泊江海子矿白垩纪地层冻结软岩力学特性试验

针对泊江海子矿白垩纪地层中的砂岩和泥岩,分别进行了不同温度（-20~20℃）下的三轴压缩试验。试验结果表明：在-20~20℃之间,白垩纪地层软岩的峰值强度和弹性模量均随温度的降低及围压的升高而增加,其中中砂岩的峰值强度随温度的变化程度明显大于泥岩,即其对温度的敏感性更高;而岩石峰值处的轴向应变则随温度的下降而减小;另外,随着温度降低,两种岩石的峰值内摩擦角和黏聚力均有一定程度的提高,并且抗剪强度指标的增加主要集中在黏聚力上。通过对试验结果的整理和分析,掌握了白垩纪地层软岩在不同低温和围压下的力学特性和规律,为西部地区矿井冻结法设计与施工提供了可靠的依据。     

Early Cambrian high pressure/low temperature metamorphism in the southeastern Tarim craton in response to circum-Gondwana cold subduction

The circum-Gondwana subduction initiated by the early Cambrian has been suggested to reflect the establishment of the modern plate tectonics. The metamorphic rocks with low thermobaric (T/P) ratios indicative of cold subduction in the present tectonic regime have not been well investigated. To better understand the circum-Gondwana subduction and to test its possible link with the emergence of the modern plate tectonics, this study focused on blueschist-facies metamorphic rocks in the Altyn Tagh of the southeastern Tarim craton. Mineral assemblage and chemistry, phase equilibrium modelling, and quartz-in-garnet Raman elastic geobarometry reveal that the zoisite blueschist and glaucophane (Gln)-bearing quartz schist in northern Altyn Tagh were metamorphosed to lawsonite to epidote blueschist-facies at 520–545 °C and 16–19 kbar. It reflects high-pressure (HP)/low temperature (LT) metamorphism with low T/P ratios of <300 °C/GPa and thermal gradients of <10 °C/km. These blueschist-facies metamorphic rocks underwent rapid decompression starting at P-T conditions of <495 °C and <9.6 kbar during exhumation. Ar-Ar geochronology records paragonite Ar-Ar plateau ages of 520–506 Ma for the zoisite blueschist samples and phengite Ar-Ar plateau ages of 522–516 Ma for the Gln-bearing quartz schist samples, suggesting that the peak HP/LT metamorphism occurred prior to ca. 522 Ma. Based on new results and available data from the major Gondwana blocks, cold subduction was suggested to profoundly operate along circum-Gondwana in the early Cambrian after the amalgamation of Gondwana. The extensive circum-Gondwana subduction represents the earliest global cold subduction in Earth’s history associated with the establishment of the modern plate tectonics, as directly recorded by the studied early Cambrian blueschist-facies metamorphic rocks and a dramatic drop in the mean T/P of metamorphism since the early Paleozoic.     

茂名油页岩沉积有机质特征及古气候意义

基于海洋沉积确定的始新世晚期至渐新世早期(约33.5 Ma)的气候过渡期是新生代全球性气候事件,但长期以来相关的陆相沉积记录研究则比较缺乏。本文对形成于始新世晚期至渐新世早期的茂名油柑窝组油页岩样品进行了有机质丰度、烃类组成、单体烃碳同位素组成等分析,以期研究低纬度陆相沉积有机质对古近纪始新世-渐新世气候过渡期(EOT)的响应。研究结果显示,埋藏较浅的上部层位样品正构烷烃碳同位素组成显著正偏,为-19.1‰~-25.9‰,平均值为-22.2‰;而下部层位样品正构烷烃碳同位素组成在-23.7‰~-30.2‰,平均值为-26.3‰。两个样品正构烷烃碳同位素组成之差在1.5‰~8.1‰,平均值之差为4.6‰。正构烷烃碳同位素组成的显著差异指示了EOT低纬度陆相古气候变化引起的陆相有机质响应,而这种响应与当时大气CO2浓度和海洋温度降低导致的气候和植物群落变化密切相关,即可能存在着C3植物向C4植物的转化、C4植物的迅速增加并最终导致沉积有机质碳同位素组成的变化;也可能是由于大气CO2浓度降低导致的大气CO2碳同位素组成整体正偏的结果。很显然,进一步详细的连续剖面分析将对研究古近纪EOT低纬度陆相古气候变化提供重要科学依据。     

