江苏丰、沛、铜地区高氟地下水成因探讨

通过该区太古界一新生界氟的地层地球化学剖面及岩浆岩和土壤中氟的丰度的研究,论证了该区为一高氟的地球化学区。根据重矿物对比研究和地貌分析,阐明了泰沂隆起区太古界和元古界的高氟古老岩系为该区土壤沉积物源,黄河多次泛滥堆积（粘土矿物对氟的吸附）对土壤氟起了叠加富集的作用。研究揭示该区土壤水溶氟较高,经降水淋滤和浸取作用氟转入地下水,并在凹陷区或河间洼地中聚集,水体停泄、蒸发浓缩形成高氟地下水区。     

An infrared spectroscopic study of lawsonite to 20 GPa

The infrared spectrum of CaAl₂Si₂O₇ · H₂O-lawsonite, has been characterized to pressures of 20 GPa at 300 K. Our results constrain the response to compression of the silicate tetrahedra, hydroxyl units, and water molecules in this material. The asymmetric and symmetric stretching and bending vibrations of the Si₂O₇ groups (at zero pressure frequencies between 600 and 1000 cm⁻¹) increase in frequency with pressure at rates between 3.6 and 5.9 cm⁻¹/GPa. All silicate modes appear to shift continuously with pressure to 20 GPa, although the lowest frequency stretching vibration becomes unresolvable above 18 GPa, and a splitting of the main bending vibration is observed near this pressure. The O-H stretches of the hydroxyl units exhibit a discontinuity in their mode shifts at ∼8–9 GPa, which we interpret to be produced by a pressure-induced change in hydrogen bonding. The stretching and bending vibrations of the water molecule are relatively unaffected by compression to 20 GPa, thus demonstrating that the structural cavities in which water molecules reside are relatively rigid. Significant changes in the amplitude of the O-H stretches of the hydroxyl and water units are observed at this pressure as well; nevertheless, our results demonstrate that the dominant structural units in lawsonite persist metastably at 300 K with only modest structural modifications well beyond the known stability field of this phase. Received: 10 July 1998 / Revised, accepted: 23 October 1998     

天然闪锌矿原位高温X射线衍射研究

对天然闪锌矿进行了原位高温X射线衍射实验研究,结果表明：闪锌矿受热膨胀,27～675℃温度范围内其膨胀系数为25.61×10-6℃-1;随着温度的升高,在543℃时产生中间物相Zn3O（SO4）2,并分解产生红锌矿ZnO;在797℃时中间物相完全消失,同时出现尖晶石结构的ZnFe2O4;加热至1160℃时的产物为ZnO和ZnFe2O4。实验表明,天然闪锌矿的热改性可产生一定比例的红锌矿（ZnO）,其与闪锌矿一起形成二元复合半导体。在光的激发下,该半导体体系产生的光生载流子由一种半导体注入另一种半导体,降低了光生电子-空穴对的复合几率,提高其光催化活性。本文的研究可为热改性提高天然闪锌矿光催化活性提供理论依据。     

Formation Mechanism of High Quality Marine Source Rocks—Coupled Control Mechanism of Geological Environment and Organism Evolution

High quality marine source rock (HQMSR) is the key prerequisite for medium to large hydrocarbon accumulations. However, the forming mechanism remains unclear. On the basis of the in-vestigation for the geodynamic setting of the Middle-Upper Yangtze during the Early Cambrian in dif-ferent spatial scales and the analysis of trace elements, the main controlling factors of the development of high quality marine source rock are discussed, with specific consideration of the burial rate of the organic matter. The ...     

南边界强迫的非线性临界层与副高的形成、维持和振荡

用非线性准地转正压涡度方程模式，在南边界取定常强迫波，采用４种方案模拟了非线性临界层及其上激发的Ｋｅｌｖｉｎ猫眼，以确定热带的定常强迫对副高的形成、维持和振荡的影响。结果表明，南边界定常强迫仍在非线性临界层内激发行星尺度的准定常反气旋的Ｋｅｌｖｉｎ猫眼流场，猫眼的移动、强度和形状变化与夏季副高比较相似．而北边界定常强迫所得结果与夏季副高差异较大。因此，南边界所激发的非线性临界层上的Ｋｅｌｖｉｎ猫眼可能是夏季副高形成、维持和振荡的一种更为重要的新物理机制。文中还提出准定常行星波穿越副热带的非线性临界层的物理机制。     

贵州省优质烤烟气候区划指标的补充和修正

从贵州省优质烤烟气候区划指标出发,结合威宁县高海拔地区种烟的实际情况,详细分析了贵州省优质烤烟气候区划指标。得出表征热量与作物生长发育的关系,不仅要考虑日平均温度和持天数,还要考虑积温、昼夜温差、地温及叶面温度等。通过分析,对原指标中成熟期平均温度。大田生长期温度、旺长－成熟期天数等指标进行了修正。补充≥１０℃活动积温≥２２００℃,移栽期日平均气温≥１４℃,月平均日较左≥８℃等指标。     

