Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

华南叠加-重熔型花岗岩的成生机制

南岭成矿带是太平洋及印度洋板块对中国大陆板块联合作用的结果。囊括大量稀有-有色金属矿床的中心弧形构造-岩浆岩系正是这个“钳式”应力场作用的集中体现,“深部叠加-重熔”——以板块持续运动和相对高速率运动产生并贮集能量为前提,以俯冲板块不断带入新的挥发物质为条件,随着动力热和挥发组分的不断回流—汇集—贮集而使仰冲板块深部预热的原地或途中固化-半固化的先期熔融的岩浆岩发生了二次甚至多次的熔融作用。     

盆地烃类运移二维二相流动数学模型分析与应用实例

从地质固体系统与流体系统相互作用所形成的能量流、物质流的观点，系统地论述了建立烃类运移主要控制方程，即烃水两相拉格朗日型异常地层压力方程和饱和度方程，研制了开发了烃类运移数值模拟系统，阐明了该耦合系统的要素功能和求解方法，提供了改善系统模拟精度的措施，最后介绍了该模拟系统在松辽盆地东南隆起某测线的应用实例。     

金矿床石英中负价氮的发现及赋存状态探讨

利用ｘ光电子能谱测试，发现金矿床石英中有负价氮的存在。这种氮的结合能为３９８ｅＶ士，该结合能氮的化合物有多种，氦均为负价态，其中有Ｓｉ＿３Ｎ＿４Ｓｉ的ｘ光电子能谱有二个谱峰值：１０３．４ｅＶ和１０１．９ｅＶ，前者为ｓｉＯ＿２的结合能，后者为Ｓｉ＿３Ｎ＿４的结合能。Ｎ和Ｓｉ的结合能均表明石英中有Ｓｉ＿３Ｎ＿４为负三价态。石英中负价Ｎ可能为替代氧的类质同象成分。     

局域积能振荡模型在地震研究中的应用

采用非均匀介质中能量的非线性积累过程，模拟唐山７．８级和大同６．１级地震的前兆场演化，发现能量主要聚集在介质参数发生改变的地区，而且能量的增强呈现聚集－恢复－聚集的过程，说明地震孕育过程中出现的各种前兆特征，与地壳内能量的非线性聚集有关。     

应变能释放随时间变化的聚类方法研究

由于线性回归模型应用的广泛性，本文设定样品集的趋势是线性的，在用最优分割法对地震活动性类研究的基础上引进线性模型，扩大了最优分割法在地震活动性分类中的应用，将降类问题与建模问题有机地结合起来，去揭示地震活动性中的某种内在规律，这对于探索地震预报，研究地震发生的规律性有一定的实际意义。     

地震能量空间分布局域标度特性的初步研究

本文利用计算机数值模拟数据及大同地区三次中强地震前后的地震记录资料，在空间能量分布“漫化”的基础上，通过多重分形方法着重对能量空间分布的局域标度性质及可能的震兆信息进行研究。结果表明能量分布普遍地表现出多标度分形特性，但相同ｑ值Ｄｑ的时间变化或Ｄｑ￣ｑ谱形态变化不明显。中强地震前标度指数谱ｆ（α）￣α曲线由两端大体对称或右端略低变为左端明显下降，同时α及ｆ（α）数值分布范围扩展、顶点右移。计算机模     

耗能-隔震柔性底层钢管混凝土-钢筋混凝土组合框架的实验研究

本文用钢管混凝土柱作为结构底层耗能柱、用承重墙和隔震器控制结构底层倒塌破坏,从而提出了一种新的耗能-隔震柔性底层结构体系。通过本文12根钢管混凝土柱和文献[7]中7根钢管混凝土柱的低周疲劳实验,初步确定了钢管混凝土柱地震损伤模型的参数;通过两个钢管混凝土-钢筋混凝土三层框架模型和一个纯钢筋混凝土三层框架模型的拟动力实验,研究和比较了两类结构体系的地震损伤。     

Seismic risk of circum-pacific earthquakes I. Strain energy release

Commonly used earthquake “whole process” frequency - magnitude and strain energy - magnitude laws are merged to obtain an analytic expression for an upper bound magnitude to regional earthquake occurrenceM ₃, which is expressed primarily in terms of the annual maximum magnitudeM ₁ and the magnitude equivalent of the annual average total strain energy releaseM ₂. Values ofM ₃ are also estimated graphically from cumulative strain energy release diagrams. Both methods are illustrated by application to the high seismicity of the circum-Pacific belt, using Duda’s (1965) data and regionalisation. Values ofM ₃ obtained analytically, with their uncertainties, are in agreement with those obtained graphically. Empirical relations are then obtained betweenM ₁,M ₂, andM ₃, which could be of general assistance in regional seismic risk considerations if they are found to be of a universal nature. For instance.M ₃ andM ₂ differ by one magnitude unit in subregions of the circum-Pacific.     

Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer

The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the _m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most _m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised _m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear _m relation for the stable case; (3) data that define collinear _m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of _m and z/L.