Actinic flux and photolysis frequency comparison computations using the model PHOTOGT

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.     

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

自重湿陷性黄土地区桩基设计探讨

根据自重湿陷性黄土的特点、《湿陷性黄土地区建筑规范》（GB50025—2004）和《建筑桩基技术规范》（JGJ94—94）中关于桩基设计的对比分析，通过自重湿陷性黄土场地工程实例分析计算，依据负摩擦产生的机理——中性点理论，论述了自重湿陷性黄土场地中桩基设计应考虑中性点，而不应全部计入负摩阻的观点。     

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

引黄水在北大港水库蓄存期水质咸化的研究

依据引黄水在北大港水库蓄存期水质咸化的事实以及传质理论,定性地分析了引黄水水质咸化的主要原因,包括盐碱土传质作用、蒸发浓缩作用以及风的扰动加速传质作用等.在北大港水库旁修建了一个模拟试验水池,进行了现场模拟试验研究.依据水量平衡和氯离子总量平衡的原理,分别定量地计算了传质作用和蒸发浓缩作用对水质咸化影响的比重.结果表明,在模拟水池蓄水后的30 d内,传质作用对水质咸化影响的比重有随时间增加而增长的趋势;30 d后,传质作用对水质咸化影响的比重稳定在80%,蒸发浓缩作用对水质咸化影响的比重稳定在20%,说明导致水质咸化的最主要因素是盐碱土传质作用.     

不同辐射传输方案对中尺度降水影响的对比分析

在MM5非静力稳定中尺度气象模式中引进了建立在δ-4流近似和相关-k分布基础上的对云水、雨水、冰晶和霰的辐射特性进行详细描述的辐射传输方案。新建立的辐射传输方案和MM5中原有的辐射传输方案在华南暴雨中的模拟结果相互比较，并与天气实况的对比表明:辐射在中尺度暴雨中起着重要的作用；辐射传输方案对云辐射特性描述的准确程度对于地面降水影响是明显的；不同的辐射传输方案对地面降水的影响存在较大的差异，并且这些差异在白天比在夜间明显；辐射传输过程对地面降水影响的差异主要表现在降水中心上，而对降水的地理分布改变很小；相对而言，不同的辐射传输方案之间对短波描述的差异对地面降水的影响明显，而对长波描述差异的影响不大；新辐射传输方案能够在一定程度上改进MM5对中尺度降水的模拟能力。     

Ekman动量近似下中间边界层模式中的风场结构

发展了一个准三维的、中等复杂的边界层动力学模式，该模式包含了EKman动量近似下的惯性加速度和Blackadar的非线性湍流粘性系数，它进一步改进了Tan和Wu(1993）提出的边界层理论模型。该模型在数值计算复杂性上与经典Ekman模式相类似，但由于包含了Ekman动量近似下的惯性项，使得该模式比传统Ekman模式更近于实际过程。中详细地比较了该模式与其他简化边界层模式在动力学上的差异，结果表明：在经典的Ekman模式中，由于忽略了流动的惯性项作用，导致在气旋性切变气流（反气旋性切变气流）中风速和边界层顶部的垂直速度的高估（低估），而在半地转边界层模式中，由于高估了流动惯性项的作用，结果与经典Ekman模式相反。同样，该模式可以应用于斜压边界层，对于Ekman动量下的斜压边界层风场同时具有经典斜压边界层和Ekman动量近似边界层的特征。     

旋转流地转适应过程与能量转换规律

利用一维线性浅水模式从一个比较普遍的角度对地转适应过程中能量转换的特点进行分析。中首先考虑了两类不同的初始不平衡流的适应问题。一个是Gill所采用的质量不平衡模型，即初始场是静止的，只有水面扰动；另一个是Rossby中所考虑的动量不平衡模型，其初始不平衡流中只有风场的扰动，对这两个模型的适应过程而言，一个显的 特点就是能量转换率始终不会大于1／2或小于0，即适应过程中有位（动）能的释放和向动（位）能的转换，但释放出的能量最多只有其中的一半可以保留在最后的平衡场中。另外，本对任意初始不平衡流适应过程中的能量学特征也进行了分析，指出对于偏差场（相对于一定基本态）的动能和位能而言，上述能量转换关系依然成立。     

紫外线模式预报方法的研究和试验

文章介绍了在T106全球谱模式中应用大气辐射传输模式预报紫外线辐射(UVR)的方法,给出了试验运行的结果.UVR强度的划分考虑了到达地表的UVR通量.参考国内、外紫外线(UV)预报服务的经验,制定了5个日光暴露的级别、相应的紫外线指数(UVI)及防护措施.1999年9月起,国家气象中心已在NOTES网上每月不定期地展示UVR预报的一些结果,2000年9月起,在Cray-C92业务操作系统上实施了连续的试验运行.