地下洞室群随机地震响应研究中传递函数的应用探讨

在证明随机响应的统计参数可以用传递函数进行直接表达的前提下,将传递函数引入地下洞室群随机地震响应研究中,对白鹤滩水电工程13#机组剖面地下洞群进行了随机地震响应分析,并对之进行了地震动力可靠度的探讨。结果表明：较之常规方法,基于传递函数的方法除可得到洞室群的随机地震响应以外,还可同时得到洞室群的地震响应频谱特性,并可以直接利用传递函数得到确定性地震动输入下洞室群的响应值进行验证,显示对问题的研究具有更加深刻的优势;将所得到的随机地震响应结果与基于传递函数的确定性估算结果,与实际时程计算得到的确定性结果比较,吻合良好;首次采用超越破坏理论对地下洞室群进行地震动力可靠度分析的可行性,为地下工程抗震可靠度计算中如何以动力方式考虑地震荷载的随机性提供了一些新思路。     

塔河油田3区石炭系超深薄层碎屑岩储层预测研究

针对塔河油田3区石炭系卡拉沙依组地震数据很难识别薄砂体的问题,对比分析了采用地震资料提频处理、分频处理、储层高分辨率敏感参数反演等不同手段得到的储层预测结果,筛选出高分辨率储层敏感参数反演作为卡拉沙依组砂泥岩段储层主要预测手段。通过探讨砂泥岩对声波时差的响应,以及对比分析自然电位、自然伽马以及补偿中子孔隙度与声波时差的关系,确定自然电位与声波时差的相关性最好,由此选取自然电位作为最佳电性敏感参数参与高分辨率敏感参数反演预测。从井点、剖面、平面等方面检验和评价高分辨率储层预测成果,结果表明其反演预测效果较好,符合塔河油田3区石炭系的储层预测要求,实现了对石炭系主力砂体空间展布的解释与描述,建立了塔河油田3区石炭系卡拉沙依组储层模型。     

对矿物包裹体溶液性质的新认识——兼论含矿溶液是酸性溶液的地质证据

对金属矿床成矿溶液的性质 ,特别是 pH值 (酸碱度 )的确定 ,是认识含矿溶液的成因、成矿条件和成矿机理的关键。目前对成矿溶液性质的研究主要局限在对围岩蚀变矿物包裹体的测定方面 ,并得出近中性热卤水成矿的结论。作者认为 ,多数围岩蚀变矿物的包裹体溶液不能代表原成矿溶液的性质 ,“近中性的热卤水成矿”的认识有误 ,应是酸性水形成的含矿溶液成矿 ,并从矿物包裹体溶液的特征、Roedder的高金属含量的矿物包裹体溶液的发现、氢氧同位素资料、矿物包裹体中高卤水溶液的起源以及成矿溶液的演化机理等方面论述了酸性金属含矿溶液的成因及成矿演化过程。     

Longitudinal Displacement of the Subtropical High in the Western Pacific in Summer and its Influence

Using the relative vorticity averaged over a certain area, a new index for measuring the longitudinal position of the subtropical high (SH) in the western Pacific is proposed to avoid the increasing trend of heights in the previous indices based on geopotential height. The years of extreme westward and eastward extension of SH using the new index are in good agreement with those defined by height index. There exists a distinct difference in large-scale circulation between the eastward and westward extension of SH under the new definition, which includes not only the circulation in the middle latitudes but also the flow in the lower latitudes. It seems that when the SH extends far to the east (west), the summer monsoon in the South China Sea is stronger (weaker) and established earlier (later). In addition, there exists a good relationship between the longitudinal position of SH and the summer rainfall in China. A remarkable negative correlation area appears in the Changjiang River valley, indicating that when the SH extends westward (eastward), the precipitation in that region increases (decreases). A positive correlation region is found in South China, showing the decrease of rainfall when the SH extends westward. On the other hand, the rainfall is heavier when the SH retreats eastward. However, the anomalous longitudinal position of SH is not significantly related to the precipitation in North China. The calculation of correlation coefficients between the index of longitudinal position of SH and surface temperature in China shows that a large area of positive values, higher than 0.6 in the center, covers the whole of North China, even extending eastward to the Korean Peninsula and Japan Islands when using NCEP/NCAR reanalysis data to do the correlation calculation. This means that when the longitudinal position of the SH withdraws eastward in summer, the temperature over North China is higher. On the other hand, when it moves westward, the temperature there is lower. This could explain the phenomenon of the seriously high temperatures over North China during recent summers, because the longitudinal position of SH in recent summers was located far away from the Asian continent. Another region with large negative correlation coefficients is found in South China.