青藏高原北部移动冰丘破坏桥墩的数值模拟

青藏高原北部常年冻土区断裂破碎带发育的移动冰丘对桥梁、涵洞、输油管道等工程设施具有不同形式的破坏作用。考虑移动冰丘与工程设施的相互作用,根据野外观测和实验资料设计模型,应用三维有限元数值模拟方法,计算移动冰丘冻胀产生的位移场、应力场和桥墩弯曲应力,分析桥墩破裂机理。结果表明,移动冰丘能够产生11～-21 MPa的轴向应力和15～-31 MPa的主应力,在桥墩周围形成不同规模的应力集中区,导致桥墩发生显著偏移。桥墩的偏移和弯曲能够在桥墩内部产生高达61.9～64.6 MPa的张应力和-45.0～-49.0 MPa的压应力,超过桥墩的强度极限。在粗细桥墩连接部位,外侧形成张应力集中区,最大张应力达26～30 MPa;内侧形成压应力集中区,最大压应力达-25～-28.8 MPa。粗细桥墩连接部位外侧的张应力超过了钢筋混凝土的抗张强度,产生与野外观测资料基本吻合的桥墩破裂和结构破坏。移动冰丘导致桥墩变形破坏的三维有限元数值模拟能够为常年冻土区桥梁工程设计和地质灾害防治提供力学参数和科学依据。     

西湖凹陷西斜坡平湖组储层特征及致密化过程分析

综合应用铸体薄片、扫描电镜、阴极发光、恒速压汞、流体包裹体和X衍射等分析技术,对储层岩石学、孔喉结构和成岩作用类型及特征进行深入研究,探讨储层致密化过程和物性演化。结果表明：平湖组储层砂岩类型主要为长石岩屑质石英砂岩,以细—中粒结构为主,分选性中到好;孔隙类型以溶蚀粒间孔为主,孔隙半径主要集中于130～190 μm,喉道半径主要集中于0.2～10 μm;埋藏压实是导致平湖组储层低渗-特低渗的主因,埋深、粒度及泥质决定了压实作用的强弱,而后期次生溶蚀及胶结作用的差异加剧了储层的非均值性。中成岩A期平湖组储层次生溶蚀规模受限于流体环境,细粒沉积不利于后期溶蚀是造成储层致密化的主因;进入中成岩B期,成岩环境呈碱性且逐渐封闭,大量含铁碳酸盐、呈丝状或弯曲片状伊利石等富集堵塞喉道,致使储层大规模致密。     

Application of topo-edaphic factors and remotely sensed vegetation indices to enhance biomass estimation in a heterogeneous landscape in the Eastern Arc Mountains of Tanzania

Estimating tropical biomass is critical for establishment of conservation inventories and landscape monitoring. However, monitoring biomass in a complex and dynamic environment using traditional methods is challenging. Recently, biomass estimates based on remotely sensed data and ecological variables have shown great potential. The present study explored the utility of remotely sensed data and topo-edaphic factors to improve biomass estimation in the Eastern Arc Mountains of Tanzania. Twenty-nine vegetation indices were calculated from RapidEye data, while topo-edaphic factors were taken from field measurements. Results showed that using topo-edaphic variables or vegetation indices, biomass could be predicted with an R² of 0.4. A combination of topo-edaphic variables and vegetation indices improved the prediction accuracy to an R² of 0.6. Results further showed a decrease in biomass estimates from 1162 ton ha^?1 in 1980 to 285.38 ton ha^?1 in 2012. This study demonstrates the value of combining remotely sensed data with topo-edaphic variables in biomass estimation.     

发展“三高”果业需重视大生态系统的耗散协调性──剖析龙泉花果山的大生态环境

发展高产优质高效果业，常会涉及到大生态系统的各类环境因子群。龙泉花果山的大生态系统主要是以风化岩体→紫色土容库→蜜桃等构成的向量大系统的综合反映，并呈现非均衡耗散结构的复杂协调性，这些因素直接制约“三高”果业的发展。     

