深地震反射剖面揭示的天津地区张渤带地壳精细结构

穿过天津地区张渤带的长86 km、NE向深地震反射剖面揭示了该区清晰的地壳精细结构图像和断裂的深浅构造特征,为研究张渤地震构造带的深部孕震环境和构造模式提供了地震学证据,对探讨晚中生代以来华北裂陷盆地的深部动力学过程及演化具有重要意义.结果表明,天津地区张渤带地壳以结晶基底反射T_G为界,分为上下两部分;上地壳反射波组丰富,分层特征明显,界面起伏形态清楚,清晰地刻画出冀中坳陷新生代沉积分层、箕状沉积凹陷的底界、潮白河断裂、蓟运河断裂及丰台—野鸡坨断裂的几何结构;地壳内部结晶基底（T_G）至Moho之间,显示出近于"反射透明"的地震波场特征,无明显震相,这与华北其他地区的深地震反射剖面结果明显不同;地壳厚度为30.0~34.5 km,总体变化趋势为中段地壳厚而南北端相对较薄,Moho在横向上显示出明显的不均匀和横向间断特征,在Moho被错断处存在两个明显的反射事件R_A和R_C,R_A可能是软流圈热物质上涌的侧向残留物,叠层状反射震相R_C则表现出壳幔过渡带特征;剖面揭示了2条错断Moho的超壳深大断裂（F_D1和F_D2）和9条上地壳断裂,深大断裂应是软流圈热物质上涌,造成上地幔隆起而形成的,上地壳断裂与地壳垂直运动及侧向引张力有关;超壳深断裂（F_D1和F_D2）为本区深部热物质的上涌与能量交换提供了通道,而与之对应的地壳浅部断裂（F₃和F₉）,则为能量调整提供了可能的条件,断裂邻近区域可能是未来发生强震的地区,值得注意.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

生物质燃烧颗粒物有机示踪化合物的测定和应用

使用气相色谱-质谱法对2002年7月-2003年7月的北京市大气粗、细颗粒物样品中的左旋葡聚糖等糖类化合物进行了测定。结果表明，左旋葡聚糖主要存在于细颗粒中，可以作为示踪化合物来研究生物质燃烧现象。生物质燃烧对北京市大气颗粒物有较重要的贡献。对应于12％-40％的PM2.5有机碳和10％-33％的PM10有机碳。北京市在2002年10月和11月受到明显的生物质燃烧的影响，可能由于农田秸杆焚烧和秋季落叶焚烧。2003年5月7日颗粒物样品受到直线距离约为1000km以外的内蒙古自治区呼伦贝尔市大兴安岭林区森林大火烟雾的影响。生物质燃烧事件具有突发性，可以长距离传输；生物质作为农村生物燃料的使用其燃烧排放具有经常性和持久性的特征。     

Characteristics of Aerosol Ionic Compositions in Summer 2003 at Lin''''an of Yangtze Delta Region

With the size-resolved aerosol mass and ion composition data obtained at Lin'an regional atmospheric pollution monitoring station in July 2003, the size distributions of aerosol mass and ionic components, and the correlations between major ion pairs were analyzed. The primary results indicate that in the period of in-situ measurement, the aerosols are mainly composed of fine particles. The mass of aerosols with size less than 2.1μm accounts for 66% of the total mass of all size ranges, in which about 50% of the mass is contributed by the particles with size less than 0.65μm. Similar to the size distributions of aerosol mass, the water-soluble ions are mainly concentrated in the size range of <0.65μm, accounting for about 77% of the sum of analyzed ions, and the ions within the range of <2.1μm reach 88%. The sulfate, ammonium, and potassium are the dominant ionic components in fine particles (particle size less than 2.1μm). Ion correlation analysis suggests that the sulfates in fine particles are mostly in the compounds of (NH4)2SO4, Na2SO4, and K2SO4, but for submicron particles the sulfates are mainly in the form of (NH4)2SO4.     

