Atomistic simulation of the structure and elastic properties of pyrite (FeS2) as a function of pressure

Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS₂. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS₂ marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite.     

Petrological and geochronological constraints on high pressure, high temperature metamorphism in the Snowbird tectonic zone, Canada

The upper deck of the East Athabasca mylonite triangle (EAmt), northern Saskatchewan, Canada, contains mafic granulites that have undergone high P–T metamorphism at conditions ranging from 1.3 to 1.9 GPa, 890–960 °C. Coronitic textures in these mafic granulites indicate a near‐isothermal decompression path to 0.9 GPa, 800 °C. The Godfrey granite occurs to the north adjacent to the upper deck high P–T domain. Well‐preserved corona textures in the Godfrey granite constrain igneous crystallization and early metamorphism in the intermediate‐pressure granulite field (Opx + Pl) at 1.0 GPa, 775 °C followed by metamorphism in the high pressure granulite field (Grt + Cpx + Pl) at 1.2 GPa, 860 °C. U–Pb geochronology of zircon in upper deck mafic granulite yields evidence for events at both c. 2.5 Ga and c. 1.9 Ga. The oldest zircon dates are interpreted to constrain a minimum age for crystallization or early metamorphism of the protolith. A population of 1.9 Ga zircon in one mafic granulite is interpreted to constrain the timing of high P–T metamorphism. Titanite from the mafic granulites yields dates ranging from 1900 to 1894 Ma, and is interpreted to have grown along the decompression path, but still above its closure temperature, indicating cooling following the high P–T metamorphism from c. 960–650 °C in 4–10 Myr. Zircon dates from the Godfrey granite indicate a minimum crystallization age of 2.61 Ga, without any evidence for 1.9 Ga overgrowths. The data indicate that an early granulite facies event occurred at c. 2.55–2.52 Ga in the lower crust (c. 1.0 GPa), but at 1.9 Ga the upper deck underwent high P–T metamorphism, then decompressed to 0.9–1.0 GPa. Juxtaposition of the upper deck and Godfrey granite would have occurred after or been related to this decompression. In this model, the high P–T rocks are exhumed quickly following the high pressure metamorphism. This type of metamorphism is typically associated with collisional orogenesis, which has important implications for the Snowbird tectonic zone as a fundamental boundary in the Canadian Shield.     

对目前岩石“全曲线”测试的若干看法

从电液伺服岩石压力试验机工作机理的角度,对目前岩石应力-应变全过程曲线(以下简称“全曲线”)测试中的一些问题进行了分析,提出了自己的看法,目的是为了解决“全曲线”测试的2个问题,即如何测出“全曲线”;如何使测出的“全曲线”真实反映岩石的力学特性,并将其用到工程中。     

止水帷幕在高层建筑深基坑中的应用

某高层建筑基坑西侧紧邻一道河沟,水量较大,采取三重管高压摆喷帷幕止水[1～4],施工完成后通过监测,未发现渗漏、地下水位明显下降和周围建筑物沉降现象。     

岩体断层基础加固与溶洞灌浆处理中的高压灌浆技术

阐述了在岩体断层加固和溶洞处理中的高压灌浆技术,分析了高压灌浆的作用机理,灌浆压力控制的方法,介绍了高压灌浆在水利枢纽工程上的应用效果。     

长效振弦式锚索测力计应用研究

介绍了长效振弦式锚索测力计传感器的工作原理、结构特点、技术性能和配套仪器,并对主要相关技术的应用研究成果作了论述:(1)弱激发电路解决频率不一致问题;(2)微小变形原则解决长期稳定性问题;(3)新数学模型提高了传感器准确度,二次仪表提高了传感器准确度。     

黄壁庄水库副坝塌坑Ⅳ76+1槽段安全监测

介绍了黄壁庄水库副坝塌坑Ⅳ76+1槽段进行的安全监测设计及根据此设计进行的安全监测实施,根据取得的监测资料解决了一直未能确定的主要变形地层的问题,为水库的加固施工和后期的运行安全提供了一定的依据。     

俯伪斜分段密集采煤法三维有限元数值模拟研究

俯伪斜分段密集采煤法,作为一种较新的采煤方法,在我国技术上还不很成熟,因此,首次针对京煤集团木城涧矿大台井的地质条件和赋煤状况,通过简化建立三维立体有限元模型,模拟计算了该矿煤层顶底板在开采前后运动变化情况。结果表明:煤层倾角、推采距离和开采巷道数三者是影响煤层顶底板运动规律的重要因素,得到了表征顶底板运动规律的顶底板法向最大应力和法向最大位移与三影响因素关系曲线,详细阐述了三影响因素下的煤层顶底板运动规律;同时,对现场开采中支撑压力大小,特别是在三影响因素下,超前支撑压力的作用范围与应力峰值位置进行了数值计算,并总结了其影响规律;最后,指出了该数值分析方法对现场开采将具有十分重要的应用价值和指导意义。     

中尺度非静力模式中常用气压分离技术的研究

分析了气压分离和不分离,在几种不同的层结情况下,垂直气压梯度的截断误差.结果表明:基本场取法不当,会引起巨大的截断误差,甚至和不分离时相当;反之,则较小.根据计算,提出了一种取基本场的方法,在一定条件下,可以使气压偏差的垂直梯度的截断误差比不分离时的相应误差小一个量级,从而,可以取较小的垂直分辨率.     

应用区域地基全球定位系统观测分析北京地区大气总水汽量

利用2000年6月1日～8月11日北京地区地基全球定位系统(Globe Positioning System)网遥感大气总水汽量试验的观测资料,分析了北京地区夏季大气总水汽量的时空变化,研究了大气总水汽量与日平均温度、地面水汽压和降水的关系.研究结果表明:大气总水汽量存在明显的时空变化,对于地理位置基本相近的台站,海拔高度的影响比较明显,一般情况下高山站的水汽总量低于平原站;在晴天,地面水汽压与大气总水汽量有较好的相关性,而在云雨日,由于高低层大气湿度的变化常常不同步,用地面水汽压估算的大气总水汽量具有较大的偏差;大气总水汽量短时间内的快速增加往往对应有降水过程出现,但总水汽量的大小与降水量之间并没有明显的相关,在降水预报中应综合考虑总水汽量的前期平均水平、短时的增幅和峰值大小等条件的影响.