日本大沼湖沉积物碳氮比值、有机碳同位素特征及其近400年的古气候环境意义

通过对日本大沼湖沉积物样品总有机碳含量(TOC)及其稳定同位素、总氮含量(TN)和C/N值的测定,结合沉积岩芯火山灰和1℃年代,分析了大沼湖沉积物中有机质的来源,探讨了沉积物有机碳同位素的主要影响因素.结果表明:大沼湖沉积物中有机质主要来源于自生藻类,受陆源输入的影响较小;沉积物δ13C值指示了夏季温度的变化.过去400年来,大沼湖地区存在1660～ 1730年和1780～ 1860年两个明显的冷期,与邻近地区冰芯、树轮和湖泊沉积物记录的冷期基本一致,分别对应于Maunder和Dalton太阳黑子极小期.     

微细浸染型金矿床的稳定同位素特征与成因探讨

对我国众多沉积岩系中的微细当染型金矿床开展了较为系统的稳定同位素地球化学研究,非常分散复杂的氢氧同位素组成被认为是沉积盆地流体的一个典型特征,这是因为盆地流体中水的两个主要来源－海水和大气降水,经不同程度的水－岩反应同位素交换后又以不同比例相互混合,再加上有机物和粘土矿物的相变水在不同阶段以不同比例加入。     

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals： Constraints on the Tectonic Setting and Evolution of the Fuping Complex, Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

澜沧江河流沉积物碎屑锆石U-Pb年龄、Hf同位素组成及其地质意义

为研究澜沧江沉积物的物质来源及相邻地块的地壳生长和演化规律,利用LA-MC-ICP-MS分析技术,对澜沧江河流沉积物碎屑锆石进行了U-Pb年龄和Hf同位素研究。结果表明：锆石U-Pb年龄主要有5个年龄段,分别是＜177 Ma、201~418 Ma、428~544 Ma、581~1189 Ma和1406~2533 Ma,主要峰值为260 Ma、788 Ma、1 827 Ma和2 474 Ma。其年龄分布特征与北羌塘地块的年龄分布非常一致,说明澜沧江沉积物主要来源于北羌塘地块;结合Hf同位素分析结果,能够反映源区北羌塘地块的形成与演化历史。新太古代-中元古代是北羌塘地块从亏损地幔物质增生的地壳持续生长阶段,它们构成现今北羌塘地块全部地壳物质的78%以上,此后直到0.64 Ga,北羌塘地块的地壳增生作用基本结束。     

鄂尔多斯盆地西峰油田原油地球化学特征及其成因

通过对鄂尔多斯盆地西峰油田原油进行系统地采样和高分辨率的GC-MS、IRMS分析,研究了原油的生物标志化合物和碳同位素组成特征,并且进行了油源对比,探讨了其成因。研究资料指示了所研究原油属于同一成因类型;原油有机母质为菌藻类和高等植物,特别是高等植物为原油的形成作出了贡献;原油形成于弱还原和淡水或微咸水环境;原油均为成熟原油;原油地球化学特征和上三叠统延长组长,油层组具有亲缘关系,反映了原油主要来源于长,油层组。这些研究结果为盆地的石油勘探提供了科学依据。     

与火山岩容矿有关的海底热水沉积矿床硫同位素地球化学证据

对国内与火山岩容矿有关的海底热水沉积矿床新疆阿巴宫、铁-铅锌矿、甘肃桦树沟铁-铜矿床、新疆阿舍勒铜锌矿、新疆阿尔泰可可塔勒铅锌矿等矿床硫化物进行硫同位素测定,这些矿床硫化物和硫酸盐的硫同位素组成分别为-4.3‰~1‰(阿巴宫)、+8.1‰~+33.4‰(桦树沟)、-3.3‰~+8.2‰(阿舍勒矿床硫化物)、-20.6‰~5.1‰(阿尔泰可可塔勒)。硫化物的硫同位素变化范围较小,硫同位素可以达到平衡,也可以没有达到平衡,获得的δ34SΣS值有+18‰~29‰之间,δ34SΣS值高;表明与火山岩控矿有关的海底热水沉积矿床热液中硫的来源,不是直接来源岩浆去气的硫,而是岩浆去气硫与海水硫酸盐硫混合而成的硫。     

西藏措勤晚白垩世英安岩的厘定与地球化学特征

野外地质调查和SHRIMP锆石U/Pb地质年代学研究表明,拉萨地块中带措勤地区发育一套形成于晚白垩世中期的英安岩(88.5±1.2 Ma)。该套火山岩具有岛弧火山岩的地球化学特征,为地壳深部岩浆岩部分熔融形成的Ⅰ型岩浆岩,经历了明显的斜长石分离结晶作用。与同时代的侵入岩相比,该套火山岩为高度演化的岩浆,Rb/Sr比值较高,但Sr/Y比值较低。在拉萨地块内部,广泛发育的90～85 Ma的岩浆作用与新特提斯洋的北向俯冲作用相关。     

华北克拉通古老大陆地壳组成及演化

对鞍本、冀东、鲁西、阴山等早前寒武纪典型地区和深部物质进行了深入研究,总结了华北克拉通早期地壳形成演化历史。揭示出鄂尔多斯地块本身强烈卷入了古元古代晚期构造热事件。首次在华北克拉通划分出3个>2.6 Ga古陆块。     

中甸红山矽卡岩铜矿稳定同位素特征及其对成矿过程的指示

红山铜矿床位于三江地区义敦岛弧南端的中甸弧,是在晚三叠世甘孜-理塘洋盆向西俯冲过程中形成的一个中型规模的矽卡岩矿床.通常,矽卡岩体就是铜矿体或铜矿化体,主要呈似层状、层状、脉状及透镜体状产于大理岩与角岩接触带或局部在角岩中,未见其与侵入岩直接接触.通过对不同成矿阶段所形成的石榴石、磁铁矿、磁黄铁矿、黄铁矿、黄铜矿、方解石等典型矿物以及大理岩的稳定同位素特征研究,发现矽卡岩的最主要组成矿物石榴石的δ18OSHOW范围为6.2～8.3‰,反映了矽卡岩可能直接继承隐伏斑岩体的氧同位素组成.根据磁铁矿的氧同位素组成(5.5～7.1‰)所计算的磁铁矿化阶段成矿流体的δ18OSHOW为13.1～14.7‰(400℃)或12.5～14.1‰(500℃),暗示有富集δ18O的CO2溶入到成矿流体中.硫化物的δ18SCDT范围4.45～6.20‰,说明矿床具有高度均一的硫源,并且在硫化物的结晶沉淀过程中,流体中硫同位素分馏很弱.由此推测主成矿期成矿流体的δ18S∑S为5.6±0.6‰.矿床中的大理岩的δ13CPDB为2.0～2.2‰,δ18OSMOW为24.0～24.8‰,说明大理岩是由海相碳酸盐岩经重结晶作用而成.成矿晚期阶段形成的方解石脉的δ13C范围是-2.4～1.7‰,δ18OSMOW范围是16.3～22.4%o,表明其C和O主要来源于大理岩.总之,我们推测红山矽卡岩很可能主要是由中酸性岩浆浅成侵位时局部同化碳酸盐围岩所形成的一种富含钙质成分的次生岩浆就位于碎屑岩与碳酸盐岩之间的构造薄弱带冷凝固结而成,矽卡岩型矿化与深部斑岩型矿化具有共同的成矿物质和成矿流体来源.