辽西晚古生代长茂河子辉绿岩墙群的地球化学特征

根据全岩K-Ar年龄(287.5~243.6Ma), 辽西朝阳长茂河子辉绿岩墙群形成于晚古生代.这些辉绿岩分为低铁钛辉绿岩和高铁钛辉绿岩2种, 以低铁钛辉绿岩为主.低铁钛辉绿岩以低TiO₂(< 2%)、FeO_t(12.39%~15.33%)、V(227~335μg/g)、Sc(24~36μg/g) 含量和高的SiO₂ (45.61%~47.72%)、Al₂O₃(12.51%~16.71%)、MgO(6.66%~9.31%)、K₂O(0.57%~2.39%)、Cr(107~177μg/g)和Ni(96~235μg/g) 含量, 以及低Ti/Y(327~496)和Ti/Zr (69~114) 比值为特征, 类似于大陆拉斑玄武质岩石; 高铁钛辉绿岩以高的TiO₂ (5%~6%)、FeO_t(22.13%~22.16%)、V(850~859μg/g)、Sc(51~52μg/g) 含量和低的SiO₂ (42.88%~44.90%)、Al₂O₃(11.53%~11.57%)、MgO (5.15%~5.29%, Mg#=0.32)、K₂O (0.48%~0.51%)、Cr(< 2μg/g)和Ni(< 30μg/g) 含量及高的Ti/Y(1046~1106)、Ti/Zr(250~263) 比值为特征, 类似于Skaergaard侵入体.这些辉绿岩相对富集Rb、Th、U、Pb、Ti和轻稀土元素, 而相对亏损Ba、Sr、P和Nb、Ta.ε_Nd(t) (-6.43~-4.12)、ε_Sr(t) (42.94~64.19) 显示Sr-Nd同位素组成较为均匀, 并反映它们源于富集岩石圈地幔.认为长茂河子辉绿岩形成于富集岩石圈地幔的部分熔融, 经历了岩浆结晶分异与地壳混染作用.高铁钛辉绿岩和低高铁钛辉绿岩形成环境不同, 前者形成于相对低氧逸度或相对封闭的结晶环境中.      

花岗岩低温热力效应参数及强度规律研究

长期处于变低温环境中的岩石热力学效应主要表现为材料的力学特性参数、热力系数和饱和冻结状态孔隙冰胀系数等随温度改变而发生变化,这种变化对岩体的变形及强度特性均有显著影响。根据变物性参数的非线性热弹性理论,建立了考虑热力系数和冰胀力系数的本构方程,给出了单轴压缩条件下热力效应系数随温度变化的分析格式和确定方法;借助于花岗岩不同低温干燥和饱和冻结状态的单轴压缩试验资料,获得了花岗岩低温热力效应与温度的关系,并探讨了其对花岗岩抗压强度的影响特性。分析表明,在变低温环境下花岗岩热力系数和冰胀力系数均随相对温差的增大而逐渐减小,热力系数降低速率小于冰胀系数降低速率,在同一温差下热力系数大于冰胀系数;热应力和冰胀应力与温度改变量呈非线性增长关系;花岗岩抗压强度在两种状态下均呈增大趋势,但主要以热应力为主,热力系数引起的试样轴向应力增量总是大于冰胀力引起的轴向应力增量。所给方法及研究成果可用于长期处于变低温状态下材料的力学性能研究及其工程应用。     

商河县郑路镇中低产田项目治理综合效益分析

土地整理效益研究是土地整理理论及实践研究的重要组成部分,也是当今土地科学领域专家和学者关注的重要课题。结合商河县郑路镇项目区的自然和社会经济条件以及土地利用状况,对土地开发整理项目进行社会效益、生态效益及经济效益分析,指出土地整理应寻求社会、生态和经济三大效益的最大结合,实现效益最大化,最终促进农村经济的可持续发展。     