Methoxy formation in the reaction of CH3O2 radicals with NO

Formation of methoxy (CH₃O) radicals in the reaction (1) CH₃O₂+NOCH₃O+NO₂ at 298 K has been observed directly using time resolved LIF. The branching ratio % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaeqOXdyMaae% 4qaiaabIeadaWgaaWcbaGaae4maaqabaGccaqGpbGaaeiiaiaabIca% ieqacaWF9aGaa8hiaiaa-nbicaWFGaGaeuiLdqKaai4waiaaboeaca% qGibWaaSbaaSqaaiaabodaaeqaaOGaae4taiaac2facaWFVaGaeuiL% dqKaai4waiaaboeacaqGibWaaSbaaSqaaiaabodaaeqaaOGaae4tam% aaBaaaleaacaqGYaaabeaakiaac2facaqGPaaaaa!4E31!\[\phi {\rm{CH}}_{\rm{3}} {\rm{O (}} = -- \Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}]/\Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}_{\rm{2}} ]{\rm{)}}\] has been determined by quantitative cw-UV-laser absorption at 257 nm of CH₃O₂ and CH₃ONO, the product of the consecutive methoxy trapping reaction (2) % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaae4qaiaabI% eadaWgaaWcbaGaae4maaqabaGccaqGpbacbeGaa83kaiaa-bcaieaa% caGFobGaa43taiaa+bcacaGFOaGaa83kaiaa+1eacaGFPaGaa4hiai% abgkziUkaabccacaqGdbGaaeisamaaBaaaleaacaqGZaaabeaakiaa% b+eacaqGGaGaaeOtaiaab+eacaqGGaGaa4hkaiaa-TcacaGFnbGaa4% xkaiaa+5cacaGFGaGaa4hiaiabeA8aMnaaBaaajqwaacqaaiaaboea% caqGibWaaSbaaKazcaiabaGaae4maaqabaqcKfaGaiaab+eaaSqaba% aaaa!55AC!\[{\rm{CH}}_{\rm{3}} {\rm{O}} + NO ( + M) \to {\rm{ CH}}_{\rm{3}} {\rm{O NO }}( + M). \phi _{{\rm{CH}}_{\rm{3}} {\rm{O}}} \] is found to be (1.0±0.2). The rate constant k ₁ is (7±2) 10^-12 cm³/molecule · s in good agreement with previous results.     

Utilization of Lime for Stabilizing Soft Clay Soil of High Organic Content

This paper presents the results of geotechnical and mineralogical investigations on lime-treated soft clay soil from Idku City, Egypt, where high organic matters of about 14% exist. Lime was added in the order of 1%, 3%, 5% and 7% by weight and laboratory experiments after 7, 15, 30 and 60 days were conducted including the mineralogical and microstructural examinations, grain size analysis, plasticity limits, unconfined compressive tests, vane shear tests and oedometer tests. The results indicate that soft clay soil of high organic content of 14% can be stabilized satisfactorily with the addition of 7% lime. The results also demonstrate that the changes in the mineralogical contents and soil fabric of high organic lime-treated soft clay improve soil plasticity, strength and compressibility.     

顾及外拓扑的异构建筑三维拓扑重建

分析了异构建筑在三维拓扑重建中的问题,依据拓扑数据模型的需求,提出了基于顶图、底图和结构图的自动拓扑重建算法,该算法能够有效地对异构建筑进行整体三维拓扑重建,不仅保留了建筑内每一实体单元的内拓扑,同时也兼顾了实体间的外拓扑。基于该方法,设计并开发了三维地籍管理系统中的数据生成模块,以深圳市某小区为实验区,验证了算法的可行性及有效性。     

Continuous reactions with amphibole, garnet and plagioclase

Abstract End-member, continuous and degenerate reactions are derived for the multisystem with the six components Na₂O, CaO, (Mg/Fe)O, Al₂O₃, SiO₂, H₂O among the phases plagioclase_ss, garnet_ss, amphibole_ss, cpx, opx, olivine, spinel, quartz and an aqueous fluid. The chemography of this system is degenerate due to the co-linearity 2Opx = Ol + Qtz. This co-linearity has its implications both on reaction space and phase equilibria. From a total of 28 reaction systems, reaction space is derived for nine subsystems (phases in parentheses are absent): Case A₁: (Cpx,Ol) (Cpx,Opx) and (Cpx,Qtz), Case A₂: (Spl,Ol) (Spl,Opx) and (Spl,Qtz), Case B: (Ol,Opx) (Ol,Qtz) and (Opx,Qtz). In the absence of either cpx or spl (case A), three reactions form an invariant point, either [Cpx] or [Spl], where the co-linear phases olivine, opx and quartz coexist on the transformation line 2Opx = Ol + Qtz. Changing mineral compositions force invariant points to move along the line with the different reaction curves changing their relative position according to Schreinemakers’rules. Zero contours, i.e. the location where (a) phase(s) disappear(s) in reaction space correspond to singular points in phase diagrams. Two types are distinguished; singular points of indispensable and of substitutable phases. In the first case the phase disappears from the entire bundle while in the second it disappears from a single reaction. In the specific case where the substitutable phases are also the co-linear ones, two of the three co-linear phases disappear simultaneously. Two of the three reaction curves coincide. In the system including Cpx and Spl (Case B) three reactions, (Ol,Opx) (Ol,Qtz) and (Opx,Qtz), oppose three invariant points, [Ol], [Opx] and [Qtz]. Invariant points no longer move along the line 2Opx = Ol + Qtz. The coincidence of the zero contours of all three co-linear phases in reaction space-the result of the chemographic degeneracy-causes the respective singular points to coincide in the phase diagrams. This is the location where curves must be rearranged in a bundle to conform Schreinemakers’rules. The reaction Grs₁Prp₂= 2 Ol + An is fourth order degenerate and part of all nine subsystems (cases A and B). It can be used to relate the different phase diagrams to one another.