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51.
The possible influences of the increasing anthropogenic emissions in India on tropospheric ozone and OH 总被引:2,自引:0,他引:2
A 3-D chemical transport model (OSLO CTM2) is used to investigate the influences of the increasing anthropogenic emission in India. The model is capable of reproducing the observational results of the INDOEX experiment and the measurements in summer over India well. The model results show that when NOx and CO emissions in India are doubled, ozone concentration increases, and global average OH decreases a little. Under the effects of the Indian summer monsoon, NOx and CO in India are efficiently transported into the middle and upper troposphere by the upward current and the convective activities so that the NOx, CO, and ozone in the middle and upper troposphere significantly increase with the increasing NOx and CO emissions. These increases extensively influence a part of Asia, Africa, and Europe, and persist from June to September. 相似文献
52.
The classic two-level or equivalent two-level model that includes only the statistical equilibriumof radiative and thermal processes of excitation and quenching between two vibrational energy levelsis extended by adding chemical production to the rate equations. The modifications to the non-localthermodynamic equilibrium source function and cooling rate are parameterized by φc, which characterizesthe ratio of chemical production to collisional quenching. For applications of broadband emission of O3 at9.6 μm, the non-LTE effect of chemical production on the cooling rate and limb emission is proportionalto the ratio of O to O3. For a typical [O]/[O3], the maximum enhancements of limb radiance and coolingrate are about 15%-30% and 0.03-0.05 K day-1, respectively, both occurring near the mesopause regions.This suggests that the broadband limb radiance above ~80 km is sensitive to O3 density but not sensitiveto the direct cooling rate along the line-of-sight, which makes O3 retrieval feasible but the direct coolingrate retrieval difficult by using the O3 9.6 μm band limb emission. 相似文献
53.
M. Karl H.-P. Dorn F. Holland R. Koppmann D. Poppe L. Rupp A. Schaub A. Wahner 《Journal of Atmospheric Chemistry》2006,55(2):167-187
Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower. 相似文献
54.
Analysis of tropospheric ozone residual (TOR) data from satellite measurements indicates an increasing trend of tropospheric ozone over the Yangtze Delta region of China. The increasing trend can be derived both from the annual mean TOR and from the monthly mean TOR except for January and March. The increase rate of the decadal mean TOR was 0.82 DU during 1978-2000. The impact of this long-term trend on the climate and atmospheric oxidizing capacity over the region should be further studied. Data comparison shows a significant correlation between the TOR and surface ozone data collected at Lin'an background station in the Yangtze Delta region, suggesting an internal connection between both quantities. 相似文献
55.
R. Müller J.-U. Grooß D. S. McKenna P. J. Crutzen C. Brühl J. M. Russell III L. L. Gordley J. P. Burrows A. F. Tuck 《Annales Geophysicae》1998,17(1):101-114
Severe chemical ozone loss has been detected in the Arctic in the winter and spring of 1995–96 by a variety of methods. Extreme reductions in column ozone due to halogen catalysed chemistry were derived from measurements of the Halogen Occultation Experiment (HALOE) on board the Upper Atmosphere Research Satellite in the Arctic vortex. Here, we discuss further aspects of the HALOE observations in the Arctic over this period. Potential problems, both in the data themselves and in the methodology of the data analysis are considered and the reason for the differences between the Arctic ozone losses deduced from HALOE data version 17 and 18 is analysed. Moreover, it is shown that HALOE measurements in the Arctic in winter and spring 1995–96 compare well with observations by other ground-based and satellite instruments. 相似文献
56.
A commercial version of the prototype New Zealand narrowband interference filter instrument has been run at Garmisch-Partenkirchen since autumn 1977. The vicinity of the Dobson stations Hohenpeissenberg and Arosa permitted a check of the filter instrument's utility, reliability and long-term stability in total ozone measurement by (i) station to station-or short-range intercomparisons of daily means and (ii) a several days' direct intercomparison at Arosa in spring 1978.The regression analysis with the Hohenpeissenberg data-covering the five month autumn-winter 1977/78 period with highly variable ozone-shows that the filter instrument's direct-sun modeX
AD
total ozone values were systematically too low by a conversion factor of 0.93. The excellent proportionality between the instruments is indicated by the standard deviation of only 1,3%. The (–7.0±1.3%) bias perfectly agrees with the result reported byBasher [1] for a similar, yet direct, intercomparison.During the direct Arosa intercomparison the filter instrument also tracked down short-time variations in a remarkable, though biased, parallelism with the Dobson instruments, and theX
AD
daily means fit well into the prognostic relationship derived from the preceding autumn-winter short-range intercomparison.A creeping deterioration of the characteristics of the 305.5 nm double filter then prevented any furtherX
AD
total ozone intercomparison. No final decision is possible whether this behaviour after a half year's run is typical or just an unusual exception. The otherwise excellent long-term stability is demonstrated by the comparison of theX
CD
daily means with the HohenpeissenbergX
AD
data for a 1 1/2 year's period (autumn 1977–spring 1979), resulting in the same bias relationship as for theX
AD
total ozone measurements. 相似文献
57.
Irene Pundt Jean-Pierre Pommereau Celine Phillips Eric Lateltin 《Journal of Atmospheric Chemistry》1998,30(1):173-185
It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small. 相似文献
58.
S. J. Reid M. Rex P. Von Der Gathen I. Fløisand F. Stordal G. D. Carver A. Beck E. Reimer R. Krüger-Carstensen L. L. De Haan G. Braathen V. Dorokhov H. Fast E. Kyrö M. Gil Z. Lityñska M. Molyneux G. Murphy F. O'Connor F. Ravegnani C. Varotsos J. Wenger C. Zerefos 《Journal of Atmospheric Chemistry》1998,30(1):187-207
In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism. 相似文献
59.
The time damping rate of gravity wave in the range of 30-70 km is calaclated in three circumstances:(1) adiabatic process,(2) diabatic process caused by atmospheric cooling,and(3) diabatic process resulting from atmospheric photochemical heating and cooling.The results indicate that the photochemical heating is as important as Newtonian cooling and its contribution to the time damping rate of gravity wave can not he negligible. 相似文献
60.
The time damping rate of gravity wave in the range of 30-70 km is calaclated in threecircumstances:(1)adiabatic process,(2)diabatic process caused by atmospheric cooling,and(3)diabatic process resulting from atmospheric photochemical heating and cooling.The resultsindicate that the photochemical heating is as important as Newtonian cooling and its contribution tothe time damping rate of gravity wave can not he negligible. 相似文献