Geochemical Mapping: With Special Emphasis on Analytical Requirements

More than 40 national and regional geochemical mapping projects in the world carried out from 1973 to 1988 do not conform to common standards. In particular they have many analytical deficiencies. In the period 1988 to 1992, the International Geochemical Mapping project （Project 259 of UNESCO＇s IGCP Program） prepared recommendations designed to standardize geochemical mapping methods. The analytical requirements are an essential component of the overall recommendations. They included the following： 71 elements should be analyzed in future mapping projects; the detection limits of trace and ultratrace elements must be lower than the corresponding crustal abundances; and the Chinese GSD and Canadian STSD standard sample series should be used for the correlation of global data. A proposal was also made to collect 5000 composite samples, at very low sampling densities to cover the whole Earth＇s land surface. In 1997 an IUGS Working Group on Global Geochemical Baselines was formed to continue the work which began with IGCP 259. From 1997 up to now, new progress has been made especially in China and FOREGS countries under the aegis of this working group, including the study of suitable sampling media, development of a multi-element analytical system, new proficiency test for selection of competent laboratories and role of wide-spaced mapping in mineral exploration. One of the major problems awaiting solution has been the inability of many laboratories to meet the IGCP recommendations to generate high quality geochemical maps. Fortunately several laboratories in China and Europe have demonstrated an ability to meet the requirements and they will be well placed to render technical assistance to other countries.     

低荧光防塌沥青及低荧光特效封堵防塌降滤失剂的研制与应用

研发了一种具有优良防塌效果的低荧光钻井液用井壁稳定剂，提高石油沥青磺化度，解决降低产品荧光级别的新工艺，突破因荧光干扰测录井导致油储层被误判、漏判的关键技术，磺化反应后期，引入提高产品综合性能的特种材料进行交联反应。介绍了低荧光防塌沥青LF—TEX-1及低荧光特效封堵防塌降滤失剂FSL-1的关键技术原理和生产工艺流程，并对这两种处理剂的性能测试结果进行了分析。实际生产应用表明，他们具有明显的封堵、降失水功能。     

氢氧化物族矿物的氧同位素分馏

应用增量方法计算了氢氧化物族矿物的氧同位素分馏,得到常见氢氧化物的18O富集顺序为：褐铁矿＞三水铝石＞针铁矿＞水镁石＞硬水铝石。氢氧化物与其对应的氧化物相比显著地富集18O。三价阳离子的氢氧化物和氧化物的18O富集顺序为：M（OH）3＞MO（OH）＞M2O3。Al（OH）3同质多象变体之间也存在一定的分馏。对于石英-氢氧化物、方解石-氢氧化物和氢氧化物-水体系,本文计算提供了在0-1200℃温度范围内三组内部一致的分馏系数方程。这些理论校准与合成实验结果和／或地表温度下的天然样品相吻合,特别针铁矿、勃姆石和硬水铝石与水之间的氧同位素分馏关系能够满足地质测温的要求。因此,对氢氧化物-水体系的氧同位素分析可望提供表生环境下可靠的地质温度计。     

混合气体驱替煤层气技术的可行性研究

气体驱替煤层气技术是近年来发展起来的具有温室气体减排和提高煤层气采收率双赢效果的新兴技术,相关研究受到世界主要发达国家的广泛重视。对于温室气体减排的压力,发达国家的研究主要着眼于该技术在高渗透、不可采煤层中的应用,注入气体主要为CO2,目的是尽可能多地封存CO2,同时提高煤层气采收率。目前,国内在这方面的研究刚刚起步。国内煤层具有渗透率普遍较低、不开采煤层与要开采煤层难以界定的特点,注CO2气体驱替煤层气在这种煤层中的可行性值得商榷。针对国内煤层特点和煤矿瓦斯抽采率低的现状,建议采用富N2混合气体驱替煤层气技术,以提高煤层气产采收率。通过理论分析、数值模拟和现场试验研究分析了实施混合气体驱替煤层气技术的可行性。研究结果表明,混合气体驱替煤层气技术适用于国内低渗透、可开采煤层,可以提高煤层气采收率和单产量。