一株低温降解菌的分离鉴定及其降解特性研究

从刺参(Apostichopus japonicus)养殖池塘环境中驯化分离筛选到1株低温有机物和氨氮降解菌株DB11。根据其形态特征、生理生化特性以及16S rDNA序列分析,将该菌株鉴定为马氏副球菌(Paracoccus marcusii)。经驯化,该菌株以刺参饵料为唯一营养源,低温(15℃)、低接种量(<5×10-3)条件下能同时高效降解饵料中的有机物和氨态氮,5 d时间内对富集培养基中COD和NH4+-N的降解率分别达50%和98%。进一步研究其降解特性表明,菌株生长适温15~30℃,生长适宜pH值为7~10,降解刺参饵料中COD和NH4+-N的最适温度条件为15~20℃、最适pH条件为8.0~8.5;在最适降解条件下、接种量为5×10-3时,对10~20 g/L高质量浓度的刺参饵料液中COD降解效果显著,3 d时间去除率达56.9%~65.7%,对1~20 g/L质量浓度的刺参饵料液中NH4+-N 3 d时间的去除率达91.7%~99.9%。     

The causes of low-temperature demagnetization of remanence in multidomain magnetite

In this paper, the mechanisms of low-temperature demagnetization of remanence in multidomain magnetite are considered. New experimental observations of the behaviour of the saturation isothermal remanence, thermoremanence and partial thermoremanence at low temperatures are presented. The results show that there are two main contributions to this low-temperature demagnetization. The first and predominant contribution (type-1 demagnetization) is due to 'kinematic' domain state reorganization and occurs throughout cooling from room temperature to the Verwey transition, T _v , at 120–124  K. The second contribution arises from the change in anisotropy from cubic to monoclinic at T _v , which changes the overall domain structure of the grain. On warming in zero field, some domain walls will not return to their original positions but will take up a position that leads to a lower net remanence (type-2 demagnetization). In stoichiometric magnetite, demagnetization does not occur at 130  K at the isotropic point, T _k , contrary to some previous predictions. In non-stoichiometric magnetite, the influence of the Verwey transition is greatly reduced, and anomalous behaviour is observed at T _k .     

冻土区天然气水合物钻井泥浆冷却系统设计及关键参数计算

泥浆冷却技术是天然气水合物钻探的关键技术之一,低温泥浆可以抑制天然气水合物在钻进和提钻过程中分解,有利于钻获水合物实物样品。新型天然气水合物钻井泥浆冷却系统主要包括载冷剂制冷器、翅片管式换热器、温度监测与记录和防冻装置4部分。制冷机组采用变频启动,减小了野外施工中配套发电机的功率,大幅度降低油料消耗;翅片管式换热器中泥浆与载冷剂对流换热,换热面积大,换热效率高;温度监测与记录装置对4个关键节点的温度进行监测和记录,同时防冻装置可防止泥浆在换热器中结冰堵塞,影响正常使用。运用传热学和流体力学理论对泥浆与载冷剂对流换热过程进行计算,在满足制冷要求的前提下,换热器换热面积是10.58 m2,管路压力损失为0.34 MPa。     

扬子地块西南缘大面积低温成矿时代

中国西南地区(川、滇、黔、桂、湘)发育有世界上很典型的低温成矿域,其面积之大(约90万km2)、包含的矿种之多(Au、Hg、Sb、As、P、Pb-Zn、U、Ni-Mo-PGE、重晶石、冰州石和分散元素等)、矿床组成和组合之复杂,在全球十分鲜见。扬子地块西南缘是中国西南大面积低温成矿域的重要组成部分。近年来,作者采用Rb-Sr、Sm-Nd、Ar-Ar等多种同位素定年方法,对扬子地块西南缘产出的磷矿、金矿、锑矿等低温矿床的成矿时代进行了较系统的研究。文章总结了这些研究成果,并结合前人的资料,初步拟定出该区存在三期大规模低温成矿作用,它们分别相当于晚元古代—早古生代(晚震旦世—早寒武世)、晚加里东期(晚志留世—早泥盆地)和燕山期(晚侏罗世—中白垩世)。该区的磷矿、重晶石矿和黑色页岩中的镍钼铂矿主要形成于晚元古代—早古生代,同位素年龄主要为585～540Ma;赋存于前寒武纪浅变质碎屑岩中的金-锑-钨矿床主要形成于晚加里东期,同位素年龄主要为435～380Ma;产于寒武系以后地层中的锑矿床主要是在中燕山期成矿,同位素年龄主要为160～140Ma;而该区的卡林型金矿和汞矿主要在燕山中晚期大规模成矿,同位素年龄主要为170～80Ma。     

Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China

The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo₉₁), enstatite (En_92?93), garnet (Alm_20?23Prp_53?58Knr_6?9Grs_12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al₂O₃ and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp_44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm_29?34Prp_32?50Grs_15?39) + omphacite (Jd_24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km^?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.     

