大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究

多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。     

油田开发中的相态特征及流体组份研究--以大张坨凝析气藏为例

大张坨凝析气藏是在我国发现的高含量凝析气藏之—．开发中据相态特征及流体组份研究结果，适时调整开发方式．1994年开始试采，1995年初实施循环注气开发．该气藏的开发经历了衰竭试采循环注气2个开采过程，开发过程中定期取地层流体样品进行相态特征和流体组份研究，并注重其成果的应用，凝折油采出率29．0％，取得了较好的开发效果．证实了相态研究在凝析气藏循环注气开发全过程应用的重要性．     

长江日流量混沌变化特性研究——Ⅰ相空间嵌入滞时的确定

为了以新途径探索长江水量变化规律并在此基础上做出预测,全面而系统地研究了宜昌站日流量混沌变化特性并建立了新预测模型.重点论述相空间嵌入滞时的确定.分析了传统的自相关函数法和真实矢量场法确定嵌入滞时的优劣,并提出以广义相关函数合理确定嵌入滞时的方法.研究结果表明广义相关函数法是一个合理又可操作的途径.     

Predictive instantaneous optimal control of elastic structures during earthquakes

A predictive instantaneous optimal control (PIOC) algorithm is proposed for controlling the seismic responses of elastic structures. This algorithm compensates for the time delay that happens in practical control applications by predicting the structural response over a period that equals the time delay, and by substituting the predicted response in the instantaneous optimal control (IOC) algorithm. The unique feature of this proposed PIOC algorithm is that it is simple and at the same time compensates for the time delay very effectively. Numerical examples of single degree of freedom structures are presented to compare the performance of PIOC and IOC systems for various time delay magnitudes. Results show that a time delay always causes degradation of control efficiency, but PIOC can greatly reduce this degradation compared to IOC. The effects of the structure's natural periods and the choice of control gains on the degradation induced by the time delay are also analyzed. Results show that shorter natural periods and larger control gains are both more sensitive and more serious to the degradation of control efficiency. Finally, a practical application of PIOC is performed on a six‐story moment‐resisting steel frame. It is demonstrated that PIOC contributes significantly to maintain stability in multiple degree of freedom structures, and at the same time PIOC has a satisfactory control performance. Copyright © 2003 John Wiley & Sons, Ltd.     

Predictive instantaneous optimal control of inelastic structures during earthquakes

A new inelastic structural control algorithm is proposed by incorporating the force analogy method (FAM) with the predictive instantaneous optimal control (PIOC) algorithm. While PIOC is very effective in compensating for the time delay for elastic structures, the FAM is highly efficient in performing the inelastic analysis. Unlike conventional inelastic analysis methods of changing stiffness, the FAM analyzes structures by varying the structural displacement field, and therefore the state transition matrix needs to be computed only once. This greatly simplifies the computation and makes inelastic analysis readily applicable to the PIOC algorithm. The proposed algorithm compensates for the time delay that happens in practical control systems by predicting the inelastic structural response over a period that equals the magnitude of the time delay. A one‐story frame with both strain‐hardening and strain‐softening inelastic characteristics is analyzed using this algorithm. Results show that the proposed control algorithm is feasibile for any inelastic structures. While the control efficiency deteriorates with the increase in magnitude of the time delay, the PIOC maintains acceptable performance within a wide range of time delay magnitudes. Finally, a computer model of a six‐story moment‐resisting steel frame is analyzed to show that PIOC has good control results for real inelastic structures. Copyright © 2003 John Wiley & Sons, Ltd.     

A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.     

Measuring the k–S–p relations on DNAPLs migration

Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.     

Numerical models of tectonic deformation at the Baltica–Avalonia transition zone during the Paleocene phase of inversion

Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence.     

Global thermal and dynamical perturbations due to Cretaceous mantle avalanche

The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone.     

VLBI观测的电离层延迟改正模型研究

电离层是大气层中的一个电离区域，高度范围大约在60－1000km。电磁波信号穿越电离层时其传播速度会发生变化，传播路径也会略微发生弯曲，从而使信号的传播时间乘以在真空中的光速不等于信号源至测站的几何距离。对VLBI观测来讲，电离层引起的差异可达近百米百米。文中从电磁波的传播原理出发，讨论了信号传播速度和传播路径变化引起的VLBI观测延迟；对目前采用的各种电离层延迟模型进行了分析总结；并指出单频率VLBI观测应顾及高阶项和路径弯曲的影响或使用区域性电离层延迟改正模型。