小试金光谱法同时测定地质样品中超痕量铂钯金

用小试金光谱法同时测定地质样品中低至0·x×10~(-9)级Pt、Pd和Au,包括先用小试金熔炼和灰吹预富集10g样品中的Pt、Pd和Au于1mg的银合粒中,然后把银合粒装入石墨电极同锇-锑合金(ω(Os)=0.06)一起激发,以发射光谱法同时测定它们的含量。小试金法类同经典火试金,但采用纯化过的2PbCO_3·Pb(OH)_2(Pt、Pd和Au的含量皆<0.05 ×10~(-9)代替商品PbO,并且用50ml高铝坩埚在950℃进行熔炼。方法的检出限是Pt0.2×10~(-9),Pd和Au均为0.1×10     

Sectoral targets for developing countries: combining ‘common but differentiated re-sponsibilities’ with ‘meaningful participation’

Although a global cap-and-trade system is seen by many researchers as the most cost-efficient solution to reduce greenhouse gas (GHG) emissions, the governments of developing countries refuse to enter into such a system in the short term. Many scholars and stakeholders, including the European Commission, have thus proposed various types of commitments for developing countries that appear less stringent, such as sectoral approaches. A macroeconomic assessment of such a sectoral approach is provided for developing countries. Two policy scenarios in particular are assessed, in which developed countries continue with Kyoto-type absolute commitments, while developing countries adopt an emissions trading system limited to electricity generation and linked to developed countries' cap-and-trade systems. In the first scenario, CO₂ allowances are auctioned by the government, which distributes its revenues as a lump sum to households. In a second scenario, the auction revenues are used to reduce taxes on, or to give subsidies to, electricity generation. The quantitative analysis, conducted with a hybrid general equilibrium model, shows that such options provide almost as much emissions reduction as a global cap-and-trade system. Moreover, in the second sectoral scenario, GDP losses in developing countries are much lower than with a global cap-and-trade system, as is also the effect on the electricity price.     

中国能源领域温室气体排放现状及减排对策研究

自工业革命以来,随着化石燃料的广泛应用,能源领域的温室气体排放逐渐成为其主要的人为排放源,能源、环境和经济发展之间的矛盾也日益成为各国政府共同关注的焦点。如何有效地进行能源活动中温室气体的减排已经成为涉及环境、经济、政治、外交等多方面的全球性科学问题。文章对中国能源开发利用现状和主要温室气体二氧化碳(CO₂)、甲烷(CH₄)、氧化亚氮(N₂O)能源排放源进行了简要分析,并对适合中国国情的温室气体减排与能源可持续开发与利用"双赢",实现"发展型减排"的有效途径进行了初步的探讨。     

端视电感耦合等离子体发射光谱法测定土壤中有效钼

样品经草酸?草酸铵溶液(Tamm溶液)浸提,分取浸提液,蒸干灼烧破坏草酸盐,制备成硫酸介质溶液,采用端视电感耦合等离子体发射光谱法测定土壤中有效钼。方法检出限(3s)为0.013μg/g,精密度(RSD,n=12)为2.13%~6.70%。经国家一级标准物质验证,测定值与标准值吻合。     

Experimental study on soil CO2 emission in the alpine grassland ecosystem on Tibetan Plateau

The Tibetan Plateau, the Roof of the World, is the highest plateau with a mean elevation of 4000 m. It is characterized by high levels of solar radiation, low air temperature and low air pressure compared to other regions around the world. The alpine grassland, a typical ecosystem in the Tibetan Plateau, is distributed across regions over the elevation of 4500 m. Few studies for carbon flux in alpine grassland on the Tibetan Plateau were conducted due to rigorous natural conditions. A study of soil respiration under alpine grassland ecosystem on the Tibetan Plateau from October 1999 to October 2001 was conducted at Pangkog County, Tibetan Plateau (31.23°N, 90.01°E, elevation 4800 m). The measurements were taken using a static closed chamber technique, usually every two weeks during the summer and at other times at monthly intervals. The obvious diurnal variation of CO2 emissions from soil with higher emission during daytime and lower emission during nighttime was discovered. Diurnal CO2 flux fluctuated from minimum at 05:00 to maximum at 14:00 in local time. Seasonal CO2 fluxes increased in summer and decreased in winter, representing a great variation of seasonal soil respiration. The mean soil CO2 fluxes in the alpine grassland ecosystem were 21.39 mgCO2 · m-2 · h-1, with an average annual amount of soil respiration of 187.46 gCO2 · m-2 · a-1. Net ecosystem productivity is also estimated, which indicated that the alpine grassland ecosystem is a carbon sink.     

