长岛县南五岛土壤地球化学特征及环境质量评价

以长岛县南五岛土壤为研究对象,对区内土壤元素的含量特征进行分析,并对土壤环境质量进行评价。结果表明：研究区土壤平均含量与烟台市、山东省以及全国土壤平均水平相比,除CaO,Na2O,Hg,S,Se,P,F元素含量差异较明显,其他大部分元素含量相对稳定,元素含量的高低不仅与研究区背景条件有关,也与人类活动密切相关。研究区土壤环境质量整体较好,大部分区域属于清洁区和尚清洁区,仅城区局部受到一定程度的Cd,Hg,Zn污染。     

Variability of levee failure mechanisms subject to heavy rainfalls,case studies in Taiwan

In this study, the failure mechanisms for Chiuliao 1st Levee and Gueishan Levee in Taiwan were re-examined comprehensively considering the uncertainty of different parameters. Results have shown that for Chiuliao 1st Levee, the slope sliding failure has a higher coefficient of variation (COV). For Gueishan Levee, retaining wall sliding and overturning failure have higher values of COV instead. It can also be found that the scouring depths affect the stability of the levee significantly, therefore, a protecting system for the backfill material may be necessary to increase the stability of the levee effectively.     

发扬地学学科优势,形成具有国土资源部门特色的土壤修复理论与技术体系

岩石圈是土壤重金属元素的根本来源,是其迁移转化和生物-地球化学循环的场所,也是重金属元素的最后归宿,因此地质学、岩石学、矿物学和地球化学在重金属污染土壤修复中具有基础性的重要指导意义。国土资源部门已经在土壤重金属调查、溯源和风险评价上发挥了重要作用,还可以在探索研究灾害链的组成、影响因素和阻断途径的基础上,形成有地学特色的修复理论和技术。目前,国土资源部门的修复理论研究成果主要集中在缓变型地球化学灾害理论和地球化学工程学方面,在所属研究机构已经形成了若干种土壤修复剂,通过小试、中试和典型示范,验证了这些修复剂具有优异的修复性能与效果,是落实"土十条"和生态文明建设的一支重要力量。     

小秦岭太峪水系沉积物重金属污染生态危害评价

以金矿开发影响的黄河二级支流太峪水系沉积物为研究对象,沿河采集16个表层沉积物样品,分层采集垂向剖面10件水库沉积物样品,测定了样品中重金属元素Hg、Pb、Cd、Cr、As、Cu和Zn的含量,采用Hakanson潜在生态指数法和Tomlinson污染负荷指数法评价重金属元素污染程度和潜在生态风险。结果表明,矿业活动是太峪水系沉积物重金属元素污染的主要因素;变异系数、富集系数和最高污染系数均反映Hg、Pb、Cd是太峪水系沉积物的特征污染重金属元素,Cr和As的质量分数接近地区背景值;太峪水系表层沉积物受到重金属元素的极强污染,山区段污染较山外更严重;整个流域的Hg、Pb、Cd具有很强的潜在生态危害,Cr、As、Zn的潜在生态危害轻微;太峪水系沉积物垂向各层沉积物都受到重金属元素的极强污染,生态问题以Hg、Pb、Cd的潜在生态危害为主,其污染和生态危害程度都高于流向上的沉积物。潜在生态危害指数评价突出了不同元素的毒性和危害程度,而污染负荷指数法侧重于样本空间上的污染程度,二者互补使用有利于实际问题的全面评价。     

秦岭某钼矿区开发对东川河流域Cd的影响

为了探索矿业活动对河流水质产生的影响,以秦岭某大型钼矿区下游的东川河流域为研究对象,通过现场采样与室内测试的方法,分析了地表水、沉积物、岩矿样品中重金属Cd的含量特征。采用污染超标倍数法、地累积指数法及Hakanson潜在生态风险评价法分别对东川河流域的河水和底泥样品进行了污染现状评价和生态风险程度评价,最后讨论了Cd的来源。结果表明:东川河主沟16个河水采样点位中,有11个点位的Cd含量明显高于未受矿业活动影响的对照区各点位Cd含量值,Cd含量变异系数达到95.65%,并且从上游到下游各点位Cd含量呈偏态分布,说明东川河流域Cd受矿业活动影响显著。东川河主沟16个河水采样点中有15个Cd含量满足地表水Ⅱ类水标准,比重为93.75%,可以判断东川河整体水质较好。仅5号点位超Ⅱ类水质标准,污染超标倍数为1,为轻度污染。地累积指数分析结果表明,东川河主沟11个底泥样品均存在不同程度的污染:污染最严重的10号点位达到中度-强污染级别;污染最轻的8、9、13号点位为无污染-中度污染;大多数点位为中度污染。东川河主沟11件底泥样品重金属Cd的潜在生态危害指数平均值为120.27,表明东川河主沟底泥总体达到强生态风险程度。酸性矿山废水、原生地质背景、底泥释放、大气干湿降尘等是造成东川河流域Cd重金属污染的主要污染源。     

