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41.
Michael H. Ramsey Paul D. Taylor Katy A. Boon 《中国地球化学学报》2006,25(B08):209-210
All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants (organic and metals), previous land uses (e.g. tin mining, railway sidings and gas works), intended future use (housing to nature reserves) and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty (〉70% of measurement uncertainty) in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation (OCLI) method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 (predicted by sampling theory). It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment. 相似文献
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Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg−1 and a range of 2.4–8.7 mg kg−1. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg−1. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ
LF), susceptibility of anhysteretic remanent magnetization (χ
ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils. 相似文献
44.
圆形标志中心子像素定位方法的研究与实现 总被引:18,自引:1,他引:18
黄桂平 《武汉大学学报(信息科学版)》2005,30(5):388-391
采用回光反射材料制作圆形回光反射标志,经摄影后得到标志的“准二值影像”;对标志的椭圆影像进行亚像素边缘提取,经最小二乘椭圆拟合后得到标志中心的子像素级位置。试验表明,可以达到0.02像素的定位精度。 相似文献
45.
煤矿水害多源信息预测方法研究 总被引:1,自引:0,他引:1
基于MAPGIS平台,用Visual C++对其进行二次开发,研制了煤矿水害多源信息预测系统.通过对地震、电法、水文地质等多源数据进行处理后,在MAPGIS系统下进行成图、配准和空间定量分析,建立了预测模型.用该系统对煤矿实际资料进行了处理,结果表明其预测结果较传统方法更为准确. 相似文献
46.
阐述了关于微量相X射线衍射定量分析的一种简便方法———近似线性关系法,它适用于二相体系(或基体吸收系数基本恒定的多相体系)材料中微量相的定量分析。该方法不需要在待测样品中加入参考物相,分析时仅需对一条衍射线进行测定,因而分析时间很短,其测定结果与实际含量的相对误差为-10.2%~ 21.4%,与外标法和内标法的测量结果的精度相当。 相似文献
47.
对中国大陆科学钻探主孔的岩心进行了声发射测量,确定了301~1531m深度的最大主应力。并与钻孔崩落法(深度1269~1655m)测量结果进行了对比,结果表明,声发射测量所得测值基本上落在钻孔崩落法测值的趋势线上,两种方法所得结果一致,说明测量结果可信。测量结果表明科学钻探主孔地应力大小随深度增加,在浅部301m最大主应力为13.4MPa,在深部1655m为55.2MPa。随深度的增加率为0.0279MPa/m。最大主应力方向为N54°±3.3°E,且方向不随深度变化。 相似文献
48.
安正泽 《中国地质灾害与防治学报》2005,16(1):69-71
文章通过对贵州省大方县以公鸡山地裂隙实地调查,认为地裂隙的形成主要与公鸡山一带地下采煤有关。即采煤虚脱,沿先存构造断裂拉张而成。同时叙述了地裂缝特征及危害,并提出防灾减灾措施。 相似文献
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