柱色谱分离-分子筛络合洗脱过程中正构烷烃单体碳同位素分馏研究

应用气相色谱-气体同位素质谱（GC-C-IRMS）分析正构烷烃单体碳同位素之前,需要对饱和烃样品中正构烷烃和异构烷烃进行预分离、富集,在预分离和富集过程中正构烷烃单体碳同位素是否发生分馏是高精度分析正构烷烃单体碳同位素比值（δ13C）的关键。本文以正构烷烃混合溶液为对象,利用柱色谱、5Å分子筛络合、环己烷-正戊烷混合溶剂两次洗脱,GC-C-IRMS分析正构烷烃单体碳同位素,研究前处理过程中正构烷烃单体碳同位素是否发生分馏。结果表明：使用柱色谱分离前后,多数正构烷烃单体碳同位素比值相差-0.2‰~0.2‰;当5Å分子筛不完全络合时,未络合的正构烷烃单体碳同位素比值偏重约0.7‰,可能发生了微弱的碳同位素分馏,但并未影响洗脱后的正构烷烃单体碳同位素比值;使用环己烷-正戊烷混合溶剂洗脱前后,碳同位素比值相差-0.2‰~0.5‰,以同样方式洗脱第二次,获得的正构烷烃单体碳同位素比值与模拟样品相差-0.3‰~0.2‰。分析不同回收率（>20%）正构烷烃的单体碳同位素比值,处理前后的差值基本在0.3‰以内,可见当正构烷烃回收率低至20%左右时,其单体碳同位素仍未发生明显分馏。柱色谱分离-5Å分子筛络合-混合溶剂洗脱方法适用于回收率大于20%的正构烷烃单体碳同位素分析。     

Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.     

钢筋-沥青隔震层非线性震动特性研究

为了研究钢筋-沥青隔震层的材料与几何非线性震动特性,对钢筋-沥青隔震结构进行了振动台试验,分析了结构在不同加速度幅值输入时的隔震性能。同时,在钢材的应力-应变关系基础上,考虑构件竖向力的二次矩效应,提出了钢筋-沥青隔震层骨架曲线的计算方法,并结合双线型恢复力模型的滞回规则,建立了相应的恢复力模型。利用建立的恢复力模型,编制程序进行了弹塑性时程分析,并与试验结果作对比。结果表明:当钢筋-沥青隔震层的受力钢筋进入弹塑性阶段时,隔震层能够吸收大部分地震能量,显著降低上部结构的地震反应;弹塑性时程分析结果与试验结果吻合较好,由此建立的恢复力模型准确并且适用,可为钢筋-沥青隔震层的工程设计与非线性地震反应分析提供参考。     

Assessment of Nitrate—Nitrogen Distribution in Kansas Groundwater, 1990–1998

Nitrate-nitrogen (nitrate-N) in groundwater is a potential problem in many parts of Kansas.From 1990 to 1998, 747 water samples were collected from domestic, irrigation, monitoring,and public water supply wells primarily from the western two-thirds of the state, and analyzedfor nitrate-N by the Kansas Geological Survey. Nitrate-N concentrations of the 747 samplesanalyzed range from 29% with less than or equal to 3 mg/L, 51% between 3 and 10 mg/L,and 20% greater than or equal to 10 mg/L. Factors that show a statistically significantrelationship with the occurrence of nitrate-N in Kansas groundwater in this assessment includegeographic area of the state, depth of well, and age of well. Nitrate-N levels of wells screenedin the High Plains aquifer in south-central Kansas showed a statistically higher concentrationthan samples collected from the High Plains aquifer in the western portion of the state.Comparison of nitrate-N with depth of well indicated that shallower wells throughout the stategenerally have higher nitrate-N values than deeper wells. Irrigation wells older than 1975showed statistically higher nitrate-N concentration than wells installed during and since 1975,possibly related to changes in well-construction practices and regulations that occurred in 1975.     