Atmospheric Electrification in the Solar System

Atmospheric electrification is not a purely terrestrial phenomenon: all Solar System planetary atmospheres become slightly electrified by cosmic ray ionisation. There is evidence for lightning on Jupiter, Saturn, Uranus and Neptune, and it is possible on Mars, Venus and Titan. Controversy surrounds the role of atmospheric electricity in physical climate processes on Earth; here, a comparative approach is employed to review the role of electrification in the atmospheres of other planets and their moons. This paper reviews the theory, and, where available, measurements, of planetary atmospheric electricity which is taken to include ion production and ion–aerosol interactions. The conditions necessary for a planetary atmospheric electric circuit similar to Earth’s, and the likelihood of meeting these conditions in other planetary atmospheres, are briefly discussed. Atmospheric electrification could be important throughout the solar system, particularly at the outer planets which receive little solar radiation, increasing the relative significance of electrical forces. Nucleation onto atmospheric ions has been predicted to affect the evolution and lifetime of haze layers on Titan, Neptune and Triton. Atmospheric electrical processes on Titan, before the arrival of the Huygens probe, are summarised. For planets closer to Earth, heating from solar radiation dominates atmospheric circulations. However, Mars may have a global circuit analogous to the terrestrial model, but based on electrical discharges from dust storms. There is an increasing need for direct measurements of planetary atmospheric electrification, in particular on Mars, to assess the risk for future unmanned and manned missions. Theoretical understanding could be increased by cross-disciplinary work to modify and update models and parameterisations initially developed for a specific atmosphere, to make them more broadly applicable to other planetary atmospheres.     

Surface properties of stabilizing coastal dunes: combining spectral and field analyses

The coastal dunes of Israel have been undergoing a process of stabilization since 1948. One of the major features of this process is a change in the surface properties of the dunes – the development of a biological soil crust (BSC), and a change in the properties of the sand grains themselves. In Ashdod, at the southern coastal plain of Israel, sand properties that include the BSC, their fines (silt and clay) content and free iron-oxide (indicating their degree of rubification) have been analysed in detail using field and lab spectroscopy methods. In addition, sand erosion and deposition were measured using erosion pins to determine their effect on the presence of the above-mentioned factors. It was found that the BSC over these dunes is comprised of green algae that differs in its reflectance spectra from cyanobacterial crust, especially in the blue band. The crust was found to be particularly developed in the stable areas (mainly the interdunes) and on the north-facing slopes rather than on the south-facing slopes. A positive correlation was found between the crust fines and chlorophyll content, with stable areas showing more developed BSC. The stable areas showed also a lower albedo and slightly more developed reddish colour, indicating a slightly higher rate of rubification. This study demonstrates that the intensity of sand erosion/deposition rates affects soil properties, with the BSC being the fastest to react to the stabilization process (months to several years), followed by the content of fine particles (several years to a decade), whereas the rubification process is a much weaker marker and may need much longer time periods to develop (decades to centuries).     

临安大气气溶胶理化特性季节变化

分别利用碳成分分析仪、离子色谱仪和原子吸收光谱仪等获取浙江省临安地区大气气溶胶在春、夏、秋、冬四季的质量浓度、离子与碳成分特性，并对不同粒径气溶胶成分分布特点作了较详细分析。结果表明:气溶胶质量浓度、可溶性离子浓度以及碳成分浓度具有明显的季节变化趋势。整个尺度范围内，气溶胶质量浓度季节变化特点为春季浓度最高，达到534 μg/m3；冬季次之，质量浓度为117.21 μg/m3；夏季浓度最低，平均为65.7 μg/m3；秋季质量浓度98.6 μg/m3。可溶性离子成分在气溶胶中所占比例具有明显的季节性，其中夏季最高为49.4%，春季最低为11.3%。硫酸根离子SO₄2-和氨根离子NH₄+和硝酸根离子NO₃- 3种离子浓度之和约占离子总量的75%~83%。受温度影响，硝酸根离子NO₃-浓度随季节变化幅度较大，夏季平均浓度为1.7 μg/m3, 冬季平均浓度为11.5 μg/m3，是夏季浓度的6.8倍。碳浓度分布特点显示，气溶胶中元素碳浓度春季最高，夏季最低。有机碳浓度春季最高，冬季最低。气溶胶粒度分布特点也非常明显。四季中粒径小于11 μm（PM₁₁）的气溶胶均占气溶胶总量的90%以上，粒径小于2.1 μm（PM_2.1）的气溶胶占到气溶胶总量的53%以上。可溶性离子在粒径小于2.1 μm气溶胶颗粒中，以硫酸根离子、氨根离子和硝酸根离子为主。碳成分尺度分布特征为颗粒越小，有机碳及元素碳浓度越高。     