由膨润土提铝残渣直接合成五配位体有机硅化合物

研究了以膨润土提铝残渣为原料，采用低温加热法直接合成有机硅化合物新方法。由实验确定了最佳的合成条件。用红外光谱法和X射线衍射法分析了合成产物的结构。结果表明，当以碱金属氢氧化物为介质时，合成的产物为五配位体有机硅化合物；在最佳合成条件下，钠盐和锂盐的收率分别为63．0％和44．9％。     

负温条件下激光位移传感器的标定

在使用激光位移传感器测试冻土位移中,由于测试现场环境条件恶劣,厂家给出的传感器线性度会降低,因此,需要对所有传感器在使用前应模拟使用时的环境条件重新进行标定。为验证激光位移传感器在冻土测试中的适用性,依据德国森萨帕特FT-50RLA220型激光位移传感器的结构、使用特点、技术指标,设计了由控温箱、标定支架、激光位移传感器、量块及数据采集装置组成的标定的装置,进行了不同负温条件下对激光位移传感器标定,并依据标定试验结果进行拟合参数修正,得到不同环境温度下的试验结果的线性度和迟滞特性。试验结果表明：不同的环境温度下,两个激光位移传感器与标准厂家测试曲线存在差异,不同负温条件下标定的两个激光位移传感器的拟合优度R²分别为0.999和1;线性度最大值分别为0.88%FS和0.32%FS。     

2008年初湖北省低温雨雪冰冻天气温度平流配置分析

利用NCEP／NCAR再分析资料,对2008年1月11日-2月1日湖北省低温雨雪冰冻过程进行温度平流空间分布诊断分析。结果表明：低温雨雪冰冻期间,湖北省近地层不断有弱冷空气补充和渗透;中层暖平流、低层冷垫和南方沿冷垫向上爬升的暖空气是湖北省降雪最基本的条件,而湖北省东部出现强降雪的另一个更重要的原因就是低层偏东回流带来的暖平流;当冷空气充斥湖北省上空整层大气时,则预示雨雪将减弱停止。     

西南印度洋脊龙旂热液区富铝蚀变黏土矿物类型和地球化学特征研究

产出于不同地质背景下的热液成因黏土矿物组成、晶体结构及化学成分等信息,可指示与海底热液作用有关的水-岩反应过程和流体的物理化学条件变化。但目前对于以西南印度洋脊为代表的超慢速扩张脊热液区的黏土矿物研究程度较低,尚未了解其经历的热液蚀变作用及形成过程。本文综合应用SEM-EDS、XRD、FT-IR、EPMA和LA-ICP-MS等多种分析测试手段对采自龙旂热液区矿化蚀变角砾的形貌结构、矿物组成及其化学成分进行系统表征。研究表明:该蚀变角砾中的共生矿物相主要由具二八面体结构、富Al端元的蒙皂石族矿物贝得石与蛋白石组成,角砾中可见呈细粒浸染状的TiO_2。蚀变黏土矿物的化学成分较为单一,具有富Al、贫Mg和贫Fe的特征;其稀土元素总量普遍不高(2. 43～43. 45μg/g),配分模式呈负Eu异常(0. 31～0. 53)而未显示Ce异常(1. 09～1. 16)。推断产出于硫化物堆积丘体边部的矿化角砾长期受酸性、相对还原的、低温热液流体持续叠加和淋滤改造,除Al和Ti以外大部分元素被活化迁移,形成矿物组成简单的富铝黏土矿物相。本研究查明了龙旂热液区新的蚀变黏土矿物类型及其元素地球化学特征,反映该区广泛发育低温热液蚀变作用,为进一步探讨西南印度洋超慢速扩张脊热液成矿系统的水-岩反应过程提供了一定依据。     

Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.