基于模型试验的泥石流坡面物源启动预警模型

为进一步探明银洞子沟物源区坡面物源启动机理与降雨的相关性,在进行详细的现场考察与工程勘察工作后选取了典型模型体,并采用20余组人工降雨物理试验方法将降雨强度与坡度设为控制变量,研究了4种坡形、5种雨强条件下,坡面松散物源的失稳机制及破坏模式。试验结果揭示了地表变形与地下物理力学参数变化的定量响应关系,并基于试验发生破坏的临界雨量,建立了银洞子沟传统I-D预警模型。之后提炼可靠预警参数(坡度、深部体积含水率),通过数学回归分析方法并采用Exponential模型,得出IGD、IGM多参数新型预警判别式,实现了传统I-D模型的有效修正,并具一定的可靠性和实用价值。     

A Study of the Extended-range Forecast for the Low Frequency Temperature and High Temperature Weather over the Lower Reaches of Yangtze River Valley in Summer

Based on the observational data, the variations of Intraseasonal Oscillation (ISO) of the daily temperatures and its relationships to the high temperature in summer over the lower reaches of the Yangtze River Valley (LYRV) were studied for the period of 1979-2011. It is found that the daily temperatures over LYRV in May-August was mainly of periodic oscillations of 1525, 3060 and 6070 days, and the interannual variation of the intensity of its 3060-day oscillation had a strongly positive correlation with the number of days with daily highest temperature over 35 ℃ in July-August. Low frequency components of daily temperature in the LYRV, and the principal components of the Eastern Asian 850 hPa low frequency temperature, over a time period ranging from 1979 to 2000, were used to establish the Extended Complex Autoregressive model (ECAR) on an extended-range forecast of the 3060-day low frequency temperature over the LYRV. A 11-year independent real-time extended-range forecast was conducted on the extended-range forecast of low frequency component of the temperature over the LYRV in May-August, for the period ranging from 2001 to 2011. These experimental results show that this ECAR model, which is based on a data-driven model, has a good forecast skill at the lead time of approximately 23 days, with a forecast ability superior to the traditional autoregressive (AR) model. Hence, the development and variation of the leading 3060-day modes for the Eastern Asian 850 hPa low frequency temperatures and temporal evolutions of their relationships to low frequency components of the temperature over the LYRV in summer are very helpful in predicting the persistent high temperature over the LYRV at a 20 to 25 days lead.     

Objective Analysis on Large-scale Circulation Type and Its Links to Precipitation over China

Atmospheric circulation anomaly is a direct cause of weather and climate change. In the past, most researches for the relationship between Weather Type (WT) and precipitation have mainly focused on the subjective classification and diagnosis. Compared to the subjective analysis, objective classification uses more consistent index and standard unification, thus, we can get more WTs, and it has been widely used in many areas. By using daily 12UTC Sea Level Pressure (SLP), Precipitable Water (PW), and 700 hPa wind speed (UV700) data from ECMWF’s Interim Reanalysis, the classification of WTs over China was performed with the method of obliquely rotated T-mode principle component analysis. WT and its link to precipitation over China were further analyzed. The results show that the influence of different WTs on precipitation is not uniform over China, and also show distinctly difference in different seasons. A common feature is that WTs great impact on the regions and months with large precipitation, while less impact on regions and months have with less precipitation. In addition, precipitation trends originating from WT intensity changes are much more deterministic, significant, and predictable than trends from WT frequency changes.     

江苏灌河入海口附近重金属元素环境地球化学质量分析

以往对灌河口附近海域进行地球化学调查发现,海底沉积物及海水质量总体良好,但局部沉积物中Cr含量高于一类标准,Cu、As、Pb、Hg等其他重金属元素含量也明显高于其他地区,个别重金属元素已接近一类标准最高限,存在潜在生态风险。为进一步了解其与人类活动是否有关,对灌河靠近入海口40 km长的河水进行了地球化学调查,发现灌河河水中Hg、Cu、Pb等重金属元素存在一定程度的超标现象。结合其他证据认为,人类活动不仅对灌河下游河水质量产生了负面影响,还对入海口附近的海域环境质量产生了潜在威胁。借鉴内梅罗综合指数评价思路对灌河下游及入海口的重金属元素环境质量进行评价,并对如何降低、消除生态风险提出了若干建议。     

Application of Geochemistry and VNIR Spectroscopy in Mapping Heavy Metal Pollution of Stream Sediments in the Takab Mining Area, NW of Iran

This study considered the possibility of using visible and near infrared (VNIR) spectral absorption feature parameters (SAFPs) in predicting the concentration and mapping the distribution of heavy metals in sediments of the Takab area. In total, 60 sediment samples were collected along main streams draining from the mining districts and tailing sites, in order to measure the concentration of As, Co, V, Cu, Cr, Ni, Hg, Ti, Pb and Zn and the reflectance spectra (350–2500 nm). The quantitative relationship between SAFPs (Depth500nm, R610/500nm, R1344/778nm, Area500nm, Depth2200nm, Area2200nm, Asym2200nm) and geochemical data were assessed using stepwise multiple linear regression (SMLR) and enter multiple linear regression (EMLR) methods. The results showed a strong negative correlation between Ni and Cr with Area2200nm, a significant positive correlation between As and Asym2200nm, Ni and Co with Depth2200nm, as well as Co, V and total values with Depth500nm. The EMLR method eventuated in a significant prediction result for Ni, Cr, Co and As concentrations based on spectral parameters, whereas the prediction for Zn, V and total value was relatively weak. The spatial distribution pattern of geochemical data showed that mining activities, along with the natural weathering of base metal occurrences and rock units, has caused high concentrations of heavy metals in sediments of the Sarough River tributaries.