钛（Ⅳ）的反相萃取柱色层新体系研究及应用

本文研究了以ｃＨＣｌ＝８ｍｏｌ·Ｌ－１盐酸为移动相，以聚四氟乙烯负载的钽试剂－ＣＨＣｌ３为固定相反相萃取层析钛（Ⅳ）的新体系，柱上层析的钛用ｃＨＣｌ＝３ｍｏｌ·Ｌ－１盐酸洗脱后经二安替比林甲烷光度法测定，不仅钛回收率可达１００％，并可使钛（Ⅳ）与多种离子分离。能用于矿物岩石类复杂样品及其他物质中钛的分离富集与测定，方法简便快速。     

人工合成宝石级翡翠的研究

本文以对化学试剂为原料，用静奇谈怪论同温高压固相转变法合成宝石级翡翠的机理和工艺条件进行了实验研究，测定了与硬玉化学组分相同的玻璃物质的高压熔融曲线和固相转变的区域，提出了在熔融曲线左侧附近固相区生长优质硬玉的观点，以及在宝石级悲翠合成中的若干技术问题。     

Multivariate nonparametric resampling scheme for generation of daily weather variables

A nonparametric resampling technique for generating daily weather variables at a site is presented. The method samples the original data with replacement while smoothing the empirical conditional distribution function. The technique can be thought of as a smoothed conditional Bootstrap and is equivalent to simulation from a kernel density estimate of the multivariate conditional probability density function. This improves on the classical Bootstrap technique by generating values that have not occurred exactly in the original sample and by alleviating the reproduction of fine spurious details in the data. Precipitation is generated from the nonparametric wet/dry spell model as described in Lall et al. [1995]. A vector of other variables (solar radiation, maximum temperature, minimum temperature, average dew point temperature, and average wind speed) is then simulated by conditioning on the vector of these variables on the preceding day and the precipitation amount on the day of interest. An application of the resampling scheme with 30 years of daily weather data at Salt Lake City, Utah, USA, is provided.     

Thermodynamic Modelling of Ore-Forming Mechanism of the Changkeng Gold-Silver Deposits in Guangdong Province

The Changkeng gold-silver deposits consist of a sediment-hosted, disseminated gold deposit and a replacement-type silver deposit. The mineralizations of gold and silver are zoned and closely related to the silicification of carbonate and clastic rocks, so that siliceous ores dominate in the deposit. The mineralizing temperature ranges mainly from 300 to 170℃, and K+, Na+, Ca2+, Mg2+, and Cl- are the major ions in the ore-forming fluid. Calculations of distribution of metal complexes show that gold is mainly transported by hydrosulphide complexes, but chloride complexes of silver, iron, lead, and zinc, which are transformed into hydroxyl and hydrosulphide complexes under neutral to weak-alkaline circumstances in the late stage, predominate in the ore-forming solutions. Water-rock interaction is confirmed to be the effective mechanism for the formation of silver ores by computer modelling of reaction of hydrothermal solution with carbonate rocks. The solubility analyses demonstrate that the precipitation     

国内外PMP/PMF的发展和实践

对20世纪80年代以来PMP／PMF在国内外的发展和实践情况作了简要的介绍和评论。内容包括PMP／PMF定义、估算方法、成果合理性检查和概率。PMP估算方法包括概化估算法、当地暴雨放大、暴雨移置、暴雨组合、推理模式和统计估算法。PMF估算着重介绍了由PMP转化为PMF的产流和汇流特点，以及目前在南非和法语非洲国家广泛应用的经验公式。     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

山东省气候变化及其对冬小麦生产潜力的影响

利用全省 2 7个台站 1 96 1～ 1 998年的温度、降水、日照等基本气象要素资料 ,对山东省气候变化特点进行了分析 ,并对冬小麦生产潜力进行了计算、分析。结果表明 ,山东省年、季平均气温呈波动性增暖趋势 ,降水量呈减少趋势。气候变暖有利于生产潜力的提高 ,冬小麦气候生产潜力总的变化趋势是波动性的上升 ,但较光温生产潜力倾向率小 ,反映了小麦生育期内光、温、水的综合影响。     

星载被动微波遥感反演降水算法回顾

根据不同的降水反演方法对多种利用SSM／I、TMI反演降水的算法进行归类总结，按下垫面检测和降水反演算法两大步骤进行简要描述，并分经验法、半经验(半物理)法、物理模式法及物理廓线法4类方法对多种算法作了回顾。