The Converter Mechanism of Particle Acceleration and Its Applications to the Unidentified Egret Sources

We discuss the properties of gamma-ray radiation accompanying the acceleration of cosmic rays via the converter mechanism. The mechanism exploits multiple photon-induced conversions of high-energy particles from charged into neutral state (namely, protons to neutrons and electrons to photons) and back. Because a particle in the neutral state can freely cross the magnetic field lines, this allows to avoid both particle losses downstream and reduction in the energy gain factor, which normally takes place due to highly collimated distribution of accelerated particles. The converter mechanism efficiently operates in relativistic outflows under the conditions typical for Active Galactic Nuclei, Gamma-Ray Bursts, and microquasars, where it outperforms the standard diffusive shock acceleration. The accompanying radiation has a number of distinctive features, such as an increase of the maximum energy of synchrotron photons and peculiar radiation beam-pattern, whose opening angle is much wider at larger photon energies. This provides an opportunity to observe off-axis relativistic jets in GeV–TeV energy range. One of the implications is the possibility to explain high-latitude unidentified EGRET sources as off-axis but otherwise typical relativistic-jet sources, such as blazars.     

低压密闭消解-电感耦合等离子体发射光谱法测定地质样品中的硼

采用酸溶-电感耦合等离子体发射光谱法(ICP-OES)测定地质样品中的全硼量,关键环节在于如何防止样品消解过程中硼元素的损失,降低测量过程中的基体干扰、光谱干扰和记忆效应。基于以上问题,本文采用氢氟酸-硝酸-高氯酸-磷酸在低压密闭溶样罐中消解样品,溶出的硼元素与少量磷酸充分络合,防止硼的挥发损失;以基体及主成分浓度与样品相类似的地质类固体标准物质绘制标准曲线做线性校准,有效匹配和降低样品的基体干扰;采用仪器自带的操作软件,观察分析谱线附近是否存在其他元素的干扰,来确定背景扣除最佳的位置及宽度,降低ICP-OES测量中的光谱干扰;以10%的王水作为进样系统的冲洗液,有效消减测量过程中的记忆效应。当稀释因子为200时,方法的检出限(3SD)为1.2μg/g,定量限(10SD)为4.0μg/g;用岩石、土壤及水系沉积物国家一级标准物质对精密度及准确度进行分析验证,11次测定相对标准偏差为1.8%～7.9%,相对误差为-3.6%～6.3%;以外检分析结果为参考,对硼含量在定量限以上的样品测定,相对误差为-9.3%～12.5%。     

煤柱-顶板系统协同作用的脆性失稳与非线性演化机制

把坚硬顶板视为弹性梁,把煤柱视为应变软化介质并采用W e ibu ll分布描述它的损伤本构模型,本文对坚硬顶板和煤柱组成的力学系统,用突变理论方法研究了它的演化失稳过程。通过对建立的尖点突变模型的分析发现,系统失稳主要取决于系统的刚度比k与材料的均匀性或脆性指标m值,并给出了失稳的充要条件力学判据和失稳突跳量的表达式。考虑煤柱介质的粘性或蠕变性,建立了系统演化的非线性动力学模型物理预报模型,并给出了根据顶板沉降观测数据反演非线性动力学模型的方法和稳定性判别准则。对木城涧矿根据观测序列进行了动力学模型的反演分析,一个重要发现是:D值在临近失稳时陡增出现峰值而后急剧下降。根据材料损伤与声发射累计计数的对应关系,建立了系统演化过程中声发射率的动力学模型,并进行了声发射模拟分析和分维分析,发现m值与系统的演化路径对系统演化的声发射活动规律及分维特征有重要影响,单纯根据声发射监测和降维现象预报冲击地压是不可靠的。     

中国海洋交通运输业碳排放效率测度及影响因素分析

海洋交通运输业碳排放研究对制定行之有效的低碳海洋交通政策具有重要意义。本文首先对2006—2015年中国沿海11个省(区、市)的海洋交通运输业碳排放量进行估算,然后运用超效率SBM模型对碳排放效率进行测度,最后运用Tobit模型探究碳排放效率的影响因素。结果表明:①中国海洋交通运输业碳排放效率整体上处于低效率状态,且各省(区、市)间差异明显,但差异正在逐渐缩小。②2006—2015年沿海各省(区、市)市海洋交通运输业碳排放效率变动呈现出“M”形波动上升趋势。③将各省(区、市)海洋交通运输业碳排放效率水平划分为不同类型,其中上海和天津属于高效率型,河北属于中效率型,其余省(区、市)市属于低效率型。④货运距离和能源结构对海洋交通运输业碳排放效率具有显著的正向作用,而能源强度对其具有显著的负向作用。