MULTICOMPONENT DETERMINATIONS BY A MEMBRANE-DISCRIMINATED GAS PHASE ANALYZER AND SUCCESSIVE REGRESSION IN THE FIDUCIARY REGION

A membrane-discriminated gas phase analyzer is proposed for multicomponent determinations. Nitrogengas flows countercurrent through outer and inner channels in a tube-in-tube arrangement. The onlycommunication between the two channels occurs through a 500μm aperture covered by a porous PTFEmembrane. A mixture of organic compounds (up to four components) is injected into the inner channelby a heated backflushed injector and the sample components diffusing into the outer channel aremonitored by a flame ionization detector (FID). A calibration set, consisting of pure components, binary,ternary and quaternary mixtures (a total of 64 samples), provides the known data base: temporal profilesof the FID output as a function of sample composition, Although the overall response behavior is nota linearly additive function of individual analyte concentrations, the use of successive inverse multiplelinear regression (while continually altering the choice of the calibration samples considered for theforward regression, on the basis of the most recent values of the predicted unknown sample composition)is shown to yield analytical results for unknown samples that are in good agreement with their true values.     

Properties of iron at the Earth's core conditions

Summary. The phase diagram of iron up to 330 GPa is solved using the experimental data of static high pressure (up to 11 GPa) and the experimental data of shock wave data (up to 250 GPa). A solution for the highest triple point is found ( P = 280 GPa and T = 5760 K) by imposing the thermodynamic constraints of triple points. This pressure of the triple point is less than the pressure of the inner core–outer core boundary of the Earth. These results indicate that the density of iron at the inner core–outer core boundary pressure is close to 13 g cm⁻³, which lies close to the seismic solutions of the Earth at that pressure. It is thus concluded that the Earth's inner core is very likely to be virtually pure iron in its hexagonal close packed (hcp) phase.
It is shown that four properties of the Earth's inner core determined from seismology are close in value to the corresponding properties of hcp iron at inner core conditions: density, bulk modulus, longitudinal velocity, and Poisson's ratio. The density–pressure profile of hcp iron at inner core conditions matches the density–pressure profile of the inner core as determined by seismic methods, within the spread of values given by recent seismic models.
This indicates that the Earth is slowly cooling, the Earth's inner core is growing by crystallization, and the impurities of the core are concentrated in the outer core. The calculated temperature at the Earth's centre is 6450 K.     

海河平原东部地区地面沉降机理与趋势

海河平原东部地区是中国水资源最紧缺的地区之一。地下水开采量占该地区供水总水量的60％以上。深、浅层地下水超采量均超过500亿m^3。该区也是山前拦蓄地表径流最高的地区,大小水库达1820多座,拦蓄能力320亿m^3,控制山区流域面积近90％。在地下水补给源减少与大规模超采地下水的综合作用下,造成平原区河流干涸、地下水水位持续下降、含水层疏干及地面沉降等环境地质问题。同时诱发了含水层之间强越流渗透以求动力场平衡问题,第四系松散地层出现垂向压密而导致地层塑性变形。在滨海平原区,区域性地层垂向压密变形存在缓慢发展趋势。研究表明,地面沉降致灾过程至少存在3个阶段,即自然沉降机制阶段、缓变劣变质变阶段以及快速衰变破坏阶段。缓变劣变质变阶段是采取措施减灾最佳时期。     

SDINS/GPS in-flight alignment using GPS carrier phase rate

The alignments of the strapdown inertial navigation system (SDINS) utilizing GPS carrier phase rate measurements is introduced. In this paper, a measurement model of GPS carrier phase rate under two antenna configurations is derived in order to be used for the SDINS alignment process. For in-flight alignment, the performance of the proposed SDINS/GPS integration method is analyzed using the covariance analysis and the overall performance is briefly confirmed by the navigation result of a van test. Furthermore, we find that during in-flight alignment the proposed SDINS/GPS integrated system using GPS carrier phase rate measurements can be implemented in real time because the integer ambiguity problem resulting from carrier phase measurements is avoided.     

Comparison of the dynamic response of a saturated soil between two models

The dynamic response of marine sediment to ocean surface waves is treated extremely by marine geotechnical and coastal engineers. In the area of conventional hydrodynamics, the assumption of im-permeable rigid seabed has been used as the boundary of water waves theories and the waves parameters de-duced from the theory have not referred to the interac-tion of water waves and seabed. In the area of soil mechanics, many engineers regard the response as slow loading according to the Zienkewiczs[1…     

基于拓扑构建的多边形区域间运算的新方法

提出了一种新的直观的方法进行多边形区域之间的运算.首先将需要计算的多边形区域的边进行自动拓扑构建,利用多边形区域的边将平面划分为n个小多边形区域;然后生成这些多边形区域的内点,通过判断小多边形区域的内点是否在原始多边形区域内来确定小多边形区域是否选取;最后合并选取的小多边形即为所求.试验结果表明,该方法思路清晰、鲁棒性强,在GIS中得到了有效的运用.     

道路平面测设计算的通用公式

基于各类道路线型曲率呈线性变化的共同特性,给出了线元上任意点坐标方位角的统一计算公式,进而提出了适用于所有道路线型平面测设计算的中桩坐标、边桩坐标的通用公式。在此基础上,讨论线路外一点对应中桩的计算以及直线与线路交点的计算,给出了相应的计算方案。     

星载GPS载波相位周跳探测方法

在星载GPS载波相位测量中,周跳的探测与修复对最后的定位精度起着至关重要的作用。本文根据在星载条件下GPS载波相位测量的观测时间短、环境变化复杂、所得历元少和基本不受对流层延迟影响等特点,论述了适用于星载高动态环境GPS载波相位周跳探测和修复的方法,并指出各种方法的特点和适用要求。