1991 年6月江淮持续暴雨的云系特征分析

通过对GMS静止卫星的红外数据处理，获得了1991年夏季江淮梅雨期暴雨大范围的平均云分布。对1991年6月6次江淮暴雨过程逐时和3小时的GMS红外云图动画和照片的分析，得到了该地区梅雨期暴雨的三种中低纬云系相互作用的云型演变模型图，并利用由卫星气象中心处理的NOAA卫星的TOVS水汽反演资料，结合低层的θse和急流分析，给出了1991年6月江淮暴雨的水汽输送的一些特征。     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

华南花岗岩物源成因特征与陆壳演化

华南不同时代的花岗岩按物质来源及成因可划分为:幔源(分异)系列:幔-壳混源(同熔)系列;壳源改造(重熔)系列和幔-壳混源碱性系列等四个不同的系列,简要阐述了划分四类系列的岩石学、地球化学的依据。侧重根据Sm-Nd、Rb-Sr同位素成分,以二元混合模型计算了花岗岩源区物质组成中,上壳和亏损地幔组份各占的比例。在此基础上探讨了不同物源成因系列花岗岩形成与华南陆壳演化的内在联系:东安、雪峰旋回褶皱系阶段花岗岩物源成因类型比较多样,有幔源(分异)系列、不成熟壳源、成熟壳源改造(重熔)系列等;加里东,海西期以陆壳改造(重熔)系列为主;印支、燕山期活化区(地洼)阶段,在地幔活化激发下,中国东部陆缘形成幔—壳混源(同熔)系列花岗岩和相应的火山岩;但沿内部断裂带,在壳下地幔热传输及构造作用下引起陆壳重熔,形成属于壳源改造(重熔)系列花岗岩。同位素的研究证明了:地洼阶段的构造-岩浆活动主要动力是来自壳下地幔的活化。     

非理想热力学混合作用对固溶体矿物热容的影响——以斜方顽火辉石-正铁辉石固溶体为例

斜方顽火辉石-正铁辉石(MgSiO_3-FeSiO_3)中Fe~(2+)及Mg~(2+)在M_1和M_2两种非等效位置上进行非理想混合。研究表明,辉石的等压热容(C_p)强烈依赖于组成,呈非线性关系,可表示为: 低温时热容的非理想混合效应显著,随着温度的升高,等温热容曲线(空间热容曲面)从一个极大值点(峰脊)分解为两个极大值点(峰脊),且逐渐趋向于理想混合热容直线(或平面)。     

天目山火山岩的反序现象及其成因

浙江天目山地区的中生代火山岩由流纹岩、英安岩、安山岩组成,其喷发存在反序现象。笔者用带状岩浆房的模式解释了该区火山岩的特点,应用各种物理化学方法建立了岩浆房中存在的温度、密度和粘度梯度。主要元素及微量元素的行为及其定量模拟表明,分离结晶是导致岩浆成分变化的主要机理。然而,各种矿物在岩浆房中的沉降速度计算表明,尤其是酸性岩浆中,晶体的重力沉降是不可能的。因此,岩浆房中存在的分离结晶现象主要是通过对分离作用进行的。     

多功能雾化室在ICP—AES中的应用研究

本文研究了一种多功能雾化室装置,以探索ICP-AES技术中溶液进样的新方式;并对雾化系统的主要参数进行测试,取得最佳的匹配条件。该雾化室装置包括旋流雾化、循环雾化和氢化-雾化等系统,可在同一操作条件下进行工作,适应多种分析的需要。并可任意选择合适的雾化射程来增强元素谱线强度的信背比和雾化的稳定性,以达到改善分析的精密度和检出限。     

诸暨洞室工程稳定性评价

本文主要根据杭铁诸暨387洞室工程所取得的地质资料及室内岩石物理力学试验指标为依据,对该工程的围岩进行分类、並对围岩进行有限元方法的分析,及对围岩局部块体利用赤平极射投影方法进行稳定性验算,对该工程主体洞室的稳定性作出评价。     

Model studies of the impact of chemical inhomogeneity on SO2 oxidation in warm stratiform clouds

A one-dimensional, time-dependent model of the physics and chemistry of a warm stratiform cloud is used to study the possible impact of chemical inhomogeneity among cloud and raindrops on the oxidation of SO₂ in clouds. The effects of chemical inhomogeneity are examined using two contrasting models: In Model 1 a bulk-solution parameterization is adopted which effectively treats all cloud and raindrops as if they are chemically homogeneous; in Model 2 we allow the cloud and raindrops to have a dichotomous distribution. The dichotomous distribution in Model 2 is simulated by assuming that the two groups of cloud droplets nucleate from two chemically distinct populations of condensation nuclei; one being acidic and the other being alkaline. While the two models yield essentially identical results when the ambient levels of H₂O₂ are greater than the ambient levels of SO₂, the rate of conversion of SO₂ to sulfuric acid and the amount of sulfate removed in the precipitation can be significantly enhanced in Model 2 over that of Model 1 under conditions of oxidant limitation (i.e., H₂O₂ < SO₂). This enhancement is critically dependent upon the fraction of alkaline nuclei assumed to be present in Model 2 and arises from the rapid increase in the aqueous-phase reaction between O₃+S_IV at high pH. Our results suggest that cloud models which adopt a bulk-solution parameterization for cloud droplet chemistry, may underestimate the amount of in-cloud SO₂ oxidation under oxidant-limited conditions.     

局地强风暴云团与中尺度锋面波动

本文分析了1982—1988年2—5月份的41例与中尺度锋面波动相关联的局地强风暴云团的活动和演变特征，给出了其强盛期天气系统配置模式及其在天气尺度云系演变中的表现型式，最后对其移动做了一般性讨论。