Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Study on the characteristics of the marine boundary layer in the Equatorial Pacific

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Effects of crab–halophytic plant interactions on creek growth in a S.W. Atlantic salt marsh: A Cellular Automata model

The Bahía Blanca Estuary (38° 50′ S, and 62° 30′ W) presents salt marshes where interactions between the local flora (Sarcocornia perennis) and fauna (Chasmagnathus granulatus) generate some kind of salt pans that alter the normal water circulation and condition its flow and course towards tidal creeks. The crab–vegetation dynamics in the salt marsh presents variations that cannot be quantified in a reasonable period of time. The interaction between S. perennis plant and C. granulatus crab is based on simple laws, but its result is a complex biological mechanism that causes an erosive process on the salt marsh and favors the formation of tidal creeks. To study it, a Cellular Automata model is proposed, based on the laws deduced from the observation of these phenomena in the field, and then verified with measurable data within macroscale time units. Therefore, the objective of this article is to model how the interaction between C. granulatus and S. perennis modifies the landscape of the salt marsh and influences the path of tidal creeks. The model copies the basic laws that rule the problem based on purely biological factors.The Cellular Automata model proved capable of reproducing the effects of the interaction between plants and crabs in the salt marsh. A study of the water drainage of the basins showed that this interaction does indeed modify the development of tidal creeks. Model dynamics would likewise follow different laws, which would provide a different formula for the probability of patch dilation. The patch shape can be obtained changing the pattern that dilates.     

疏勒河流域昌马灌区泉水量预测分析

疏勒河流域农业灌溉主要采用地表水灌溉 ,泉水为该区农业灌溉的主要水源之一 ,该文利用 2 0世纪 90年代的测流资料 ,采用有限差分方法对疏勒河中游泉水量的变化趋势进行预测分析 ,结果显示 ,随着时间的延长 ,泉流量呈逐渐减小的趋势 ,但下降梯度逐渐变小 ,最终趋于稳定     

山岳型旅游区人文建筑环境后效与调控模型

许多山岳型旅游区内或其流域上游，都建有人文建筑，而且在急剧增多，导致自然环境日趋恶化，其中乱建疗养院和旅馆的影响最为严重。通过地监测并全面分析张家界环境演变趋势，发现住宿施对环境的影响，比其他游乐设施更为明显。张家界国家森林公园生态环境的脆弱因子是金鞭溪水质。金鞭溪水质恶化主要表现为蓝藻，绿藻迅速繁殖，感官质量下降。主要原因是磷污染较重，总磷年均值100%超标。本文提出了基于环境脆弱因子的动态阈值调控模型，通过计算得出：在不超出张家界景区最为脆弱的环境因子-金鞭溪水质标准：总磷≤0.02前提下，金鞭溪上游接待区住宿设施生态阈值的动态系列：春季临界床位数为1186，夏季为3057，冬季为545，秋季为333。目前的建筑规模已超过了金鞭溪上游接待区住宿设施生态阈值。     

斜坡失稳时间的协同预测模型

斜坡岩体由小变形到大变形乃至滑坡的发生，实质上是由组成斜坡的各子系统协同作用的结果．将协同学引入斜坡的稳定性预测评价中，并提出了一种新的斜坡失稳时间预测模型──协同预测模型．经实例检验，该模型预测精度较高，可用于滑坡的短期或临滑预报．