one of the busiest maritime ports in the world. All the four s-triazine species were observed in all of the samples. This is the first time that the newly identified M2 and M3 are detected in coastal sediments and biota tissues.     

红三角地区农产品虚拟水的计算分析

农业是世界上最大的水资源利用部门,各种农产品中“寄存”了大量的水资源,蕴涵在产品生产和各种服务中的水资源就是产品或服务中的虚拟水.以红三角地区为例,分析了郴州市、韶关市、赣州市主要农产品的演变特征,计算了主要农产品的虚拟水含量及消费情况,在此基础上探讨了红三角地区农产品的战略性调整和水资源有效配置的政策意义.计算表明,不同区域生产同类型农产品所耗费的水资源不同,加上消费数量的差异,使居民人均农产品虚拟水消费也存在明显差异.红三角地区水资源富足的地区可通过农产品贸易方式更好地发挥区域水资源优势,主动开发和生产高效益的水资源密集型农产品;对局地水资源缺乏的山区,需要通过农产品生产的战略性调整,通过购入水资源密集型农产品,大力发展高效益的特色农业,实现生态-经济-水的良性循环.     

融合降水实况分析产品在四川地区的适用性评估

利用四川省地面自动站2018年6月—2019年5月的逐小时降水观测资料,在邻近插值和双线性插值对比分析的基础上,从晴雨准确率、降水时空特征、降水分量级检验等多个方面,对国家气象信息中心研制的融合降水实况分析产品在四川地区的适用性进行评估分析.评估结果表明:(1)邻近插值和双线性插值对评估结果影响小.(2)融合降水实况分...     

机载激光点云与影像联合测图的技术进展和趋势

本文通过对激光点云与光学影像联合测图所涵盖的关键技术进展进行分析,重点指出目前激光扫描仪进行测绘生产所面临的主要挑战。结合激光扫描技术与光学影像融合后的数据特点与实际行业生产需求,简要探讨了未来激光测图技术发展的趋势及新产品体系构建设想,以期对激光扫描软硬件系统在相关行业应用推广中具有一定参考意义。     

地质岩芯科技资源科普化工作探索与实践——以自然资源实物地质资料中心为例

岩芯科技资源科普化是打通地质科研—科普链条的重要途径,本文通过梳理我国岩芯科技资源现状,分析了岩芯科技资源科普化的现实意义,重点阐述了岩芯科技资源在向地质科普转化5个方面的探索与实践,提出了今后岩芯科技资源科普化工作应建立良好政策机制制度、转变科研人员观念、科技知识向科普转化水平、新技术新手段的应用以及做好科普活动的实施总结等5项工作建议。     

Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.     

高岭石的热稳定性和热处理产物的DTA IR和EPR研究

本文利用DTA、IR和EPR等方法研究了高岭石的热稳定性及100—900℃热处理产物的系统特征。高岭石的热稳定性会因为堆垛层错缺陷浓度的增大而降低。根据IR和EPR实验,所有高岭石热处理过程中的变化包括:脱羟前、脱羟和脱羟后三个阶段。小于400℃时,产物成分和结构同原高岭石相同,≥400℃开始产物的堆垛层错浓度增大并有利于继续升温后的脱羟过程。变高岭石可能介于晶质和非晶质之间。此外,高岭石Ⅰ位Fe~(3+)和变高岭石结构中的Fe~(3+)可能有某些相似的特征。     

利用GPS可降水量校正MODIS近红外水汽数据

针对MODIS近红外水汽产品精度不足以及地基GPS技术解算的大气可降水量地理分布不连续的问题,提出一种利用地基GPS可降水量来校正MODIS水汽产品从而得到区域性连续分布的高精度可降水量的方法。利用GAMIT软件和地基GPS数据解算出IGS站点的大气水含量,建立GPS可降水量与MODIS近红外水汽产品的回归分析模型得到最终的校正结果。通过与实测气象站数据对比分析可知,所提方法有效地结合了MODIS和地基GPS两种遥感水汽技术的优点,能够得到高精度、地理分布连续的大气可降水量,研究结果可为实时天气预报、气候监测等工作提供参考。     

利用资源三号测绘卫星影像实现多尺度4D产品更新

4D产品的快速生产与更新一直以来是测绘地理信息部门研究的重点,采用传统航摄技术生产和更新无图区或陈旧的地理信息资料时,生产困难,成本高,周期长,且消耗大量的人力和物力。针对这些问题,本文采用资源三号测绘卫星影像实现4D产品更新,使得更新速度加快,为多尺度4D产品的生产与更新提供了高效可靠的技术手段。