无机增强纤维Ⅰ.钛酸钾纤维

结晶质的钛酸钾纤维因其性质特殊而备受青睐，本文介绍了二钛酸钾、四钛酸钾、六钛酸钾和八钛酸钾纤维的结构、性质、用途，及国内外的研究现状．     

赤砂沸石对氮磷钾吸附与释放的研究

本文以安徽省繁昌县赤砂沸石为试验材料，以黄红壤为参照，研究了丝光沸石为主的天然沸石对ＮＨ、Ｈ＿２ＰＯ及Ｋ￣＋的吸附与释放，结果表明：赤砂沸石的吸铵量和吸磷量为黄红壤的３倍；其中易释放铵和可释放铵占总吸铵量８０％以上；易释放磷和可释放磷占７０％以上；赤砂沸石的速效钾含量为黄红壤的７倍左右，而钾位缓冲容量（ＰＢＣ￣Ｋ）则为黄红壤的３５倍左右。赤砂沸石用做肥料调理剂和土壤改良剂，将能够减少土壤中氮、磷、钾的流失，并提高肥料中养分的利用率。     

FTIR studies of reactions between the nitrate radical and haloethenes

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.     

区域航空γ能谱场地球化学解释及预测方法的探讨

本文以“铀矿区域评价准则”为依据,试用因子分析主成分比值法,铀对钍(钾)的区域相对场法和铀成矿有利指数法,对我国YW-10和YW-10B两个测区的区域航空γ能谱场进行了地球化学解释及预测方法的研究,与已知矿区660测区从宏观上做了对比分析,并研究了γ能谱参数在走向长270km,宽50—70km空间上的分布变化规律。研究结果表明,这些方法对了解成岩时原始铀的分布及后期铀的地球化学活动规律,估计成岩、成矿阶段铀源岩可能提供的生铀量,识别铀成矿有利地区是有用的。     

Investigation of NaCl deliquescence in porous substrates using RH-XRD

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.     

腾格里地区盐湖的盐类沉积特征

腾格里沙漠122个盐湖分为石盐、石盐-芒硝、石盐-白钠镁矾及芒硝(石膏)4种类型。盐湖含盐系厚度一般4～9m,总体呈现下部为含盐碎屑沉积,上部以盐类沉积为主,构成储卤层,卤水赋存其中,由湖岸至湖心储卤层厚度增长。含卤层理渐小,卤水含KCl渐高。盐湖中矿物主要为碳酸盐矿物,以芒硝、石膏为主的硫酸盐矿物、石盐以及粘土矿物。盐湖卤水以晶间卤水为主。许多卤水含K+大于2g/L。K+含量最高的红盐池,平均含量达19.14g/L。对钾矿而言,在盐湖分布相对集中地区,有一定的综合开发利用前景。     

温度对复分解法制硝酸钾生产过程的影响

探讨以硝酸铵和氯化钾为原料、复分解法制硝酸钾工艺中 ,配料、硝酸钾结晶、氯化铵结晶等处操作温度对产量、质量、操作时间等的影响     

青海盐湖氯化镁资源开发

青海盐湖中有丰富的氯化镁资源 ,由氯化镁可生产多种镁产品 ,特别是以青海盐湖卤水提钾老卤中的镁资源开发镁产品 ,既可获得经济效益 ,又可治理氯化镁老卤造成的危害与污染 ;开展高值镁产品的研究可为盐湖开发的纵深发展打基础     

三元体系RECl_3（RE＝Dy，Yb）－HOAc－H_2O（30℃）的研究

测定了三元体系ＲＥＣｌ３（ＲＥ＝Ｄｙ，Ｙｂ）－ＨＯＡｃ－Ｈ２Ｏ（３０℃）的平衡态的溶度数据并绘制了相应的溶度图。在两个体系中分别得到了ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ两种固相。依据ＨＯＡｃ对ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ有盐抗作用这一结论得到了一种制备ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ的ＨＣｌ—ＨＯＡｃ法。同时，在分析测定酸的重量百分浓度时，利用“差减法”得到了Ｈ＋的准确含量。     

WINDOW FACTOR ANALYSIS:THEORETICAL DERIVATION AND APPLICATION TO FLOW INJECTION ANALYSIS DATA

Window factor analysis(WFA)is a self-modeling method for extracting the concentration profiles ofindividual components from evolutionary processes such as flow injection,chromatography,titrationsand reaction kinetics.The method takes advantage of the fact that each component lies in a specificregion along the evolutionary axis,called the‘window’.Theoretical equations are derived.The methodis used to extract the concentration profiles and spectra of seven bismuth species from data obtained byGemperline and Hamilton,who injected bismuth perchlorate into a flowing stream of hydrochloric acid.