新疆北天山Ms≥5.0地震前的中长期地震活动空间图像特征

对新疆北天山l931年以来6级以上、l970年以来5级以上地震前的地震活动空间图像进行了分析，发现震前多有不同程度的地震空区或条带出现，其孕育时间一般为8－14年；震源深度呈现由浅而深、通常超过25km的变化，孕育时间一般为3—4年。同时对上述地震活动空间图像前兆特征的机理进行了定性分析，并对所选资料的精度等问题进研了讨论。     

高压气藏不动管柱分层压裂工艺研究与应用

川西低渗高压气藏具有多层系的特点,层间距离一般在十至百米左右。为了提高气井产量与开采经济效益,鉴于气井加砂压裂后压井会严重伤害储层,影响压裂效果,采用压裂管柱直接作为生产管柱,研究形成了以FCY211及Y241封隔器不同组合的两层不动管柱分层压裂工艺。同时,在成熟的两层分压工艺基础上,结合投球选压工艺,研究形成了以“工具分层＋投球选压”不动管柱三层分层的压裂工艺。现场应用实践表明,分层压裂极大地增加了单井的产能,取得了明显经济效益,对类似气藏的多层压裂与开采提供了有益参考。     

黏土不透水层确定及水压力分布规律试验研究

工程上将满足一定条件下的黏土层介质视为隔水层。通过模型试验的方法,对黏土层为不透水层的确定方法以及黏土层内部的水压力分布规律进行了研究。通过试验分析得出了某给定黏土层为隔水层的特定条件：即找出了黏土层的厚度、渗透系数及层上水头高度三者的关系和给定黏土层的起始水力坡降,得到了黏土层内已渗透水部分的水压力分布规律。试验结果对工程实际具有一定的指导作用。     

厚度对月壤微波辐射亮温的影响

基于嫦娥系列卫星微波辐射计数据的月壤厚度反演是中国月球科学研究的重要目标之一。基于辐射传输方程,数值模拟了不同频率、（FeO+TiO₂）含量和表面温度条件下厚度对月壤微波辐射亮温的影响;基于嫦娥二号卫星微波辐射计（Chang’E Lunar Microwave Sounder,CELMS）数据,结合Apollo 计划获取的月壤厚度资料及其他月壤厚度资料,系统分析了厚度对CELMS观测数据的影响。结果表明：频率、（FeO+TiO₂）含量、表面温度对亮温的影响远大于厚度对亮温的影响,是基于CELMS数据进行月壤厚度反演的重要影响因素;低频、低（FeO+TiO₂）含量、低温条件下,厚度对CELMS数据的影响最大;利用3 GHz、凌晨时刻的CELMS数据进行月陆地区月壤厚度反演可行。研究结果对基于嫦娥系列卫星CELMS数据的月壤厚度反演具有重要参考意义。     

改进的HRNet应用于路面裂缝分割与检测

针对利用传统卷积神经网络进行路面裂缝分割时存在准确率低、信息丢失及边缘模糊的问题,本文提出了基于改进HRNet模型的路面裂缝分割算法。模型在原始HRNet的基础上进行改进,主干网络部分采用DUC模块代替双线性插值上采样;下采样改为passthrough layer代替原始卷积;在模型解码部分,进行逐级上采样的同时引入SE-Block,对不同特征层的融合重新标定权重。通过与原始HRNet及传统卷积神经网络U-Net对比可知,本文算法在公共数据与自制数据集上的分割精度表现优秀,F1分值分别达到了91.31%和78.69%,可以很好地满足实际工程的需求。     

Multi-Layer Strain Rate Field Controlled by Netlike Plastic-Flow in the Lithosphere in Central-Eastern Asia

INTRODUCTIONAccording to the“netlike plastic-flow (NPF)”continental dynamics model ( Wang, 1993a ,1993b; Wang,et al .,2001c) ,the continental lithosphere generally includes 4 tectonic deformationlayers frombottomtotop:the NPFlayer (i .e .thelowerlithosphere ,includingthelithospheric mantleandlower crust) ,the transitional weak layer distributed discontinuously (i .e .the so-called low-velocity/high-conductivitylayer) ,the shear fracturinglayer (i .e .the seismogenic layer inthe upperc…