大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

On the tidal variation of the geopotential

In this paper analytical expressions are derived for the temporal variations ofJ ₂ andJ ₂₂ due to the tides of the solid Earth, taking into account only the deformation of the mantle, and employing a procedure already used by the authors in their Hamiltonian theory of the Earth's rotation, which obtain the necessary parameters in a direct way by integration of those provided by a selected model of Earth interior.Numerical tables giving the periodic variation of coefficients are given, as well as a new prediction for UT1. For J ₂ and J ₂₂ the amplitudes reach such a magnitude that both two variations should not be ignored in studies involving the analysis of highly precise satellite tracking data. Moreover, the possibility of improving our knowledge of the value of those harmonic coefficients in only a more exact digit appears as to be strongly dependent on the limitations in the theoretical modeling of the variations of the inertia tensor due to solid tides.     

On Szebehely's problem for holonomic systems involving generalized potential functions

We consider the problem of finding the generalized potential function V = U _i(q ¹, q ²,..., q ⁿ)q ⁱ + U(q ¹, q ²,...;q ⁿ) compatible with prescribed dynamical trajectories of a holonomic system. We obtain conditions necessary for the existence of solutions to the problem: these can be cast into a system of n – 1 first order nonlinear partial differential equations in the unknown functions U ₁, U ₂,...;, U _n, U. In particular we study dynamical systems with two degrees of freedom. Using adapted coordinates on the configuration manifold M ₂ we obtain, for potential function U(q ¹, q ²), a classic first kind of Abel ordinary differential equation. Moreover, we show that, in special cases of dynamical interest, such an equation can be solved by quadrature. In particular we establish, for ordinary potential functions, a classical formula obtained in different way by Joukowsky for a particle moving on a surface.Work performed with the support of the Gruppo Nazionale di Fisica Matematica (G.N.F.M.) of the Italian National Research Council.     

The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

Distribution and mode of occurrences of radionuclides in phosphogypsum from the Aqaba and Eshidiya fertilizer plants, Jordan

Phosphogypsum is a waste by-product of the phosphate fertilizer industry that has relatively high concentrations of some U decay-series radionuclides such as ^226Ra and ^210Pb. The distribution and environmental mobility of radionuclides in phosphogypsum are an important concern because this gypsum by-product is used for wallboard, in agriculture and as a soil amendment. This study determined the distribution of ^226Ra, ^210Pb, within phosphogypsum stacks of varying age and among three size fractions （coarse： 〈0.212 mm; medium： 0.212-0.053 mm; fine： 〈0.053 mm）, in phosphogypsum derived from Aqaba and Eshidiya fertilizer plants. The results indicated that ^226Ra and ^210Pb were generally uniformly distributed in phosphogypsum stacks and showed no significant difference in the concentration of these elements with the age of stack. In the Aqaba phosphogypsum ^226Ra was slightly 10% enriched in the coarse fraction, while ^210Pb was 10% enriched in the free size fraction. In the Eshidiya phosphogypsum ^226Ra and ^210Pb contents were both relatively enriched （10%） in the fine size fraction.     

Hydrology and hydrogeology of Sakaryabaşı Karstic springs, Çifteler, Turkey

The Sakarya River is one of the largest rivers in Turkey and is fed mainly from Sakaryabaşı springs. The Sakaryabaşı springs are located in the Central Anatolia and issue from confined/semi-confined karst having a thermal component and therefore, having quite different hydrogeological characteristics as compared to the Taurus Karst region, a typical example of the Mediterranean type of karst. The karstic carbonate rocks that form the groundwater reservoir are overlain by a thick semi-pervious overburden of mainly clastics of Neogene age. Tectonics is the major factor controlling the occurrence of the karst springs in the area where topography is rather flat. This study aimed at explaining the occurrence and movement of the karst groundwater within the system by use of hydrogeological, chemical, and isotopic tools. Isotopic composition of the waters revealed that all waters in the region are of meteoric origin and the thermal component is due to deep circulation. The catchment area of the hydrogeological system extends to the south and groundwater movement is towards the outlets, which are in a depression along a major fault. The movement of the groundwater, based on analysis of remotely sensed images, is controlled mainly by structural elements.     

Geophysical methods applied to fault characterization and earthquake potential assessment in the Lower Tagus Valley, Portugal

The study region is located in the Lower Tagus Valley, central Portugal, and includes a large portion of the densely populated area of Lisbon. It is characterized by a moderate seismicity with a diffuse pattern, with historical earthquakes causing many casualties, serious damage and economic losses. Occurrence of earthquakes in the area indicates the presence of seismogenic structures at depth that are deficiently known due to a thick Cenozoic sedimentary cover. The hidden character of many of the faults in the Lower Tagus Valley requires the use of indirect methodologies for their study. This paper focuses on the application of high-resolution seismic reflection method for the detection of near-surface faulting on two major tectonic structures that are hidden under the recent alluvial cover of the Tagus Valley, and that have been recognized on deep oil-industry seismic reflection profiles and/or inferred from the surface geology. These are a WNW–ESE-trending fault zone located within the Lower Tagus Cenozoic basin, across the Tagus River estuary (Porto Alto fault), and a NNE–SSW-trending reverse fault zone that borders the Cenozoic Basin at the W (Vila Franca de Xira–Lisbon fault). Vertical electrical soundings were also acquired over the seismic profiles and the refraction interpretation of the reflection data was carried out. According to the interpretation of the collected data, a complex fault pattern disrupts the near surface (first 400 m) at Porto Alto, affecting the Upper Neogene and (at least for one fault) the Quaternary, with a normal offset component. The consistency with the previous oil-industry profiles interpretation supports the location and geometry of this fault zone. Concerning the second structure, two major faults were detected north of Vila Franca de Xira, supporting the extension of the Vila Franca de Xira–Lisbon fault zone northwards. One of these faults presents a reverse geometry apparently displacing Holocene alluvium. Vertical offsets of the Holocene sediments detected in the studied geophysical data of Porto Alto and Vila Franca de Xira–Lisbon faults imply minimum slip rates of 0.15–0.30 mm/year, three times larger than previously inferred for active faults in the Lower Tagus Valley and maximum estimates of average return periods of 2000–5000 years for M 6.5–7 co-seismic ruptures.