Effect of Atmospheric Haze on the Deterioration of Visibility over the Pearl River Delta

The studies on the effect of atmospheric aerosol on climate and environment are hot issues in the current circle of international science and technology. In recent years the pollution of aerosol is getting worse and worse over the Pearl River Delta. The clouds of aerosol occur all year round, with heavy pollution area located at the western side at the mouth of Pearl River. The haze weather mainly occurs from October to April next year, resulting in visibility deterioration. From the beginning of 1980s, visibility dramatically deteriorated, obviously increasing haze weather, in which there are three big fluctuations, showing the periods of pollutions of dust, sulphate and dust, fine particle from photochemical process and sulphate and dust accompanying with the development of economy respectively. The long-term tendency of visibility caused by fog and light fog does not show a tendency due to human activities or economic development, which mainly shows the interannual and interdecadal variation of climate. The deterioration of visibility has close relation to the fine particles over Pearl River Delta, with half of PM10 overpass the limited value set by national second graded standard (150μg m-3), meanwhile, all values of PM2.5 overpass the day-mean limited value of American national standard (65μg m-3), especially from October to January next year, monthly mean values of PM2.5 almost reach two times of standard value, indicating the fine particle concentration is very high. The ratio of PM2.5 to PM10 is also very high, reaching 58%-77%, higher especially in dry season than in rainy season. Thus it is the fine particle pollution in aerosol pollution over the Pearl River Delta. Compared with the data of 15 years ago, the ratio of fine particle to aerosol has obviously increased.     

利用多角度POLDER偏振资料实现陆地上空大气气溶胶光学厚度和地表反照率的同时反演 I. 理论与模拟

陆地上空标量辐射对地表反射率和大气气溶胶散射都具有很强的敏感性,而偏振反射只对大气气溶胶敏感,对地表不敏感。根据这个原理并结合POLDER(POLarization and Directionality of Earth Reflectance)资料的特点,作者提出综合利用标量辐射和偏振反射信息来实现陆地上空大气气溶胶和地表反照率的同时反演。首先,利用多角度偏振辐射观测提取大气气溶胶光学参数,再利用标量辐射测量对偏振反演结果作进一步筛选和订正,同时获得地表反射率。数值模拟试验结果证明,仅利用偏振信息只能获取大气气溶胶信息,而且其结果误差较大,特别是对于散射作用较强的短波长通道如670 nm误差更大,但经过标量辐射订正后的结果得到明显改善,气溶胶光学厚度和地表反射率与真实值之间相关系数都达到0.99以上。为提高查找表的计算效率,提出并建立了反演方案所需要的半参数化数值表,利用内插方法寻求气溶胶光学厚度和地表反射率的数值解的反演方法。     

Spatio-temporal characteristics of small-scale wave–current ripples on the Ameland ebb-tidal delta

Ebb-tidal deltas are highly dynamic environments affected by both waves and currents that approach the coast under various angles. Among other bedforms of various scales, these hydrodynamics create small-scale bedforms (ripples), which increase the bed roughness and will therefore affect hydrodynamics and sediment transport. In morphodynamic models, sediment transport predictions depend on the roughness height, but the accuracy of these predictors has not been tested for field conditions with strongly mixed (wave–current dominated) forcing. In this study, small-scale bedforms were observed in the field with a 3D Profiling Sonar at five locations on the Ameland ebb-tidal delta, the Netherlands. Hydrodynamic conditions ranged from wave dominated to current dominated, but were mixed most of the time. Small-scale ripples were found on all studied parts of the delta, superimposed on megaripples. Even though a large range of hydrodynamic conditions was encountered, the spatio-temporal variations in small-scale ripple dimensions were relatively small (height 0.015 m, length 0.11 m). Also, the ripples were always highly three-dimensional. These small dimensions are probably caused by the fact that the bed consists of relatively fine sediment. Five bedform height predictors were tested, but they all overestimated the ripple heights, partly because they were not created for small grain sizes. Furthermore, the predictors all have a strong dependence on wave- and current-related velocities, whereas the ripple heights measured here were only related to the near-bed orbital velocity. Therefore, ripple heights and lengths in wave–current-dominated, fine-grained coastal areas ( mm) may be best estimated by constant values rather than values dependent on the hydrodynamics. In the case of the Ameland ebb-tidal delta, these values were found to be m and m. ©2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.